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2 was ineffective (the yield of 6a was 17%).
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54
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0000144122
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4 easily proceeds even at room temperature, see: (a) Zanella, R.; Ros, R.; Graziani, M. Inorg. Chem. 1973, 12, 2736. (b) Rauchfuss, T. B.; Shu, J. S.; Roundhill, D. M. Inorg. Chem. 1976, 15, 2096.
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4 easily proceeds even at room temperature, see: (a) Zanella, R.; Ros, R.; Graziani, M. Inorg. Chem. 1973, 12, 2736. (b) Rauchfuss, T. B.; Shu, J. S.; Roundhill, D. M. Inorg. Chem. 1976, 15, 2096.
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4 (0.02 mmol) under Pressure of CO (60 atm) at 80 °C for 39 h gave (Z)-1,3-bis(phenylthio)-2-nonen-1-one stereoselectively in 84% yield; see ref 5i.
-
-
-
-
57
-
-
85034475599
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-
note
-
1H NMR spectrometer, probably because five-membered cyclization proceeded very smoothly, compared with the six-membered cyclization.
-
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-
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58
-
-
85034466100
-
-
note
-
2 to 1-octyne under similar reaction conditions (100 °C, 50 h) gave 1,3-bis(phenylseleno)-2-nonen-1-one in 57% yield (E/Z = 1/99) with the concomitant formation of some identified materials.
-
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59
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37049082216
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Townsend, C.A.1
Christensen, S.B.2
Davis, S.G.3
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