Reactions of the cumyloxyl and benzyloxyl radicals with tertiary amides. hydrogen abstraction selectivity and the role of specific substrate-radical hydrogen bonding

Journal of Organic Chemistry

Volumn 78, Issue 12, 2013, Pages 5909-5917

  Salamone, Michela ^a   Milan, Michela ^a   Dilabio, Gino A ^b,c   Bietti, Massimo ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^c UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN ABSTRACTION REACTION; HYDROGEN BOND INTERACTION; INTRAMOLECULAR HYDROGEN; N ,N-DIMETHYLACETAMIDE; N ,N-DIMETHYLFORMAMIDE; RATE-LIMITING FORMATION; THEORETICAL INVESTIGATIONS; TIME-RESOLVED KINETIC STUDY;

AMIDES; FUNCTIONAL GROUPS; HYDROGEN BONDS; ORGANIC SOLVENTS; SUBSTRATES;

ABSTRACTING;

ACETIC ACID DERIVATIVE; ALIPHATIC AMINE; AMIDE; BENZYLOXYL RADICAL; CARBON; CUMYLOXYL RADICAL; DIMETHYL SULFOXIDE; HYDROGEN; HYDROXYL RADICAL; N,N DIMETHYLACETAMIDE; N,N DIMETHYLFORMAMIDE; OXYGEN; TERTIARY AMINE; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; DISSOCIATION CONSTANT; ENZYME SPECIFICITY; HYDROGEN BOND; MATHEMATICAL COMPUTING; MOLECULAR INTERACTION; PHASE TRANSITION; STEREOCHEMISTRY;

ACETAMIDES; ACETONITRILES; ALCOHOLS; BENZENE DERIVATIVES; DIMETHYLFORMAMIDE; FREE RADICALS; HYDROGEN; HYDROGEN BONDING; KINETICS; MOLECULAR STRUCTURE;

EID: 84879385355     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo400535u     Document Type: Article

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