C-H bond amination by photochemically generated transient borylnitrenes at room temperature: A combined experimental and theoretical investigation of the insertion mechanism and influence of substituents

Organometallics

Volumn 31, Issue 10, 2012, Pages 3894-3903

  Filthaus, Matthias ^a,b   Schwertmann, Larissa ^b   Neuhaus, Patrik ^b   Seidel, Rüdiger W ^b   Oppel, Iris M ^c   Bettinger, Holger F ^a,b  

^a UNIVERSITY OF TÜBINGEN   (Germany)

^b RUHR UNIVERSITY BOCHUM   (Germany)

^c RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,2-DIAMINOETHANE; BORYLNITRENE; C-H BOND; C-H INSERTION; CBS-QB3; CCSD; CYCLOHEXANE SOLVENT; FLOW REACTORS; INSERTION MECHANISM; INSERTION PRODUCTS; INSERTION REACTIONS; INTERSYSTEM CROSSING; KINETIC ISOTOPE EFFECTS; LOW-YIELD; ORGANIC GLASS; PINACOLS; RELATIVE ENERGIES; ROOM TEMPERATURE; SADDLE POINT; SINGLET STATE; SUBSTITUTION PATTERNS; THEORETICAL INVESTIGATIONS; TRIPLET STATE; ZERO-FIELD SPLITTING PARAMETERS;

ATMOSPHERIC PRESSURE; ISOTOPES; METHANE; PHENOLS; PHOTOLYSIS;

CYCLOHEXANE;

EID: 84861503112     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om300063y     Document Type: Article

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