How do aldehyde side products occur during alkene epoxidation by cytochrome P450? Theory reveals a state-specific multi-state scenario where the high-spin component leads to all side products

Journal of Inorganic Biochemistry

Volumn 98, Issue 7, 2004, Pages 1183-1193

  De Visser, Sam P ^a   Kumar, Devesh ^a   Shaik, Sason ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Cytochrome P450; Enzyme catalysis; Enzyme inactivation; Epoxidation; Rearrangement studies

Indexed keywords

ALDEHYDE; ALKENE; CARBON; CYTOCHROME P450; EPOXIDE; FERRIC ION; IRON; NITROGEN; PORPHYRIN; SULFUR;

CHEMICAL BOND; CONFERENCE PAPER; EPOXIDATION; STEREOCHEMISTRY; THEORETICAL STUDY;

EID: 3042635677     PISSN: 01620134     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jinorgbio.2004.01.015     Document Type: Conference Paper

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