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8], inhibiting further oxidative addition of PhSCN to the catalyst.
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97
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79951970018
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4] (10mol%) in benzene, Z to E isomerization occurred to give 3a with the E/Z ratio of 59/41.
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98
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79951962148
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2 adduct to 1-octyne
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2 adduct to 1-octyne.
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99
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79951998341
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note
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2] for hydroselenation of alkynes: See, Ref. 4m.
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79951967033
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note
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Recent theoretical studies for the palladium-catalyzed cyanothiolation suggest the following: i) Oxidative addition takes place between the SCN bond in preference to the CSCN bond; ii) Alkyne insertion takes place between the SPd bond in preference to the PdCN bond; iii) Thiopalladation takes place to introduce the thio group into the inner position of alkyne not the terminal position.
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