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It is clear from the data presented herein that the Mn(V) complexes reported in ref 9 are also anionic, D4h-symmetric dioxo species. We suspect that the broad RR bands reported there with smaller isotopic shifts (34 cm-1) are those of O=MnIV-OH complexes derived from photoreduction cf. ref 13
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IV-OH complexes derived from photoreduction (cf. ref 13).
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