Chemistry of the t-butoxyl radical: Evidence that most hydrogen abstractions from carbon are entropy-controlled

Journal of the American Chemical Society

Volumn 126, Issue 24, 2004, Pages 7578-7584

  Finn, Meghan ^a   Friedline, Robert ^a   Suleman, N Kamrudin ^a   Wohl, Christopher J ^a   Tanko, James M ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; AMINES; CHEMICAL BONDS; DISSOCIATION; ENTROPY; RATE CONSTANTS;

BOND DISSOCIATION ENERGIES (BDE); HYDROGEN ABSTACTIONS;

HYDROCARBONS;

CARBON; HYDROCARBON; HYDROGEN; RADICAL; REACTIVE OXYGEN METABOLITE; TERT BUTOXYL RADICAL; TERTIARY AMINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL MODEL; CHEMISTRY; DISSOCIATION; ENTROPY; HYDROGEN BOND; PARAMETER; ROOM TEMPERATURE;

EID: 2942667706     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0493493     Document Type: Article

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