Highly regioselective hydrothiocarboxylation of acetylenes with carbon monoxide and thiols catalyzed by Pt(PPh3)4

Journal of the American Chemical Society

Volumn 119, Issue 50, 1997, Pages 12380-12381

  Ogawa, Akiya ^a   Kawakami, Jun Ichi ^a   Mihara, Masatoshi ^a   Ikeda, Takuma ^a   Sonoda, Noboru ^b   Hirao, Toshikazu ^a  

^a OSAKA UNIVERSITY   (Japan)

^b KANSAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 85047285903     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja9726973     Document Type: Letter

References (50)

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49. The general procedure for the hydrothiocarboxylation of acetylenes with thiols and carbon monoxide is as follows: In a 50 mL stainless steel autoclave with a magnetic stirring bar under argon atmosphere were placed Pt(PPh3)4 (3 mol%), acetonitrile (5 mL), acetylene (5 mmol), and cyclohexanethiol (5 mmol). Carbon monoxide was purged three times and then changed at 30 atm. The reaction was conducted with magnetic stirring for 2 h upon heating at 120 °C. After the carbon monoxide was purged, the resulting mixture was filtered through Celite and concentrated in vacuo. Purification of the product was carried out by MPLC (silica gel, 25-40 µm, length 310 mm, i.d. 25 mm, eluent hexane:Et2O) 4:1).
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