-
1
-
-
12044254150
-
-
(a) Glueck, D. S.; Wu, J.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1991, 113, 2041-2054.
-
(1991)
J. Am. Chem. Soc.
, vol.113
, pp. 2041-2054
-
-
Glueck, D.S.1
Wu, J.2
Hollander, F.J.3
Bergman, R.G.4
-
2
-
-
0001271691
-
-
(b) Andrews, M. A.; Gould, G. L.; Voss, E. J. Inorg. Chem. 1996, 35, 5740-5742.
-
(1996)
J. Inorg. Chem.
, vol.35
, pp. 5740-5742
-
-
Andrews, M.A.1
Gould, G.L.2
Voss, E.3
-
5
-
-
0037123214
-
-
(e) Melenkivitz, R.; Mindiola, D. J.; Hillhouse, G. L. J. Am. Chem. Soc. 2002, 124, 3846-3847.
-
(2002)
J. Am. Chem. Soc.
, vol.124
, pp. 3846-3847
-
-
Melenkivitz, R.1
Mindiola, D.J.2
Hillhouse, G.L.3
-
7
-
-
0037448905
-
-
(g) Thyagarajan, S.; Shay, D. T.; Incarvito, C. D.; Rheingold, A. L.; Theopold, K. H. J. Am. Chem. Soc. 2003, 125, 4440-4441.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 4440-4441
-
-
Thyagarajan, S.1
Shay, D.T.2
Incarvito, C.D.3
Rheingold, A.L.4
Theopold, K.H.5
-
8
-
-
3242749800
-
-
(h) MacBeth, C. E.; Thomas, J. C.; Betley, T. A.; Peters, J. C. Inorg. Chem. 2004, 43, 4645-4662.
-
(2004)
Inorg. Chem.
, vol.43
, pp. 4645-4662
-
-
MacBeth, C.E.1
Thomas, J.C.2
Betley, T.A.3
Peters, J.C.4
-
9
-
-
4644320677
-
-
and references cited therein
-
(i) Kogut, E.; Zeller, A.; Warren, T. H.; Strassner, T. J. Am. Chem. Soc. 2004, 126, 11984-11994 and references cited therein.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 11984-11994
-
-
Kogut, E.1
Zeller, A.2
Warren, T.H.3
Strassner, T.4
-
10
-
-
19944409309
-
-
Anderson, T. M.; Neiwert, W. A.; Kirk, M. L.; Piccoli, P. M. B.; Schultz, A. J.; Koetzle, T. F.; Musaev, D. G.; Morokuma, K.; Cao, R.; Hill, C. L. Science 2004, 306, 2074-2077.
-
(2004)
Science
, vol.306
, pp. 2074-2077
-
-
Anderson, T.M.1
Neiwert, W.A.2
Kirk, M.L.3
Piccoli, P.M.B.4
Schultz, A.J.5
Koetzle, T.F.6
Musaev, D.G.7
Morokuma, K.8
Cao, R.9
Hill, C.L.10
-
12
-
-
33845281614
-
-
(b) Holm, R. H. Chem. Rev. 1987, 87, 1401-1449.
-
(1987)
Chem. Rev.
, vol.87
, pp. 1401-1449
-
-
Holm, R.H.1
-
16
-
-
0024785757
-
-
(b) Spaltenstein, E.; Conry, R. R.; Critchlow, S. C.; Mayer, J. M. J. Am. Chem. Soc. 1989, 111, 8741-8742.
-
(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 8741-8742
-
-
Spaltenstein, E.1
Conry, R.R.2
Critchlow, S.C.3
Mayer, J.M.4
-
17
-
-
0037436143
-
-
(c) Rohde, J.-U.; In, J.-H.; Lim, M. H.; Brennessel, W. W.; Bukowski, M. R.; Stubna, A.; Münck, E.; Nam, W.; Que, L., Jr. Science 2003, 299, 1037-1039.
-
(2003)
Science
, vol.299
, pp. 1037-1039
-
-
Rohde, J.-U.1
In, J.-H.2
Lim, M.H.3
Brennessel, W.W.4
Bukowski, M.R.5
Stubna, A.6
Münck, E.7
Nam, W.8
Que Jr., L.9
-
18
-
-
1542289897
-
-
(d) MacBeth, C. E.; Gupta, R.; Mitchell-Koch, K. R.; Young, V. G., Jr.; Lushington, G. H.; Thompson, W. H.; Hendrich, M. P.; Borovik, A. S. J. Am. Chem. Soc. 2004, 126, 2556-2567.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 2556-2567
-
-
MacBeth, C.E.1
Gupta, R.2
Mitchell-Koch, K.R.3
Young Jr., V.G.4
Lushington, G.H.5
Thompson, W.H.6
Hendrich, M.P.7
Borovik, A.S.8
-
19
-
-
2942679678
-
-
(e) Green, M. T.; Dawson, J. H.; Gray, H. B. Science 2004, 304, 1653-1656.
-
(2004)
Science
, vol.304
, pp. 1653-1656
-
-
Green, M.T.1
Dawson, J.H.2
Gray, H.B.3
-
20
-
-
37049073529
-
-
3IrO, was the first late-transition-metal oxo complex. However, the antibonding Ir-O Orbitals are not populated due to the trigonal symmetry of this complex, cf. (a) Hay-Motherwell, R. S.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1992, 3477-3482.
-
(1992)
J. Chem. Soc., Dalton Trans.
, pp. 3477-3482
-
-
Hay-Motherwell, R.S.1
Wilkinson, G.2
Hussain-Bates, B.3
Hursthouse, M.B.4
-
21
-
-
0037047841
-
-
(b) Jacobi, B. G.; Laitar, D. S.; Pu, L.; Wargocki, M. F.; DiPasquale, A. G.; Fortner, K. C.; Schuck, S. M.; Brown, S. N. Inorg. Chem. 2002, 41, 4815-4823.
-
(2002)
Inorg. Chem.
, vol.41
, pp. 4815-4823
-
-
Jacobi, B.G.1
Laitar, D.S.2
Pu, L.3
Wargocki, M.F.4
Dipasquale, A.G.5
Fortner, K.C.6
Schuck, S.M.7
Brown, S.N.8
-
22
-
-
0041691427
-
-
(a) Artero, V.; Proust, A.; Villain, F.; Cartier dit Moulin, C.; Gouzerh, P. J. Am. Chem. Soc. 2003, 125, 11156-11157.
-
(2003)
J. Am. Chem. Soc.
, vol.125
, pp. 11156-11157
-
-
Artero, V.1
Proust, A.2
Villain, F.3
Cartier Dit Moulin, C.4
Gouzerh, P.5
-
23
-
-
8444244518
-
-
(b) de Visser, S. P.; Kumar, D.; Neumann, R.; Shaik, S. Angew. Chem., Int. Ed. 2004, 43, 5661-5665.
-
(2004)
Angew. Chem., Int. Ed.
, vol.43
, pp. 5661-5665
-
-
De Visser, S.P.1
Kumar, D.2
Neumann, R.3
Shaik, S.4
-
24
-
-
23744488515
-
-
and references therein
-
(c) Bi, L.-H.; Kortz, U.; Keita, B.; Nadjo, L.; Daniels, L. Eur. J. Inorg. Chem. 2005, 3034-3041 and references therein.
-
(2005)
Eur. J. Inorg. Chem.
, pp. 3034-3041
-
-
Bi, L.-H.1
Kortz, U.2
Keita, B.3
Nadjo, L.4
Daniels, L.5
-
27
-
-
0011717658
-
-
(c) Shelef, M. Chem. Rev. 1995, 95, 209-225.
-
(1995)
Chem. Rev.
, vol.95
, pp. 209-225
-
-
Shelef, M.1
-
30
-
-
33845375223
-
-
Knoth, W. H.; Domaille, P. J.; Harlow, R. L. Inorg. Chem. 1986, 25, 1577-1584.
-
(1986)
Inorg. Chem.
, vol.25
, pp. 1577-1584
-
-
Knoth, W.H.1
Domaille, P.J.2
Harlow, R.L.3
-
31
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33645586853
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note
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1/2 = 7 Hz). See the SI for electronic absorption data. Anal. Calcd for 2: K, 7.03; Na, 1.24; P, 1.11; Pd, 1.91; W. 62.8. Found (average): Cl, <0.01; K. 6.92; Na, 1.25; P, 1.15; Pd, 1.91; W, 62.6. [MW = 5565 g/mol].
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32
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33645594573
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note
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o (for the 173 K structure). The final R1 (GOF) values for the 90 K and the 30 K structures were 7.83% (1.026) and 5.80% (1.083), respectively, based on 19 071 reflections for the 90 K structure and 20 284 reflections for the 30 K structure. See Table S1 (in the SI) for more information.
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33
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33645592253
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note
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(a) There is crowding around the Pd=O unit from O69 (a terminal oxo (from W19) located 2.57 Å from O70) and K10 (a countercation located 2.35 Å from O70). See Figure S1 for the numbering scheme,
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34
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33645595355
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note
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- as the ligand trans to the oxo unit is provided by titration studies; see Figure S2 in the SI.
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35
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33645583814
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note
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pc = -0.28 V versus SCE). In addition, 2 also displays a larger current intensity (at equal concentrations) than Pd(II) alone. This is attributed to the larger number of electrons involved in its reduction (relative to Pd(II)). The number of electrons involved in the exhaustive reduction of the Pd center in 2 (at -0.45 V versus SCE) and in Pd(II) alone (at -0.32 V versus SCE) was determined by controlled potential coulometry and confirmed to be four and two, respectively.
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36
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33645592658
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note
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(a) Refinement of the oxo and hydroxo ligands of Pd at 50% occupancy could imply that there is a mixture of four-coordinate Pd(II) and six-coordinate Pd(IV), but all other data suggest the sample is chemically homogeneous,
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37
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33645604403
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note
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(b) A reviewer states: "Such extraordinary claims require extraordinary evidence." We concur.
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38
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0000751613
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Solomon, E. I., Lever, A. B. P., Eds.; Wiley & Sons: New York, and references therein
-
(a) Zhang, H. H.; Hedman, B.; Hodgson, K. O. In Inorganic Electronic Structure and Spectroscope; Solomon, E. I., Lever, A. B. P., Eds.; Wiley & Sons: New York, 1999; pp 513-554 and references therein. Data were measured at Stanford Synchrotron Radiation Laboratory beam line 10-2. See SI for details on data collection and analysis,
-
(1999)
Inorganic Electronic Structure and Spectroscope
, pp. 513-554
-
-
Zhang, H.H.1
Hedman, B.2
Hodgson, K.O.3
-
40
-
-
33845559212
-
-
(a) Filowitz, M.; Ho, R. K. C.; Klemperer, W. G.; Shum, W. Inorg. Chem. 1979, 18, 93-103.
-
(1979)
Inorg. Chem.
, vol.18
, pp. 93-103
-
-
Filowitz, M.1
Ho, R.K.C.2
Klemperer, W.G.3
Shum, W.4
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