DFT study of the structure and reactivity of the terminal Pt(IV)-OxO complex bearing no electron-withdrawing ligands

Journal of the American Chemical Society

Volumn 132, Issue 42, 2010, Pages 14886-14900

  Efremenko, Irena ^a   Poverenov, Elena ^a   Martin, Jan M L ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE MOLECULES; ACETONE SOLUTION; ANCILLARY LIGANDS; CHEMICAL TRANSFORMATIONS; CO OXIDATION; COVALENT INTERACTIONS; DFT STUDY; DIAMAGNETIC STATE; DIHYDROGEN; ELECTRON DENSITIES; ELECTRON-WITHDRAWING LIGANDS; ELECTROPHILES; HYDROXO COMPLEXES; INTERMEDIATE FORMATION; METAL OXO COMPLEX; MICROSOLVATION; NMR CHEMICAL SHIFTS; OXO COMPLEXES; OXO LIGANDS; OXYGEN INSERTION; OXYGEN TRANSFER; REACTION MIXTURE; REACTION PATHWAYS; SOLVENT MOLECULES; THERMODYNAMIC DATA; WATER ACTIVATION;

ACETONE; COMPLEXATION; ELECTRONIC STRUCTURE; LIGANDS; OXIDATION; OXYGEN; PLATINUM; REACTION INTERMEDIATES; TRANSITION METALS;

PLATINUM COMPOUNDS;

CARBON MONOXIDE; LIGAND; METAL COMPLEX; PHOSPHORUS; PLATINUM COMPLEX;

ARTICLE; CHEMICAL BINDING; CHEMICAL COMPOSITION; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; OXIDATION; OXYGEN TRANSPORT; PROTON TRANSPORT; REACTION ANALYSIS; THERMODYNAMICS;

ELECTRONS; KINETICS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; OXIDATION-REDUCTION; OXYGEN; PLATINUM COMPOUNDS; SOLVENTS; THERMODYNAMICS;

EID: 78649739030     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja105197x     Document Type: Article

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