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Volumn 35, Issue 21, 1996, Pages 6282-6291

Synthesis, Properties, and Structure of a Stable Cobalt(III) Alkyl Peroxide Complex and Its Role in the Oxidation of Cyclohexane

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EID: 0001608852     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960500m     Document Type: Article
Times cited : (71)

References (48)
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    • (b) A brief report on the same ligand and metal complexes derived therefrom was published by Nonoyama (Nonoyama, M. Inorg. Chim. Acta 1974, 10, 59); however, this account contained no physical or spectroscopic data on the ligand.
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    • 1995. Distributed by Siemens Industrial Automation, Inc., Madison, WI. Tables of neutral-atom scattering factors. f′ and f″, and absorption coefficients were taken from: Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, Tables 6.1.1.3
    • G. Sheldrick (1995). Distributed by Siemens Industrial Automation, Inc., Madison, WI. Tables of neutral-atom scattering factors. f′ and f″, and absorption coefficients were taken from: International Tables for Crystallography, Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C, Tables 6.1.1.3 (pp 500-502), 4.2.6.8 (pp 219-222), and 4.2.4.2 (pp 193-199), respectively.
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    • Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 4.2.6.8
    • G. Sheldrick (1995). Distributed by Siemens Industrial Automation, Inc., Madison, WI. Tables of neutral-atom scattering factors. f′ and f″, and absorption coefficients were taken from: International Tables for Crystallography, Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C, Tables 6.1.1.3 (pp 500-502), 4.2.6.8 (pp 219-222), and 4.2.4.2 (pp 193-199), respectively.
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    • G. Sheldrick (1995). Distributed by Siemens Industrial Automation, Inc., Madison, WI. Tables of neutral-atom scattering factors. f′ and f″, and absorption coefficients were taken from: International Tables for Crystallography, Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C, Tables 6.1.1.3 (pp 500-502), 4.2.6.8 (pp 219-222), and 4.2.4.2 (pp 193-199), respectively.
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    • Since 8 is insoluble in pure cyclohexane, one needs dichloromethane to solubilize the complex in the oxidation medium. After several attempts in mixed solvents of different ratios, a 1:1 mixture of cyclohexane and dichloromethane was found to be optimal for this work
    • Since 8 is insoluble in pure cyclohexane, one needs dichloromethane to solubilize the complex in the oxidation medium. After several attempts in mixed solvents of different ratios, a 1:1 mixture of cyclohexane and dichloromethane was found to be optimal for this work.
  • 35
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    • At the end of the oxidation reaction, a small amount of insoluble precipitate is observed at the bottom of the reaction vessel
    • At the end of the oxidation reaction, a small amount of insoluble precipitate is observed at the bottom of the reaction vessel.
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    • Barton, D. H. R., Martell, A. E., Sawyer, D. T., Eds.; Plenum Press: New York
    • Trapping of cyclohexyl radicals by halogenated hydrocarbons has been noted in cyclohexane oxidation: (a) Leising, R. A.; Kojima, T.; Que, L., Jr. In The Activation of Dioxoygen and Homogeneous Catalytic Oxidation; Barton, D. H. R., Martell, A. E., Sawyer, D. T., Eds.; Plenum Press: New York, 1993; pp 321-331. (b) Kim, J.; Larka, E.; Wilkinson, E. C.; Que, L., Jr. Angew. Chem., Int. Ed. Engl. 1995, 34, 2048.
    • (1993) The Activation of Dioxoygen and Homogeneous Catalytic Oxidation , pp. 321-331
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    • Trapping of cyclohexyl radicals by halogenated hydrocarbons has been noted in cyclohexane oxidation: (a) Leising, R. A.; Kojima, T.; Que, L., Jr. In The Activation of Dioxoygen and Homogeneous Catalytic Oxidation; Barton, D. H. R., Martell, A. E., Sawyer, D. T., Eds.; Plenum Press: New York, 1993; pp 321-331. (b) Kim, J.; Larka, E.; Wilkinson, E. C.; Que, L., Jr. Angew. Chem., Int. Ed. Engl. 1995, 34, 2048.
    • (1995) Angew. Chem., Int. Ed. Engl. , vol.34 , pp. 2048
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    • .. radical which subsequently combines with Cy to produce P
    • .. radical which subsequently combines with Cy to produce P.
  • 47
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    • 2, and molecular oxygen in DMF was recently reported by Hirao and co-workers: (a) Moriuchi, T.; Hirao, T.; Ishikawa, T.; Ohshiro, Y.; Ikeda, I. J. Mol. Catal. 1995, 95, L1-L5. (b) Hirao, T.; Moriuchi, T.; Mikami, S.; Ikeda, I.; Ohshiro, Y. Tetrahedron Lett. 1993, 34, 1031.
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    • 2, and molecular oxygen in DMF was recently reported by Hirao and co-workers: (a) Moriuchi, T.; Hirao, T.; Ishikawa, T.; Ohshiro, Y.; Ikeda, I. J. Mol. Catal. 1995, 95, L1-L5. (b) Hirao, T.; Moriuchi, T.; Mikami, S.; Ikeda, I.; Ohshiro, Y. Tetrahedron Lett. 1993, 34, 1031.
    • (1993) Tetrahedron Lett. , vol.34 , pp. 1031
    • Hirao, T.1    Moriuchi, T.2    Mikami, S.3    Ikeda, I.4    Ohshiro, Y.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.