Amide-based nonheme cobalt(III) olefin epoxidation catalyst: Partition of multiple active oxidants Co V=O, Co IV=O, and Co III-OO(O)CR

Chemistry - A European Journal

Volumn 18, Issue 19, 2012, Pages 6094-6101

  Song, Young Joo ^a   Hyun, Min Young ^a   Lee, Jun Ho ^b   Lee, Hong Gyu ^a   Kim, Jin Hoon ^a   Jang, Seung Pyo ^a   Noh, Jin Young ^a   Kim, Youngmee ^c   Kim, Sung Jin ^c   Lee, Suk Joong ^b   Kim, Cheal ^a  

^a Seoul National University of Science and Technology   (South Korea)

^b Korea University   (South Korea)

^c Ewha Womans University   (South Korea)

Author keywords

catalysts; cleavage reactions; cobalt; epoxidation; high valent species

Indexed keywords

ACTIVE SUBSTRATES; ANIONIC NITROGEN; CHELATE LIGANDS; CLEAVAGE REACTION; COBALT COMPLEXES; COMPLEX 1; DEPROTONATED AMIDES; EPR MEASUREMENTS; EPR SPECTROSCOPY; EXTREME CONDITIONS; HETEROLYTIC CLEAVAGE; HIGH-VALENT SPECIES; HOMOLYSIS; HOMOLYTIC CLEAVAGE; NONHEME; OLEFIN EPOXIDATION; PRODUCT ANALYSIS; PROTIC SOLVENTS; REACTIVE SPECIES; STEREOSPECIFIC; TETRADENTATE LIGANDS;

AMIDES; BENZENE; CATALYSTS; CHLORINE COMPOUNDS; COBALT; EPOXIDATION; LIGANDS; OLEFINS; OXIDANTS; X RAY CRYSTALLOGRAPHY;

COBALT COMPOUNDS;

AMINE; BIPHENYL DERIVATIVE; COBALT; ENAMINE; IMIDAZOLE DERIVATIVE; OXIDIZING AGENT; TRIAZOLE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; COMBINATORIAL CHEMISTRY; CYCLIZATION; STEREOISOMERISM; SYNTHESIS;

AMINES; BIPHENYL COMPOUNDS; CATALYSIS; COBALT; COMBINATORIAL CHEMISTRY TECHNIQUES; CYCLIZATION; IMIDAZOLES; MOLECULAR STRUCTURE; OXIDANTS; STEREOISOMERISM; TRIAZOLES;

EID: 84860702782     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103916     Document Type: Article

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