Catalytic mechanism of water oxidation with single-site ruthenium-heteropolytungstate complexes

Journal of the American Chemical Society

Volumn 133, Issue 30, 2011, Pages 11605-11613

  Murakami, Masato ^a   Hong, Dachao ^a   Suenobu, Tomoyoshi ^a   Yamaguchi, Satoru ^b   Ogura, Takashi ^b   Fukuzumi, Shunichi ^a,c  

^a OSAKA UNIVERSITY   (Japan)

^b UNIVERSITY OF HYOGO   (Japan)

^c Ewha Womans University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SPECIES; CATALYTIC CYCLES; CATALYTIC INTERMEDIATES; CATALYTIC MECHANISMS; CATALYTIC REACTIVITY; COMPLEX 1; CYCLIC VOLTAMMETRIC MEASUREMENTS; HETEROPOLYTUNGSTATES; IN-SITU; KEGGIN-TYPE; KINETIC ANALYSIS; LACUNARY; ONE-ELECTRON OXIDANTS; OXO COMPLEXES; OXYGEN ATOM; POURBAIX DIAGRAM; RATE DETERMINING STEP; REDOX COUPLE; RESONANCE RAMAN; RUTHENIUM COMPLEXES; UV-VISIBLE ABSORPTION; VARIOUS PH; WATER OXIDATION;

BIOELECTRIC PHENOMENA; ELECTRON SPIN RESONANCE SPECTROSCOPY; ISOTOPES; OXIDATION; OXYGEN; REACTION INTERMEDIATES; RUTHENIUM; RUTHENIUM COMPOUNDS; WATER ABSORPTION;

CATALYTIC OXIDATION;

GERMANIUM DERIVATIVE; OXIDIZING AGENT; RUTHENIUM COMPLEX; SILICON DERIVATIVE; TUNGSTEN DERIVATIVE; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CATALYSIS; CATALYST; CYCLIC POTENTIOMETRY; ELECTRON SPIN RESONANCE; ISOTOPE LABELING; KINETICS; OXIDATION; OXIDATION REDUCTION REACTION; PH; RAMAN SPECTROMETRY; ULTRAVIOLET SPECTROSCOPY;

CATALYSIS; ELECTROCHEMISTRY; HYDROGEN-ION CONCENTRATION; OXIDATION-REDUCTION; OXYGEN; RUTHENIUM; TUNGSTEN COMPOUNDS; WATER;

EID: 79960878345     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2024965     Document Type: Article

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