Hydrogen atom abstraction reactions from tertiary amines by benzyloxyl and cumyloxyl radicals: Influence of structure on the rate-determining formation of a hydrogen-bonded prereaction complex

Journal of Organic Chemistry

Volumn 76, Issue 15, 2011, Pages 6264-6270

  Salamone, Michela ^a   Dilabio, Gino A ^b   Bietti, Massimo ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AMINE STRUCTURES; CYCLIC AMINES; DIFFUSION LIMITS; HYDROGEN ATOM ABSTRACTION; LONE PAIR; OVERALL REACTIONS; PREREACTION COMPLEXES; TERTIARY AMINE; TIME-RESOLVED KINETIC STUDY;

ABSTRACTING; AMINES; ATOMS; COMPLEXATION; DEUTERIUM; RATE CONSTANTS;

HYDROGEN;

BENZYLOXYL; CHEMICAL COMPOUND; CUMYLOXYL; HYDROGEN; NITROGEN; PEMPIDINE; TERTIARY AMINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; KINETICS;

AMINES; BENZYL COMPOUNDS; FREE RADICALS; HYDROGEN; HYDROGEN BONDING; MODELS, CHEMICAL; MOLECULAR STRUCTURE;

EID: 79961046338     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo201025j     Document Type: Article

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