Mechanistic studies of reactions of peroxodiiron(III) intermediates in T201 variants of toluene/ o-xylene monooxygenase hydroxylase

Biochemistry

Volumn 50, Issue 23, 2011, Pages 5391-5399

  Song, Woon Ju ^a   Lippard, Stephen J ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; COMPUTATIONAL STUDIES; DECAY RATE; DIOXYGEN ACTIVATION; HYDROXYLASES; KINETIC STUDY; MECHANISTIC STUDIES; MONOOXYGENASES; O-XYLENE; REACTION MECHANISM; REACTION MODEL; SINGLE MUTATION; SITE DIRECTED MUTAGENESIS; SSBAUER SPECTROSCOPIES; TRYPTOPHAN RESIDUES;

AMINO ACIDS; DECAY (ORGANIC); KINETICS; MOLYBDENUM; PHENOLS; REACTION KINETICS; XYLENE;

REACTION INTERMEDIATES;

IRON DERIVATIVE; ISOTOPE; O XYLENE MONOOXYGENASE HYDROXYLASE; ORTHO XYLENE; OXYGENASE; PEROXODIIRON; PHENOL; POLYCYCLIC AROMATIC HYDROCARBON; TOLUENE; TRYPTOPHAN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; ENZYME ACTIVE SITE; ENZYME KINETICS; MUTATION; OXIDATION; PRIORITY JOURNAL; SITE DIRECTED MUTAGENESIS; SPECTROSCOPY; ULTRAVIOLET RADIATION;

FERRIC COMPOUNDS; IRON; KINETICS; MUTAGENESIS, SITE-DIRECTED; OXIDATION-REDUCTION; OXYGENASES; PHENOL; TRYPTOPHAN; XYLENES;

EID: 79958831691     PISSN: 00062960     EISSN: 15204995     Source Type: Journal    
DOI: 10.1021/bi200340f     Document Type: Article

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