Thermal hydrogen-atom transfer from methane: The role of radicals and spin states in oxo-cluster chemistry

Angewandte Chemie - International Edition

Volumn 51, Issue 23, 2012, Pages 5544-5555

  Dietl, Nicolas ^a   Schlangen, Maria ^a   Schwarz, Helmut ^a,b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

Author keywords

C H activation; density functional calculations; gas phase reactions; hydrogen atom transfer; reaction mechanisms

Indexed keywords

AMBIENT CONDITIONS; C-H ACTIVATION; CHEMICAL PROCESS; COMPUTATIONAL STUDIES; GAS-PHASE EXPERIMENTS; GAS-PHASE REACTIONS; HYDROGEN-ATOM TRANSFER; INTRINSIC PROPERTY; OXO-CLUSTERS; REACTION MECHANISM; ROOM TEMPERATURE; SATURATED HYDROCARBONS; SPIN DENSITIES; SPIN STATE;

ABSTRACTING; ACTIVATION ANALYSIS; DENSITY FUNCTIONAL THEORY; EXPERIMENTS; FUNCTIONAL GROUPS; HYDROGEN; METHANE; PHASE INTERFACES;

FREE RADICAL REACTIONS;

EID: 84861651053     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201108363     Document Type: Review

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