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Volumn 6, Issue 4, 2004, Pages 601-603

Disulfidation of Alkynes and Alkenes with Gallium Trichloride

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; GALLIUM; GALLIUM TRICHLORIDE; UNCLASSIFIED DRUG;

EID: 1342290245     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol036391e     Document Type: Article
Times cited : (113)

References (36)
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    • 3 yielded 3a in 40% yield
    • 3 yielded 3a in 40% yield.
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    • 3-catalyzed trans addition of disulfides to alkenes was reported. However, disulfidation of alkynes gave a mixture of E/Z isomers in low yield. See: Caserio, M. C.; Fisher, C. L.; Kim, J. K. J. Org. Chem. 1985, 50, 4390.
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    • Disulfide-thiol exchange reaction was reported
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    • The reaction of thiirenium ion with diphenyl disulfide to afford (E)-1,2-diphenylthio-alkene selectively in low yield was reported. See: (a) Benati, L.; Montevecchi, P. C. Gazz. Chim. Ital. 1991, 121, 387. (b) Benati, L. ; Montevecchi, P. C. Gazz. Chim. Ital. 1989, 119, 609.
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    • The reaction of thiirenium ion with diphenyl disulfide to afford (E)-1,2-diphenylthio-alkene selectively in low yield was reported. See: (a) Benati, L.; Montevecchi, P. C. Gazz. Chim. Ital. 1991, 121, 387. (b) Benati, L. ; Montevecchi, P. C. Gazz. Chim. Ital. 1989, 119, 609.
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