Hydrogen abstraction from cyclic amines by the cumyloxyl and benzyloxyl radicals. the role of stereoelectronic effects and of substrate/radical hydrogen bonding

Journal of Organic Chemistry

Volumn 77, Issue 19, 2012, Pages 8556-8561

  Salamone, Michela ^a   Martella, Roberto ^a   Bietti, Massimo ^a  

^a UNIVERSITY OF ROME TOR VERGATA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ALKOXYL RADICALS; COMPLEX FORMATIONS; CYCLIC AMINES; ELECTRONIC EFFECTS; HYDROGEN ABSTRACTION; HYDROGEN ABSTRACTION REACTION; HYDROGEN ATOMS; KINETIC STUDY; LONE PAIR; MORPHOLINES; POLAR EFFECT; PRE-REACTIONS; PYRROLIDINES; STEREOELECTRONIC EFFECT; STERIC HINDRANCES; STRUCTURAL EFFECT; TERTIARY AMINE;

ABSTRACTING; HYDROGEN; HYDROGEN BONDS; RATE CONSTANTS;

AMINES;

AMINE; HYDROGEN; MORPHOLINE; NITROGEN; PIPERAZINE; PIPERIDINE; PYRROLIDINE DERIVATIVE; RADICAL;

ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; HYDROGEN ABSTRACTION; HYDROGEN BOND; PHOTOLYSIS; REACTION ANALYSIS; STEREOCHEMISTRY;

ALCOHOLS; AMINES; BENZYL COMPOUNDS; HYDROGEN BONDING; KINETICS; MOLECULAR STRUCTURE;

EID: 84867386015     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo3015352     Document Type: Article

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