Effect of metal ions on the reactions of the cumyloxyl radical with hydrogen atom donors. Fine control on hydrogen abstraction reactivity determined by Lewis acid-base interactions

Journal of the American Chemical Society

Volumn 135, Issue 1, 2013, Pages 415-423

  Salamone, Michela ^a   Mangiacapra, Livia ^a   Dilabio, Gino A ^b,c   Bietti, Massimo ^a  

^a Dipartimento di Scienze e Tecnologie Chimiche   (Italy)

^b NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^c UNIVERSITY OF ALBERTA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,4-CYCLOHEXADIENES; ALKOXYL RADICALS; CARBON-CENTERED RADICALS; DONOR ABILITY; DONOR SUBSTRATES; HETEROATOMS; HYDROGEN ABSTRACTION; HYDROGEN ABSTRACTION REACTION; HYDROGEN ATOMS; LEWIS ACID-BASE INTERACTION; LEWIS ACIDITY; LONE PAIR; METAL SALT; TERTIARY AMINE; TIME-RESOLVED KINETIC STUDY; TRANSITION STATE;

ABSTRACTING; ACETONITRILE; AMINES; METAL IONS; RATE CONSTANTS; SUBSTRATES;

HYDROGEN;

1,4 CYCLOHEXADIENE; ACETONITRILE; ALKOXY RADICAL; AMINE; CUMYLOXYL RADICAL; HYDROGEN; INORGANIC SALT; LEWIS ACID; LEWIS BASE; LITHIUM ION; LITHIUM PERCHLORATE; MAGNESIUM ION; MAGNESIUM PERCHLORATE; METAL ION; RADICAL; SODIUM ION; UNCLASSIFIED DRUG;

ACID BASE BALANCE; ACIDITY; ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CONCENTRATION RESPONSE; HYDROGEN BOND; MOLECULAR INTERACTION; MOLECULAR STABILITY; PHOTOLYSIS;

ALCOHOLS; HYDROGEN; IONS; LEWIS ACIDS; LEWIS BASES; LITHIUM; MAGNESIUM; MOLECULAR STRUCTURE;

EID: 84872110820     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja309579t     Document Type: Article

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