Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

Chemistry - A European Journal

Volumn 16, Issue 47, 2010, Pages 13995-14006

  Makhlynets, Olga V ^a   Rybak Akimova, Elena V ^a  

^a TUFTS UNIVERSITY   (United States)

Author keywords

hydrogen peroxide; hydroxylation; iron; kinetics; oxidation

Indexed keywords

ACTIVE SPECIES; AMINOPYRIDINES; AROMATIC HYDROXYLATION; AROMATIC RINGS; AROMATIC SUBSTRATES; BENZENE HYDROXYLATION; COMPLEX 1; EPR SIGNALS; HEME IRON; HIGH YIELD; HOMOLYSIS; HYDROPEROXIDES; KINETIC ANALYSIS; KINETIC ISOTOPE EFFECTS; MECHANISM OF ACTION; MECHANISTIC PROBES; MECHANISTIC STUDIES; OXIDATION REACTIONS; OXYGEN ATOM; RATE LIMITING; REACTION STEPS; REACTIVE SPECIES; SELF-DECOMPOSITION; STOPPED-FLOW KINETICS; SUBSTITUTED BENZENES; SUBSTRATE OXIDATION;

AROMATIC COMPOUNDS; AROMATIZATION; BENZENE; BIOMIMETICS; ETHANE; HYDROGEN; HYDROGEN PEROXIDE; HYDROXYLATION; IRON COMPOUNDS; ISOTOPES; OXIDANTS; OXIDATION; OXYGEN; PORPHYRINS; REACTION KINETICS; SUBSTRATES;

REACTION INTERMEDIATES;

EID: 78650276716     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201002577     Document Type: Article

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