Hydroxylation of methane by non-heme diiron enzymes: Molecular orbital analysis of C-H bond activation by reactive intermediate Q

Journal of the American Chemical Society

Volumn 124, Issue 49, 2002, Pages 14608-14615

  Baik, Mu Hyun ^a   Gherman, Benjamin F ^a   Friesner, Richard A ^a   Lippard, Stephen J ^b  

^a Columbia University ^*  (United States)

^b MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERROMAGNETISM; CARBON; ELECTRONIC STRUCTURE; ENZYMES; HYDROGEN; HYDROXYLATION; PROTONS;

ELECTRON TRANSFER PROCESS;

METHANE;

CARBON; HEME; HYDROGEN; METHANE; METHANE MONOOXYGENASE; OXYGENASE;

ARTICLE; ATOM; CHEMICAL STRUCTURE; DERIVATIZATION; ELECTRON TRANSPORT; ELECTRONICS; HYDROGEN BOND; HYDROXYLATION; MAGNETISM; MOLECULAR DYNAMICS; OXIDATION REDUCTION REACTION; PROTON TRANSPORT; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; SOLUBILITY;

ELECTRONS; HYDROXYLATION; IRON; METALLOPROTEINS; METHANE; MODELS, MOLECULAR; OXYGENASES; SOLUBILITY;

EID: 0037065357     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja026794u     Document Type: Article

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