Structure and valency of a cobalt-phosphate water oxidation catalyst determined by in situ X-ray spectroscopy

Journal of the American Chemical Society

Volumn 132, Issue 39, 2010, Pages 13692-13701

  Kanan, Matthew W ^a,c   Yano, Junko ^b   Surendranath, Yogesh ^a   Dincǎ, Mircea ^a   Yachandra, Vittal K ^b   Nocera, Daniel G ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

^c STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

APPLIED POTENTIALS; AQUEOUS SOLUTIONS; CLUSTER SIZES; CO-OXIDES; COBALTATES; EDGE ENERGY; EDGE SHARING; ELECTROCHEMICAL DATA; EXAFS; EXAFS DATA; EXTENDED X-RAY ABSORPTION FINE STRUCTURE SPECTRUM; IN-SITU; MOLECULAR DIMENSIONS; NEGATIVE SHIFT; NUCLEARITY; OPEN CIRCUITS; PI FILM; RATE OF REDUCTION; RESIDUAL WATERS; STRUCTURAL MOTIFS; STRUCTURAL PARAMETER; VALENCIES; WATER OXIDATION; X-RAY ABSORPTION NEAR-EDGE STRUCTURE;

ABSORPTION SPECTRA; ABSORPTION SPECTROSCOPY; CATALYSIS; CATALYSTS; COBALT; OXIDATION; REDUCTION; SOLUTIONS; THICK FILMS; WATER ABSORPTION; X RAY ABSORPTION; X RAY SPECTROSCOPY; X RAYS;

COBALT COMPOUNDS;

COBALT; PHOSPHATE; WATER;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENERGY CONVERSION; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; FILM; OXIDATION; ROENTGEN SPECTROSCOPY; X RAY ABSORPTION NEAR EDGE SPECTROSCOPY; X RAY POWDER DIFFRACTION;

CATALYSIS; COBALT; ELECTROCHEMISTRY; MEMBRANES, ARTIFICIAL; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PHOSPHATES; SURFACE PROPERTIES; WATER; X-RAY ABSORPTION SPECTROSCOPY;

EID: 77957302625     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja1023767     Document Type: Article

References (48)

1. Nocera, D. G. Inorg. Chem. 2009, 48, 10001-10007
2. Lewis, N. S. and Nocera, D. G. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 15729-15735
3. Grimes, C. A., Varghese, O. K., and Ranjan, S. In Light, Water, Hydrogen; Springer: New York, 2008.
4. Turner, J., Sverdrup, G., Mann, M. K., Maness, P., Kroposki, B., Ghirardi, M., Evans, R. J., and Blake, D. Int. J. Energy Res. 2008, 32, 379-407
5. Licht, S., Wang, B., Mukerji, S., Soga, T., Umeno, M., and Tributsch, H. Int. J. Hydrogen Energy 2001, 26, 653-659
6. Osterloh, F. E. Chem. Mater. 2008, 20, 35-54
7. Weber, M. F. and Dignam, M. J. J. Electrochem. Soc. 1984, 131, 1258-1265
8. Bard, A. J. and Fox, M. A. Acc. Chem. Res. 1995, 28, 141-145
9. Khaselev, O. and Turner, J. A. Science 1998, 280, 425-427
10. Brillet, J., Cornuz, M., Le Formal, F., Yum, J., Grätzel, M., and Sivula, K. J. Mater. Res. 2010, 25, 17-24
11. Trasatti, S. In Electrochemistry of Novel Materials; Lipkowski, J. and Ross, P. N., Eds.; VCH: New York, 1994.
12. Tarasevich, M. R. and Efremov, B. N. In Electrodes of Conductive Metal Oxides; Elsevier: Amsterdam, 1980.
13. Trasatti, S. Electrochim. Acta 1984, 29, 1503-1512
14. Singh, R. N., Pandey, J. P., Singh, N. K., Lal, B., Chartier, P., and Koenig, J. F. Electrochim. Acta 2000, 45, 1911-1919
15. Di Blasi, A., D'Urso, C., Baglio, V., Antonucci, V., Arico, A. S., Ornelas, R., Matteucci, F., Orozco, G., Beltran, D., Meas, Y., and Arriaga, L. G. J. Appl. Electrochem. 2009, 39, 191-196
16. Marshall, A., Borresen, B., Hagen, G., Tsypkin, M., and Tunold, R. Energy 2007, 32, 431-436
17. Gibson, T. L. and Kelly, N. A. Int. J. Hydrogen Energy 2008, 33, 5931-5940
18. Kanan, M. W. and Nocera, D. G. Science 2008, 321, 1072-1075
19. Lutterman, D. A., Surendranath, Y., and Nocera, D. G. J. Am. Chem. Soc. 2009, 131, 3838-3839
20. Zhong, D. K. and Gamelin, D. R. J. Am. Chem. Soc. 2010, 132, 4202-4207
21. Kanan, M. W., Surendranath, Y., and Nocera, D. G. Chem. Soc. Rev. 2009, 38, 109-114
22. Zhong, D. K., Sun, J., Inumaru, H., and Gamelin, D. R. J. Am. Chem. Soc. 2009, 131, 6086-6087
23. Steinmiller, E. M. P. and Choi, K. Proc. Natl. Acad. Sci. U.S.A. 2009, 106, 20633-20636
24. Surendranath, Y., Dinca?, M., and Nocera, D. G. J. Am. Chem. Soc. 2009, 131, 2615-2620
25. Risch, M., Khare, V., Zaharieva, I., Gerencser, L., Chernev, P., and Dau, H. J. Am. Chem. Soc. 2009, 131, 6936-6937
26. Amatucci, G. G., Tarascon, J. M., Larcher, D., and Klein, L. C. Solid State Ionics 1996, 84, 169-180
27. Newville, M. J. Synchrotron Rad. 2001, 8, 322-324
28. Rehr, J. J. and Albers, R. C. Rev. Mod. Phys. 2000, 72, 621-654
29. McAlpin, J. G., Surendranath, Y., Dinca?, M., Stich, T. A., Stoian, S. A., Casey, W. H., Nocera, D. G., and Britt, R. D. J. Am. Chem. Soc. 2010, 132, 6882-6883
30. Delaplane, R. G., Ibers, J. A., Ferraro, J. R., and Rush, J. J. J. Chem. Phys. 1969, 50, 1920-1928
31. Ama, T., Rashid, M. M., Yonemura, T., Kawaguchi, H., and Yasui, T. Coord. Chem. Rev. 2000, 198, 101-116
32. Poltavets, V. V., Croft, M., and Greenblatt, M. Phys. Rev. B: Condens. Mater. Phys. 2006, 74 125103/1-8
33. Chakrabarty, R., Bora, S. J., and Das, B. K. Inorg. Chem. 2007, 46, 9450-9462
34. Dimitrou, K., Brown, A. D., Concolino, T. E., Rheingold, A. L., and Christou, G. Chem. Commun. 2001, 1284-1285
35. Dimitrou, K., Folting, K., Streib, W. E., and Christou, G. J. Am. Chem. Soc. 1993, 115, 6432-6433
36. Beattie, J. K., Hambley, T. W., Klepetko, J. A., Masters, A. F., and Turner, P. Polyhedron 1998, 17, 1343-1354
37. Chakrabarty, R., Sarmah, P., Saha, B., Chakravorty, S., and Das, B. K. Inorg. Chem. 2009, 48, 6371-6379
38. Yin, Q., Tan, J. M., Besson, C., Geletti, Y. V., Musaev, D. G., Kuznetsov, A. E., Luo, Z., Hardcastle, K. I., and Hill, C. L. Science 2010, 328, 342-345
39. Chivot, J., Mendoza, L., Mansour, C., Pauporté, T., and Cassir, M. Corros. Sci. 2008, 50, 62-69
40. McClintock, L. F. and Blackman, A. G. Chem. Asian J. 2010, 5, 756-758
41. Brunschwig, B. S., Chou, M. H., Creutz, C., Ghosh, P., and Sutin, N. J. Am. Chem. Soc. 1983, 105, 4832-4833
42. Takada, K., Fukuda, K., Osada, M., Nakai, I., Izumi, F., Dilanian, R. A., Kato, K., Takata, M., Sakurai, H., Takayama-Muromachi, E., and Sasaki, T. J. Mater. Chem. 2004, 14, 1448-1453
43. Sakurai, H., Tsujii, N., Suzuki, O., Kitazawa, H., Kido, G., Takada, K., Sasaki, T., and Takayama-Muromachi, E. Phys. Rev. B: Condens. Mater. Phys. 2006, 74 092502/1-4
44. Sakurai, H., Osada, M., and Takayama-Muromachi, E. Chem. Mater. 2007, 19, 6073-6076
45. Ren, Z., Luo, J., Xu, Z., and Cao, G. Chem. Mater. 2007, 19, 4432-4435
46. Chen, Y.-J., Liu, C.-J., Wang, J.-S., Lin, J.-Y., Sun, C. P., Huang, S. W., Lee, J. M., Chen, J. M., Lee, J. F., Liu, D. G., and Yang, H. D. Phys. Rev. B: Condens. Mater. Phys. 2007, 76 092501/1-4
47. Gayathri, N., Bharathi, A., Sastry, V. S., Sundar, C. S., and Hariharan, Y. Solid State Commun. 2006, 138, 489-493
48. Strobel, P., Muguerra, H., Hebert, S., Pachoud, E., Colin, C., and Julien, M. J. Solid State Chem. 2009, 182, 1872-1878