Synthesis and characterization of the Keggin-type ruthenium-nitrido derivative [PW11O39{RuN}]4- and evidence of its electrophilic reactivity

Journal of the American Chemical Society

Volumn 129, Issue 22, 2007, Pages 7127-7135

  Lahootun, Vanina ^a   Besson, Claire ^a   Villanneau, Richard ^a   Villain, Françoise ^a,c   Chamoreau, Lise Marie ^a   Boubekeur, Kamal ^a   Blanchard, Sebastien ^a   Thouvenot, René ^a   Proust, Anna ^a,b  

^a CNRS   (France)

^b l'Institut Universitaire de   (France)

^c SYNCHROTRON SOLEIL   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROPHILIC REACTIVITY; OXIDATION STATE; PHOSPHORANIMINATO DERIVATIVES; RUTHENIUM-NITRIDO POM DERIVATIVE;

DERIVATIVES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; PARAMAGNETIC RESONANCE; REACTION KINETICS; SYNTHESIS (CHEMICAL); X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

RUTHENIUM COMPOUNDS;

BIS(TRIPHENYLPHOSPHANE)IMINIUM; PHOSPHINE DERIVATIVE; RUTHENIUM COMPLEX; TRIPHENYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTROPHILIC STRESS; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 34250223061     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja071137t     Document Type: Article

References (74)

1. Pope, M. T. Heteropoly and Isopoly Oxometalates; Springer-Verlag: New York, 1983.
2. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications; Pope, M. T.; Müller, A., Eds., Kluwer Academic Publishers: Dordrecht, 2001.
3. Yamase, T.; Pope, M. T., Eds. Polyoxometalate Chemistry for Nano-composite Design. In Nanostructure Science and Technology; Lockwood, D. J., Ed.; Kluwer Academic Publishers: New York, 2002; vol. 2.
4. Polyoxometalate Molecular Science; Borras-Almenar, J. J.; Coronado, E.; Müller, A.; Pope, M. T., Eds.; Kluwer Academic Publishers: Dordrecht, 2003.
5. Hill, C. L.; Brown, R. B. J. Am. Chem. Soc. 1986, 108, 536-538.
6. Weinstock, I. A.; Barbuzzi, E. M. G.; Wemple, M. W.; Cowan, J. J.; Reiner, R. S.; Sonnen, D. M.; Heintz, R. A.; Bond, J. S.; Hill, C. L. Nature 2001, 414, 191-195.
7. Okun, N. M.; Tarr, J. C.; Hilleshiem, D. A.; Zhang, L.; Hardcastle, K. I.; Hill, C. L. J. Mol. Catal. A 2006, 246, 11-17.
8. Piepgrass, K.; Pope, M. T. J. Am. Chem. Soc. 1987, 109, 1586-1587.
9. Neumann, R.; Abu-Gnim, C. J. Chem. Soc. Chem. Commun. 1989, 1324-1325.
10. Khenkin, A. M.; Kumar, D.; Shaik, S.; Neumann, R. J. Am. Chem. Soc. 2006, 128, 15451-15460.
11. Lyon, D. K.; Miller, W. K.; Novet, T.; Domaille, P. J.; Evitt, E.; Johnson, D. C.; Finke, R. G. J. Am. Chem. Soc. 1991, 113, 7209-7221.
12. Nishiyama, Y.; Nakagawa, Y.; Mizuno, N. Angew. Chem., Int. Ed. 2001, 40, 3639-3641.
13. Botar, B.; Geletii, Y. V.; Kogerler, P.; Musaev, D. G.; Morokuma, K.; Weinstock, I. A.; Hill, C. L. J. Am. Chem. Soc. 2006, 128, 11268-11277.
14. Bonchio, M.; Carraro, M.; Sartorel, A.; Scorrano, G.; Kortz, U. J. Mol. Catal. A 2006, 251, 93-99.
15. Hill, C. L.; Prosser-McCartha, C. M. Coord. Chem. Rev. 1995, 143, 407-455.
16. Mizuno, N.; Misono, M. Chem. Rev. 1998, 98, 199-218.
17. Rong, C.; Pope, M. T. J. Am. Chem. Soc. 1992, 114, 2932-2938.
18. Neumann, R.; Khenkin, A. M.; Dahan, M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1587-1589.
19. Neumann, R.; Dahan, M. Nature 1997, 388, 353-355.
20. Anderson, T. M.; Neiwert, W. A.; Kirk, M. L.; Piccoli, P. M. B.; Schultz, A. J.; Koetzle, T. F.; Musaev, D. G.; Morokuma, K.; Cao, R.; Hill, C. L. Science 2004, 306, 2074-2077.
21. Anderson, T. M.; Cao, R.; Slonkina, E.; Hedman, B.; Hodgson, K. O.; Hardcastle, K. I.; Neiwert, W. A.; Wu, S. X.; Kirk, M. L.; Knottenbelt, S.; Depperman, E. C.; Keita, B.; Nadjo, L.; Musaev, D. G.; Morokuma, K.; Hill, C. L. J. Am. Chem. Soc. 2005, 127, 11948-11949.
22. Visser, S. P.; Kumar, D.; Neumann, R.; Shaikh, S. Angew. Chem., Int. Ed. 2004, 43, 5661-5665.
23. Proust, A.; Thouvenot, R.; Robert, F.; Gouzerh, P. Inorg. Chem. 1993, 32, 5299-5304.
24. Proust, A.; Thouvenot, R.; Chaussade, M.; Robert, F.; Gouzerh, P. Inorg. Chim. Acta 1994, 224, 81-95.
25. Bustos, C.; Hasenknopf, B.; Thouvenot, R.; Vaissermann, J.; Proust, A.; Gouzerh, P. Eur. J. Inorg. Chem. 2003, 2757-2766.
26. Dablemont, C.; Proust, A.; Thouvenot, R.; Afonso, C.; Fournier, F.; Tabet, J. C. Inorg. Chem. 2004, 43, 3514-3520.
27. Dablemont, C.; Proust, A.; Thouvenot, R.; Afonso, C.; Fournier, F.; Tabet, J. C. Dalton Trans. 2005, 1831-1841.
28. Kang, H.; Zubieta, J. J. Chem. Soc., Chem. Commun. 1988, 1192-1193.
29. Abrams, M. J.; Costello, C. E.; Shaikh, S. N.; Zubieta, J. Inorg. Chim. Acta 1991, 180, 9-11.
30. Kwen, H.; Tomlinson, S.; Maatta, E. A.; Dablemont, C.; Thouvenot, R.; Proust, A.; Gouzerh, P. Chem. Commun. 2002, 2970-2971.
31. Dablemont, C.; Hamaker, C. G.; Thouvenot, R.; Sojka, Z.; Che, M.; Maatta, E. A.; Proust, A. Chem. Eur J. 2006, 12, 9150-9160.
32. Man, W.-L.; Lam, W. W. Y.; Yiu, S.-M.; Lau, T.-C.; Peng, S.-M. J. Am. Chem. Soc. 2004, 126, 15336-15337.
33. Leung, S. K.-Y.; Huang, J.-S.; Liang, J.-L.; Che, C.-M.; Zhou, Z.-Y. Angew. Chem., Int. Ed. 2003, 42, 340-343.
34. Artero, V.; Laurencin, D.; Villanneau, R.; Thouvenot, R.; Herson, P.; Gouzerh, P.; Proust, A. Inorg. Chem. 2005, 44, 2826-2835.
35. -1.
36. Chan, P.-M.; Yu, W.-Y.; Che, C.-M.; Cheung, K.-K. J. Chem. Soc. Dalton Trans. 1998, 3183-3190.
37. Rocchiccioli-Deltcheff, C.; Thouvenot, R. J. Chem. Res. (S) 1977, 46-47.
38. Rocchiccioli-Deltcheff, C.; Thouvenot, R. J. Chem. Res. (M) 1977, 549-571.
39. Peacock, R. D.; Weakley, T. J. R. J. Chem. Soc. (A) 1971, 1937.
40. Griffith, W. P.; Pawson, D. J. Chem. Soc., Dalton Trans. 1973, 5, 1315-1320.
41. Brevard, C.; Schimpf, R.; Tourné, G.; Tourné, C. M. J. Am. Chem. Soc. 1983, 105, 7059-7063.
42. Domaille, P. J. J. Am. Chem. Soc. 1984, 106, 7677-7687.
43. Proust, A.; Fournier, M.; Thouvenot, R.; Gouzerh, P. Inorg. Chim. Acta 1994, 215, 61-66.
44. Bagno, A.; Bonchio, M.; Sartorel, A.; Scorrano, G. Eur. J. Inorg. Chem. 2000, 17-20.
45. Agustin, D.; Dallery, J.; Coelho, C.; Proust, A.; Thouvenot, R. J. Organomet. Chem. 2007, 692, 746-754.
46. 7- (see ref 44).
47. Cadot, E.; Thouvenot, R.; Tezé, A.; Hervé, G. Inorg. Chem. 1992, 31, 4128-4133.
48. It should be noted however that because of different temperature coefficients, at a higher temperature, specifically 333 K (60°C), W5≡W8 becomes the most shielded.
49. 4] as a reference compound because the nature of its coordinated atoms, N and O, rather than Cl, are closer to the nature of the coordination sphere in TBA-1.
50. Benzekri, A.; Cartier dit Moulin, C.; Latour, J.-M.; Limosin, D.; Rey, P.; Verdaguer, M. Inorg. Chim. Acta 1996, 252/1-2, 413-420.
51. Okamoto, K.; Miyawaki, J.; Nagai, K.; Matsumura, D.; Nojima, A.; Yokoyama, T.; Kondoh, H.; Ohta, T. Inorg. Chem. 2003, 42, 8682-8689.
52. Niewa, R.; Hu, Z.; Kniep, R. Eur. J. Inorg. Chem. 2003, 1632-1634.
53. Laplaza, C. E.; Johnson, M. J. A.; Peters, J. C.; Odom, A. L.; Kim, E.; Cummins, C. C.; George, G. N.; Pickering, I. J. J. Am. Chem. Soc. 1996, 118, 8623-8638.
54. Fan, L.; Xu, L.; Gao, G.; Li, F.; Li, Z.; Qiu, Y. Inorg. Chem. Commun. 2006, 9, 1308-1311.
55. Sadakane, M.; Tsukuma, D.; Dickman, M. H.; Bassil, B.; Kortz, U.; Higashijima, M.; Ueda, W. Dalton Trans. 2006, 4271-4276.
56. Eikey, R. A.; Abu-Omar, M.-M. Coord. Chem. Rev. 2003, 243, 83-124.
57. Demadis, K. D.; Bakir, M.; Klesczewski, B. G.; Williams, D. S.; White, P. S.; Meyer, T. J. Inorg. Chim. Acta 1998, 270, 511-526.
58. Fang, G.-S.; Huang, J.-S.; Zhu, N.; Che, C.-M. Eur. J. Inorg. Chem. 2004, 1341-1348.
59. Following a question from one of the reviewers, we can exclude the concomitant reduction of the polyanion, on the basis of optical features: one-electron-reduced polyoxotungstates are deep blue because of the intervalence charge transfer W(V)-W(VI) (see for example, Livage, J.; Launay, J.-P. et al. J. Am. Chem. Soc. 1983, 105, 6817-6823), at variance with compound 2, which is orange with an electronic absorption at 442 nm (log ε = 3.7, see Experimental Section).
60. Neumann, R.; Abu-Gnim, C. J. Am. Chem. Soc. 1990, 112, 6025-6031.
61. Dengel, A. C.; Griffith, W. P.; O'Mahoney, C. A.; Williams, D. J. J. Chem. Soc., Chem. Commun. 1989, 1720-1721.
62. Dengel, A. C.; Griffith, W. P. Inorg. Chem. 1991, 30, 869-871.
63. Kuan, S. L.; Tay, E. P. L.; Leong, W. K.; Goh, L. Y.; Lin, C. Y.; Gill, P. M. W.; Webster, R. D. Organometallics 2006, 6134-6141.
64. Fackler, N. P. L.; Zhang, S.; O'Halloran, T. V. J. Am. Chem. Soc. 1996, 118, 481-482.
65. Taylor, C. P. S. Biochim. Biophys. Acta 1977, 491, 137-149.
66. Meyer, T. J.; Huynh, M. H. V. Inorg. Chem. 2003, 42, 8140-8160.
67. Yip, K.-L.; Yu, W.-Y.; Chan, P.-M.; Zhu, N.-Y.; Che, C.-M. Dalton Trans. 2003, 3556-3566.
68. Mendiratta, A.; Cummins, C. C.; Kryatova, O. P.; Rybak-Akimova, E. V.; McDonough, J. E.; Hoff, C. D. J. Am. Chem. Soc. 2006, 128, 4881-4891.
69. Acerete, R.; Hammer, C. F.; Baker, L. C. W. J. Am. Chem. Soc. 1979, 101, 267-269.
70. Michalowitcz, A. EXAFS version 1998 for Mac OS9, http://www.univ-paris12. fr/40615508/0/fiche_3000A_pagelibre/.
71. Lengeler, B.; Eisenberg, P. Phys. Rev. B 1980, 21, 4507.
72. Michalowitcz, A. RoundMidnight, http://www.univ-paris12.fr/40615508/0/ fiche_3000A_pagelibre/.
73. Zabinsky, S. I.; Rehr, J. J.; Ankudinov, J. J.; Albers, R. C.; Eller, M. J. Phys. Rev. B 1995, 52, 2995-3009.
74. Souchay, P. Polyanions et polycations; Gauthier-Villars: Paris, 1963.