Reactivity of activated versus nonactivated 2-(bromomethyl)aziridines with respect to sodium methoxide: A combined computational and experimental study

Journal of Organic Chemistry

Volumn 76, Issue 21, 2011, Pages 8698-8709

  Goossens, Hannelore ^a   Vervisch, Karel ^a   Catak, Saron ^a   Stanković, Sonja ^a   D'Hooghe, Matthias ^a   De Proft, Frank ^b   Geerlings, Paul ^b   De Kimpe, Norbert ^a   Waroquier, Michel ^a   Van Speybroeck, Veronique ^a  

^a GHENT UNIVERSITY   (Belgium)

^b VRIJE UNIVERSITEIT BRUSSEL   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

AZIRIDINES; CARBON ATOMS; COMPUTATIONAL ANALYSIS; COMPUTATIONAL RESULTS; DFT CALCULATION; ENERGY PROFILE; EXPERIMENTAL STUDIES; EXPLICIT SOLVENTS; INVERSION OF CONFIGURATION; RING OPENING; SODIUM METHOXIDE; SOLVENT MOLECULES; SUPER MOLECULES;

BROMINE COMPOUNDS; IONIC LIQUIDS; METHANOL; NUCLEOPHILES; SODIUM;

ORGANIC COMPOUNDS;

1 BENZYL 2 (BROMOMETHYL)AZIRIDINE; 2 (BROMOMETHYL)AZIRIDINE; 2 BROMOMETHYL 1 TOSYLAZIRIDINE; AZIRIDINE; AZIRIDINE DERIVATIVE; BROMIDE; CARBON; EPOXIDE; HETEROCYCLIC COMPOUND; METHANOL; METHOXIDE SODIUM; NUCLEOPHILE; OXIDE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; DENSITY FUNCTIONAL THEORY; EXPERIMENTAL STUDY; RING OPENING; SYNTHESIS;

AZIRIDINES; IONS; METHANOL; MOLECULAR STRUCTURE; QUANTUM THEORY; SOLVENTS; STEREOISOMERISM;

EID: 80055072245     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo201255z     Document Type: Article

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