Kinetic and mechanistic Study on p-Quinodimethane formation in the sulfinyl precursor route for the polymerization of poly(p-phenylenevinylene)(PPV)

Macromolecules

Volumn 43, Issue 18, 2010, Pages 7424-7433

  Hermosilla, Laura ^a,b   Catak, Saron ^a,b   Speybroeck, Veronique Van ^a,b   Waroquier, Michel ^a,b   Vandenbergh, Joke ^c   Motmans, Filip ^c,d   Adriaensens, Peter ^c   Lutsen, Laurence ^c   Cleij, Thomas ^c   Vanderzande, Dirk ^c  

^a GHENT UNIVERSITY   (Belgium)

^b QCMM Alliance Ghent Brussels ^*  (Belgium)

^c HASSELT UNIVERSITY   (Belgium)

^d FLEMISH INSTITUTE FOR TECHNOLOGICAL RESEARCH VITO   (Belgium)

Author keywords

[No Author keywords available]

Indexed keywords

2-BUTANOL; AROMATIC MOIETIES; COMPARISON WITH EXPERIMENTS; DENSITY FUNCTIONAL THEORY CALCULATIONS; FIRST PRINCIPLE CALCULATIONS; LEAVING GROUPS; MECHANISTIC STUDIES; P-PHENYLENEVINYLENE; POLY-P-PHENYLENEVINYLENE; PRECURSOR ROUTES; PSEUDO-FIRST-ORDER REACTION; QUANTITATIVE KINETICS; QUANTITATIVE MEASUREMENT; REACTION RATE COEFFICIENTS; THEORETICAL POINTS; UV-VIS SPECTROSCOPY;

DENSITY FUNCTIONAL THEORY; EXPERIMENTS; POLYMERIZATION; SPONTANEOUS EMISSION; ULTRAVIOLET SPECTROSCOPY;

REACTION RATES;

EID: 78651340029     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma1013012     Document Type: Article

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