Iridium-catalyzed allylic substitutions with cyclometalated phosphoramidite complexes bearing a dibenzocyclooctatetraene ligand: Preparation of (π-Allyl)Ir complexes and computational and NMR spectroscopic studies

Chemistry - A European Journal

Volumn 18, Issue 45, 2012, Pages 14314-14328

  Raskatov, Jevgenij A ^a   Jäkel, Mascha ^a   Straub, Bernd F ^a   Rominger, Frank ^a   Helmchen, Günter ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

allylic substitution; asymmetric catalysis; iridium; phosphoramidites; reaction mechanisms

Indexed keywords

AEROBIC CONDITION; ALLYLIC AMINATION; ALLYLIC CARBONATES; ALLYLIC SUBSTITUTION; ASYMMETRIC CATALYSIS; CYCLOMETALATION; DFT CALCULATION; IR COMPLEXES; MECHANISTIC ASPECTS; PHOSPHORAMIDITES; REACTION MECHANISM; RESTING STATE; SPECTROSCOPIC STUDIES; X-RAY CRYSTAL STRUCTURE ANALYSIS;

ALLYLATION; CATALYSIS; CATALYSTS; CHEMICAL COMPOUNDS; DENSITY FUNCTIONAL THEORY; IRIDIUM; SPECTROSCOPIC ANALYSIS; SUBSTITUTION REACTIONS;

IRIDIUM COMPOUNDS;

EID: 84868020743     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201201772     Document Type: Article

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