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69
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33847195269
-
-
The isomerization reaction may proceed under transition metal-catalyzed, radical, or photochemical conditions see refs 12, 14, 15
-
The isomerization reaction may proceed under transition metal-catalyzed, radical, or photochemical conditions (see refs 12, 14, 15).
-
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70
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Kamiya, I.; Nishinaka, E.; Ogawa, A. J. Org. Chem. 2005, 70, 696.
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33847231547
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The possibility of the 2 → 7, 8 isomerization will be elaborated later on the other alkynes
-
The possibility of the 2 → 7 + 8 isomerization will be elaborated later on the other alkynes.
-
-
-
-
73
-
-
33847179732
-
-
The selectivity of the addition reactions is reflected by the ratio of Markovnikov and anti-Markovnikov products 2, 3+4
-
The selectivity of the addition reactions is reflected by the ratio of Markovnikov and anti-Markovnikov products (2)/(3+4).
-
-
-
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74
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85013600812
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(a) Ananikov, V. P.; Kabeshov, M. A.; Beletskaya, I. P.; Khrustalev, V. N.; Antipin, M. Yu. Organometallics 2005, 24, 1275.
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Ananikov, V.P.1
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0037474822
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(b) Ananikov, V. P.; Beletskaya, I. P.; Aleksandrov, G. G.; Eremenko, I. L. Organometallics 2003, 22, 1414.
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Ananikov, V.P.1
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81
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0344443264
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(c) Ananikov, V. P.; Kabeshov, M. A.; Beletskaya, I. P.; Aleksandrov, G. G.; Eremenko, I. L. J. Organomet. Chem. 2003, 687, 451.
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Ananikov, V.P.1
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-
83
-
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33847230455
-
-
For a related discussion concerning the structure and formation of polynuclear transition metal arylselenolates see refs 21 and 22
-
For a related discussion concerning the structure and formation of polynuclear transition metal arylselenolates see refs 21 and 22.
-
-
-
-
84
-
-
33847232113
-
-
The particles obtained in other cases are far from round shaped (see Figure 1A-C).
-
The particles obtained in other cases are far from round shaped (see Figure 1A-C).
-
-
-
-
85
-
-
33847201049
-
-
2 is completely soluble in phenylacetylene (1h), while in 2-methyl-3-butyn-2-o1 (1a) the suspension was formed.
-
2 is completely soluble in phenylacetylene (1h), while in 2-methyl-3-butyn-2-o1 (1a) the suspension was formed.
-
-
-
-
86
-
-
33847183031
-
-
3J(H-H) coupling constant is 12-16 Hz for 3 and 7-11 Hz for 4.
-
3J(H-H) coupling constant is 12-16 Hz for 3 and 7-11 Hz for 4.
-
-
-
-
87
-
-
33847220251
-
-
Electronic effect and coordination of oxygen atom to Ni could also make some contribution to the relative stability of the intermediate complexes
-
Electronic effect and coordination of oxygen atom to Ni could also make some contribution to the relative stability of the intermediate complexes.
-
-
-
-
88
-
-
33847233170
-
-
The reaction pathway leading to the minor product 3 (for R′ = H) was omitted for simplicity.
-
The reaction pathway leading to the minor product 3 (for R′ = H) was omitted for simplicity.
-
-
-
-
89
-
-
33847237941
-
-
2: $2, $17, and $102, respectively (Aldrich Catalog, 2006).
-
2: $2, $17, and $102, respectively (Aldrich Catalog, 2006).
-
-
-
-
90
-
-
0000846336
-
-
Scott, L. T.; DeCicco, G. J.; Hyun, J. L.; Reinhardt, G. J. Am. Chem. Soc., 1985, 107, 6546.
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Scott, L.T.1
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91
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0041833717
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Chakraborti, A. K.; Sharma, L.; Gulhane, R.; Shivani. Tetrahedron 2003, 59, 7661.
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Chakraborti, A.K.1
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Shivani4
-
93
-
-
33847213770
-
-
NMR monitoring (or GC) is the easiest way to determine appropriate reaction time
-
NMR monitoring (or GC) is the easiest way to determine appropriate reaction time.
-
-
-
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