Terminal chalcogenido complexes of the transition metals

Progress in Inorganic Chemistry

Volumn 47, Issue , 1998, Pages 1-165

  Parkin, Gerard ^a  

^a Teachers College   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001023778     PISSN: 00796379     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Article

References (615)

1. W. A. Nugent and J. M. Mayer, Metal-Ligand Multiple Bonds, Wiley-Interscience, New York, 1988.
2. For a more recent compilation covering certain aspects of metal-ligand multiple bonding, see: C.-M. Che, and V. W. W. Yam, Eds., Advances in Transition Metal Coordination Chemistry, JAI Press, Greenwich, CT, 1996, Vol. 1.
3. Polonium, which is radioactive, has been little studied in this context and will not be considered in this chapter.
4. (a) V. M. Goldschmidt, J. Chem. Soc. (London), 655 (1937).
5. (b) V. M. Goldschmidt, Naturwissenschaften, 18, 999 (1930).
6. (c) K. A. Jensen, Chem. Ind., 49, 2016 (1964).
7. G. J. Leigh, Ed., IUPAC Nomenclature of Inorganic Chemistry, Recomendations 1990; Blackwell, London 1990.
8. (a) J. P. Collman, L. S. Hegedus, J. R. Norton, and R. G. Finke, Principles and Applications of Organotransition Metal Chemistry; University Science Books, Mill Valley, CA, 1987.
9. (b) G. W. Parshall and S. D. Ittel, Homogeneous Catalysis, 2nd ed.; Wiley-Interscience: New York, 1992.
10. (c) C. L. Hill, Ed., Activation and Functionalization of Alkanes, Wiley-Interscience: New York, 1989.
11. (a) B. C. Gates, J. R. Katzer, and G. C. A. Schuit, Chemistry of Catalytic Processes, McGraw-Hill, New York, 1979, Chapter 5, pp. 390-445.
12. (b) J. G. Speight, The Desulfurization of Heavy Oils and Residua; Marcel-Dekker, New York, 1981.
13. (c) M. Rakowski DuBois, Chem. Rev., 89, 1 (1989).
14. (a) R. J. Angelici, Acc. Chem. Res., 21, 387 (1988).
15. (b) C. M. Friend, Acc. Chem. Res., 21, 394 (1988).
16. (c) B. C. Wiegand and C. M. Friend, Chem. Rev., 92, 491 (1992).
17. (d) R. A. Sánchez-Delgado, J. Mol. Catal., 86, 287 (1994).
18. (a) J. M. Thomas and K. I. Zamaraev, Angew. Chem., Int. Ed. Engl., 33, 308 (1994).
19. (b) V. N. Parmon, Z. R. Ismagilov, and M. A. Kerzhentsev, in Perspectives in Catalysis, J. M. Thomas, and K. I. Zamaraev, Eds., Blackwell Scientific Publications, Oxford, UK, 1992, pp. 337-357.
20. (c) D. O'Sullivan, Chem. Eng. News, 59 (30), 40 (1981).
21. (d) S. Li, and G. Lu, New J. Chem., 16, 517 (1992).
22. A. Müller, B. Krebs, Eds., Sulfur, its Significance for Chemistry, for the Geo-, Bio-, and Cosmophere and Technology, Elsevier Science Publishers, Amsterdam, The Netherlands, 1984, pp. 349-494.
23. (a) A. A. Eagle, L. J. Laughlin, C. G. Young, and E. R. T. Tielink, J. Am. Chem. Soc., 114, 9195 (1992) and references cited therein,
24. (b) J. P. Hill, L. J. Laughlin, R. W. Gable, and C. G. Young, Inorg. Chem., 35, 3447 (1996).
25. (b) G. L. Wilson, R. J. Greenwood, J. R. Pilbrow, J. T. Spence, and A. G. Wedd, J. Am. Chem. Soc., 113, 6803 (1991).
26. (a) J. Reedijk, Ed., Bioinorganic Catalysis, Marcel-Dekker, New York, 1993.
27. (b) K. D. Karlin, Science, 261, 701 (1993).
28. (c) J. J. R. Frausto da Silva, and R. J. P. Williams, The Biological Chemistry of the Elements, Clarendon Press: Oxford, UK, 1991.
29. (a) R. H. Holm, and J. M. Berg, Acc. Chem. Res., 19, 363 (1986).
30. (b) A. G. Wedd, Coord. Chem. Rev., 154, 5 (1996).
31. (a) E. I. Stiefel, Science, 272, 1599 (1996).
32. (b) J. H. Enemark, and C. G. Young, Adv. Inorg. Chem., 40, 1 (1993).
33. (c) M. A. Pietsch and M. B. Hall, Inorg. Chem., 35, 1273 (1996).
34. (a) A. A. Eagle, S. M. Harben, E. R. T. Tiekink, and C. G. Young, J. Am. Chem. Soc., 116, 9749 (1994).
35. (b) C. G. Young, T. O. Kocaba, X. F. Yan, E. R. T. Tiekink, L. Wei, H. H. Murray, III, C. L. Coyle, and E. I. Stiefel, Inorg. Chem., 33, 6252 (1994).
36. U. Siemeling, Angew. Chem. Int. Ed. Engl., 32, 67 (1993).
37. (a) P. O'Brien, Chemtronics, 5, 61 (1991).
38. (b) M. L. Steigerwald and L. E. Brus, Acc. Chem. Res., 23, 183 (1990).
39. (c) M. Bochmann and K. J. Webb, Mater. Res. Soc. Symp. Proc., 204, 149 (1991).
40. (d) R. H. Bube, Annu. Rev. Mater. Sci., 20, 19 (1990).
41. (e) T. Yokogawa, M. Ogura, and T. Kajiwara, Appl. Phys. Lett., 50, 1065 (1987).
42. (f) A. C. Jones, J. Cryst. Growth, 129, 728 (1993).
43. (g) G. N. Pain, G. I. Christiansz, R. S. Dickson, G. B. Deacon, B. O. West, K. McGregor, and R. S. Rowe, Polyhedron, 9, 921 (1990).
44. (h) M. L. Steigerwald, Mater. Res. Soc. Symp. Proc., 131, 37 (1989).
45. (a) M. L. Steigerwald, T. Siegrist, and S. M. Stuczynski, Inorg. Chem., 30, 4940 (1991).
46. (b) M. L. Steigerwald, T. Siegrist, S. M. Stuczynski, and Y.-U. Kwon, J. Am. Chem. Soc., 114, 3155 (1992).
47. (c) M. L. Steigerwald, Polyhedron, 13, 1245 (1994).
48. (d) J. Arnold, J. M. Walker, K.-M. Yu, P. J. Bonasia, A. L. Seligson, and E. D. Bourret, J. Cryst. Growth, 124, 647 (1992).
49. (e) A. L. Seligson, P. J. Bonasia, J. Arnold, K.-M. Yu, J. M. Walker, and E. D. Bourret, Mater. Res. Soc. Symp. Proc., 282, 665 (1993).
50. For a recent review of transition metal-imido chemistry, see D. E. Wigley, Progress in Inorganic Chemistry, Vol. 42, Wiley-Interscience, 1994, pp. 239-482.
51. M. Scheer, Angew. Chem. Int. Ed. Engl., 34, 1997 (1995).
52. J. B. Bonanno, P. T. Wolczanski, and E. B. Lobkovsky, J. Am. Chem. Soc., 116, 11159 (1994).
53. C. E. Laplaza, W. M. Davis, and C. C. Cummins, Angew. Chem. Int. Ed. Engl., 34, 2042 (1995).
54. N. C. Zanett, R. R. Schrock, and W. D. Davis, Angew. Chem. Int. Ed. Engl., 117, 2044 (1995).
55. -, however, have been generated in the gas phase. See F. P. Arnold, Jr., D. P. Ridge, and A. L. Rheingold, J. Am. Chem. Soc., 117, 4427 (1995).
56. (a) W. P. Griffith, Coord. Chem. Rev., 5, 459 (1970).
57. (b) R. H. Holm, Chem. Rev., 87, 1401 (1987).
58. (c) R. H. Holm and J. P. Donahue, Polyhedron, 12, 571 (1993).
59. (d) F. Bottomley and L. Sutin, Adv. Organomet. Chem., 28, 339 (1988).
60. (e) H. Arzoumanian, Bull. Soc. Chim. Belg., 100, 717 (1991).
61. (f) F. Bottomley, Polyhedron, 11, 1707 (1992).
62. (g) W. A. Hermann, E. Herdtweck, M. Flöel, J. Kulpe, U. Küsthardt, and J. Okuda, Polyhedron, 6, 1165 (1987).
63. (h) R. C. Mehrotra and A. Singh, Chem. Soc. Rev., 25, 1 (1996).
64. (a) D. A. Rice, Coord. Chem. Rev., 227, 199 (1978).
65. (b) H. Vahrenkamp, Angew. Chem. Int. Ed. Engl., 14, 322 (1975).
66. (c) A. Müller, E. Diemann, R. Jostes, and H. Bogge, Angew. Chem. Int. Ed. Engl., 20, 934 (1981).
67. (d) A. Müller, and E. Diemann, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 16.1.
68. (e) A. Müller, Polyhedron, 5, 323 (1986).
69. (f) P. Kelly, Chemistry in Britain, 25 (1997).
70. L. C. Roof and J. W. Kolis, Chem. Rev., 93, 1037 (1993).
71. (a) A. Müller, and E. Diemann, Adv. Inorg. Chem., 31, 89 (1987).
72. (d) J. Wachter, Angew. Chem. Int. Ed. Engl., 28, 1613 (1989).
73. (e) M. G. Kanatzidis, Comments Inorg. Chem., 10, 161 (1990).
74. (f) M. G. Kanatzidis, and S.-P. Huang, Coord. Chem. Rev., 130, 509 (1994).
75. (g) J. W. Kolis, Coord. Chem. Rev., 105, 195 (1990).
76. (h) P. Böttcher, Angew. Chem. Int. Ed. Engl., 27, 759 (1988).
77. (i) M. A. Ansari, J. M. McConnachie, and J. A. Ibers, Acc. Chem. Res., 26, 574 (1993).
78. (j) M. A. Ansari, and J. A. Ibers, Coord. Chem. Rev., 100, 223 (1990).
79. (k) J. Beck, Angew. Chem., Int. Ed. Engl., 33, 163 (1994).
80. (l) M. G. Kanatzidis, and A. C. Sutorik, Progress in Inorganic Chemistry, Wiley-Interscience, New York, 1995, Vol. 43, pp. 151-265.
81. (m) D. Fenske, J. Ohmer, J. Hachgenei, and K. Merzweiler, Angew. Chem. Int. Ed. Engl., 27, 1277 (1988).
82. (a) W. A. Hermann, Angew. Chem. Int. Ed. Engl., 25, 56 (1986).
83. (b) N. A. Compton, R. J. Errington, and N. C. Norman, Adv. Organomet. Chem., 31, 91 (1990).
84. (c) C. E. Housecraft, in Inorganometallic Chemistry, T. P. Fehlner, Ed., Plenum, New York, 1992; Chapter 3, pp. 73-178.
85. (d) D. Fenske, J. Ohmer, J. Hachgenei, and K. Merzweiler, Angew. Chem. Int. Ed. Engl., 27, 1277 (1988).
86. (e) I. Dance, and K. Fisher, Progress in Inorganic Chemistry, Wiley-Interscience, New York, 1994, Vol. 41, pp. 637-803.
87. For a review of the factors that influence the bond angles in bridging oxo and sulfido complexes, see F. Bottomley and S.-K. Goh, Polyhedron, 15, 3045 (1996).
88. T. M. Trnka, and G. Parkin, Polyhedron, 16, 1031 (1997).
89. (a) W. A. Howard, M. Waters, and G. Parkin, J. Am. Chem. Soc., 115, 4917 (1993).
90. (b) W. A. Howard, T. M. Trnka, M. Waters, and G. Parkin, J. Organomet. Chem., 528, 95 (1997).
91. J. Arnold, Progress in Inorganic Chemistry, Wiley-Interscience, New York, 1995, Vol. 43, pp. 353-417.
92. For example, approximately 300 complexes with transtion metal-tellurium bonds are listed in the present version of the Cambridge Structural Database.
93. For some leading articles on multiple bonding of the heavier main group elements, see (a) W. Kutzelnigg, Angew. Chem. Int. Ed. Engl., 23, 272 (1984).
94. (b) L. E. Gusel'nikov and N. S. Nametkin, Chem. Rev., 79, 529 (1979).
95. (c) P. Jutzi, Angew. Chem. Int. Ed. Engl., 14, 232 (1975).
96. (d) N. C. Norman, Polyhedron, 12, 2431 (1993).
97. (e) M. W. Schmidt, P. N. Truong, and M. S. Gordon, J. Am. Chem. Soc., 109, 5217 (1987).
98. (f) H. Jacobsen and T. Ziegler, J. Am. Chem. Soc., 116, 3667 (1994).
99. (g) J. E. Huheey, E. A. Keiter, and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, 4th ed., Harper Collins, New York, 1993, Chapter 18, pp. 861-875.
100. (h) H. Jacobsen and T. Ziegler, Comments Inorg. Chem., 17, 301 (1995).
101. (i) J. Kapp, P. von Ragué Schleyer, M. Remko, J. Am. Chem. Soc., 118, 5745 (1996).
102. (j) M. Dreiss, and H. Grützmacher, Angew. Chem. Int. Ed. Engl., 35, 828 (1996).
103. For example, the chemistry of the Si=Si double bond is substantially less developed than that of the C=C double bond. See (a) R. West, Angew. Chem. Int. Ed. Engl., 26, 1201 (1987).
104. (b) R. West, Pure Appl. Chem., 56, 163 (1984).
105. (c) T. Tsumuraya, S. A. Batcheller, and S. Masamune, Angew. Chem. Int. Ed. Engl., 30, 902 (1991).
106. R. S. Hay-Motherwell, G. Wilkinson, B. Hussain-Bates, and M. B. Hursthouse, Polyhedron, 12, 2009 (1993).
107. J. M. Mayer, Comments Inorg. Chem., 8, 125 (1988).
108. For further discussion of the influence of filled-filled repulsions in transition metal chemistry, see K. G. Caulton, New J. Chem., 18, 25 (1994).
109. J. M. Mayer, Inorg. Chem., 27, 3899 (1988).
110. Mayer has noted, however, that M=O bond lengths do increase slightly in the presence of a second multiply bonded ligand (e.g., oxo, nitrido, imido).
111. 4CrO, involving two normal π bonds and a dative O to Cr σ bond, see: A. K. Rappé and W. A. Goddard, III, J. Am. Chem. Soc., 104, 3287 (1982).
112. D. Rabinovich and G. Parkin, Inorg. Chem., 34, 6341 (1996).
113. (a) J. W. Lauher, and R. Hoffmann, J. Am. Chem. Soc., 98, 1729 (1976).
114. (b) Z. Lin, and M. B. Hall, Coord. Chem. Rev., 123, 149 (1993).
115. (a) N. D. Silavwe, M. R. M. Bruce, C. E. Philbin, and D. R. Tyler, Inorg. Chem., 27, 4669 (1988).
116. (b) A. J. Bridgeman, L. Davis, S. J. Dixon, J. C. Green, and I. N. Wright, J. Chem. Soc. Dalton Trans., 1023 (1995).
117. (c) J. M. Fischer, W. E. Piers, T. Ziegler, L. R. MacGillivray, and M. J. Zaworotko, Chem. Eur. J., 2, 1221 (1996).
118. For discussions on multiple bonding in related imido derivatives see (a) G. Parkin, A. van Asselt, D. J. Leahy, L. Whinnery, N. G. Hua, R. W. Quan, L. M. Henling, W. P. Schaefer, B. D. Santarsiero, and J. E. Bercaw, Inorg. Chem., 31, 82 (1992).
119. (b) D. M. Antonelli, W. P. Schaefer, G. Parkin, and J. E. Bercaw, J. Organomet. Chem., 462, 213 (1993).
120. (c) K. A. Jørgensen, Inorg. Chem., 32, 1521 (1993).
121. (d) J. T. Anhaus, T. P. Kee, M. H. Schofield, and R. R. Schrock, J. Am. Chem. Soc., 112, 1642 (1990).
122. (e) M. H. Schofield, T. P. Kee, J. T. Anhaus, R. R. Schrock, K. H. Johnson, and W. M. Davis, Inorg. Chem., 30, 3595 (1991).
123. (f) D. S. Glueck, J. C. Green, R. I. Michelman, and I. N. Wright, Organometallics, 11, 4221 (1992).
124. (g) J. C. Green, M. L. H. Green, J. T. James, P. C. Konidaris, G. H. Maunder, and P. Mountford, J. Chem. Soc. Chem. Commun., 1361 (1992).
125. (a) N. D. Silavwe, M. Y. Chiang, and D. R. Tyler, Inorg. Chem., 24, 4219 (1985).
126. (b) M. Yoon and D. R. Tyler, J. Chem. Soc. Chem. Commun. 639 (1997).
127. J. H. Shin, and G. Parkin, unpublished results.
128. J. M. Mayer, Inorg. Chem., 27, 3899 (1988).
129. W. A. Nugent and J. M. Mayer, Metal-Ligand Multiple Bonds, Wiley-Interscience, New York, 1988, p. 117.
130. (a) G. Parkin and J. E. Bercaw, J. Am. Chem. Soc., 111, 391 (1989).
131. (b) G. Parkin and J. E. Bercaw, Polyhedron, 7, 2053 (1988).
132. W. A. Nugent, R. J. McKinney, R. V. Kasowski, and F. A. Van-Catledge, Inorg. Chim. Acta, 65, L91 (1982).
133. J. H. Shin and G. Parkin, Organometallics, 14, 1104 (1995).
134. W. Howard and G. Parkin, J. Am. Chem. Soc., 116, 606 (1994).
135. See, for example, the empirical Schomaker-Stevcnson equation, d(A - B) = r(A) + r(B) - c|χ(A) - χ(B)|. (a) V. Schomaker and D. P. Stevenson, J. Am. Chem. Soc., 63, 37 (1941).
136. (b) A. F. Wells, J. Chem. Soc., 55 (1949).
137. (c) A. F. Wells, Structural inorganic Chemistry, 5th ed., Oxford University Press, London, 1984, pp. 287-291.
138. (a) M. T. Benson, T. R. Cundari, S. J. Lim, H. D. Nguyen, and K. Pierce-Beaver, J. Am. Chem. Soc., 116, 3955 (1994).
139. (b) M. T. Benson, T. R. Cundari, Y. Li, and L. A. Strohecker, Int. J. Quantum Chem.: Quantum Chem. Sym., 28, 181 (1994).
140. (c) M. S. Gordon and T. S. Cundari, Coord. Chem. Rev., 147, 87 (1996).
141. L. Deng and T. Ziegler, Organometallics, 15, 3011 (1996).
142. 2+ also exhibits a trans arrangement of oxo ligands (58a-d). (a) V. W. Day and J. L. Hoard, J. Am. Chem. Soc., 90, 3374 (1968).
143. (b) C. S. Johnson, C. Mottley, J. T. Hupp, and G. D. Danzer, Inorg. Chem., 31, 5143 (1992).
144. (c) J. C. Brewer, H. H. Thorp, K. M. Slagle, G. W. Brudvig, and H. B. Gray, J. Am. Chem. Soc., 113, 3171 (1991).
145. (d) J. R. Winkler, and H. B. Gray, Inorg. Chem., 24, 346 (1985).
146. W. P. Griffith and T. D. Wickins, J. Chem. Soc. (A), 400 (1968).
147. (a) D. M. P. Mingos, J. Organomet. Chem., 179, C29 (1979).
148. (b) D. C. Brower, J. L. Templeton, and D. M. P. Mingos, J. Am. Chem. Soc., 109, 5203 (1987).
149. (c) Z. Lin, and M. B. Hall, Coord. Chem. Rev., 123, 149 (1993).
150. (d) K. Tatsumi, and R. Hoffmann, Inorg. Chem., 19, 2656 (1980).
151. (e) I. Demachy, and Y. Jean, New J. Chem., 19, 763 (1995).
152. (f) I. Demachy, and Y. Jean, New J. Chem., 20, 53 (1996).
153. (g) I. Demachy, and Y. Jean, Inorg. Chem., 35, 5027 (1996).
154. For a recent review describing the electronic structures of metal-oxo complexes, see V. M. Miskowski, H. B. Gray, and M. D. Hopkins, Adv. Transition Metal Coordination Chem., 1, 159 (1996).
155. VI dioxo complexes, see R. J. Butcher, B. R. Penfold, and E. Sinn, J. Chem. Soc. Dalton Trans., 668 (1979).
156. W. P. Griffith, J. M. Jolliffe, S. V. Ley, and D. J. Williams, J. Chem. Soc. Chem. Commun., 1219 (1990).
157. R. L. Blackbourn, L. M. Jones, M. S. Ram, M. Sabat, and J. T. Hupp, Inorg. Chem., 29, 1791 (1990).
158. T. Behling, M. V. Capparelli, A. C. Skapski, and G. Wilkinson, Polyhedron, 1, 840 (1982).
159. J. C. Dobson, K. J. Takeuchi, D. W. Pipes, D. A. Geselowitz, and T. J. Meyer, Inorg. Chem., 25, 2357 (1986).
160. W.-C. Cheng, W.-Y. Yu, K.-K. Cheung, and C.-M. Che, J. Chem. Soc. Chem. Commun., 1063 (1994).
161. (a) W.-C. Cheng, W.-Y. Yu, C.-K. Li, and C.-M. Che, J. Org. Chem., 60, 6840 (1995).
162. (b) C.-K. Li, C.-M. Che, W.-F. Tong, W.-T. Tang, K.-Y. Wong, and T.-F. Lai, J. Chem. Soc. Dalton Trans., 2109 (1992).
163. (a) T. C. W. Mak, C.-M. Che, and K. Y. Wong, J. Chem. Soc. Chem. Commun., 986 (1985).
164. (b) C. M. Che, T. F. Lai, and K. Y. Wong, Inorg. Chem., 26, 2289 (1987).
165. (a) C. L. Bailey and R. S. Drago, J. Chem. Soc. Chem. Commun., 179 (1987).
166. (b) A. S. Goldstein, R. H. Beer, and R. S. Drago, J. Am. Chem. Soc., 116, 2424 (1994).
167. T. R. Cundari and R. S. Drago, Inorg. Chem., 29, 2303 (1990).
168. P. T. Wood, W. T. Pennington, J. W. Kolis, B. Wu, and C. J. O'Connor, Inorg. Chem., 32, 129 (1993).
169. (a) J. Chatt, L. Manojlovic-Muir, and K. W. Muir, Chem. Commun., 655 (1971).
170. (b) L. Manojlovic-Muir, and K. W. Muir, J. Chem. Soc. Dalton Trans., 686 (1972).
171. (c) L. Manojlovic-Muir, J. Chem. Soc. (A), 2796 (1971).
172. (d) L. Manojlovic-Muir and K. W. Muir, J. Chem. Soc. Dalton Trans., 686 (1972).
173. (e) B. L. Haymore, W. A. Goddard, III, and J. N. Allison, Proc. Int. Conf. Coord. Chem., 23rd, 535 (1984).
174. (a) Y. Jean, A. Lledos, J. K. Burdett, and R. Hoffmann, J. Am. Chem. Soc., 110, 4506 (1988).
175. (b) Y. Jean, A. Lledos, J. K. Burdett, and R. Hoffmann, J. Chem. Soc. Chem. Commun., 140 (1988).
176. (a) G. Parkin, Acc. Chem. Res., 25, 455 (1992).
177. (b) G. Parkin, Chem. Rev., 93, 887 (1993).
178. (c) K. Yoon, G. Parkin, and A. L. Rheingold, J. Am. Chem. Soc., 113, 1437 (1991).
179. (d) K. Yoon, G. Parkin, and A. L. Rheingold, J. Am. Chem. Soc., 114, 2210 (1992).
180. For a brief review, see C. A. McAuliffe and D. S. Barratt, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds.; Pergamon, Oxford, UK, 1987, Chapter 31.
181. P. Mountford and D. Swallow, J. Chem. Soc. Chem. Commun., 2357 (1995).
182. M. Tsutsui, R. A. Velapoldi, K. Suzuki, and T. Koyano, Angew. Chem. Int. Ed. Engl., 7, 891 (1968).
183. J. W. Buchler, G. Eikelman, L. Puppe, K. Rohbock, H. H. Schneehage, and D. D. Weck, Justus Liebigs Ann. Chem., 745, 135 (1971).
184. P. Fournari, R. Guilard, M. Fontesse, J.-M. Latour, and J.-C. Marchon, J. Organomet. Chem., 110, 205 (1976).
185. L. K. Woo, J. A. Hays, V. G., Young, Jr., C. L. Day, C. Caron, F. D'Souza, and K. M. Kadish, Inorg. Chem., 32, 4186 (1993).
186. For a review of titanium and vanadium porphyrin oxo complexes, see R. Guilard, and C. Lecomte, Coord. Chem. Rev., 65, 87 (1985).
187. R. Guilard, J.-M. Latour, C. Lecomte, J.-C. Marchon, J. Protas, and D. Ripoll, Inorg. Chem., 17, 1228 (1978).
188. T. Malinski, D. Chang, J.-M. Latour, J.-C. Marchon, M. Gross, A. Giraudeau, and K. M. Kadish, Inorg. Chem., 23, 3947 (1984).
189. L. K. Woo, Chem. Rev., 93, 1125 (1993).
190. V. L. Goedken and J. A. Ladd, J. Chem. Soc. Chem. Commun., 142 (1982).
191. C.-H. Yang, J. A. Ladd, and V. L. Goedken, J. Coord. Chem., 19, 235 (1988).
192. (a) C. E. Housmekerides, R. S. Pilato, G. L. Geoffroy, and A. L. Rheingold, J. Chem. Soc. Chem. Commun., 563 (1991).
193. (b) C. E. Housmekerides, D. L. Ramage, C. M. Kretz, J. T. Shontz, R. S. Pilato, G. L. Geoffroy, A. L. Rheingold, and B. S. Haggerty, Inorg. Chem., 31, 4453 (1992).
194. (a) C. E. Housmekerides, R. S. Pilato, G. L. Geoffroy, and A. L. Rheingold, J. Chem. Soc. Chem. Commun., 563 (1991).
195. (b) C. E. Housmekerides, D. L. Ramage, C. M. Kretz, J. T. Shontz, R. S. Pilato, G. L. Geoffroy, A. L. Rheingold, and B. S. Haggerty, Inorg. Chem., 31, 4453 (1992).
196. A. Bodner, P. Jeske, Wieghardt, K. Weyhermüller, E. Dubler, H. Schmalle, and B. Nuber, Inorg. Chem., 31, 3737 (1992).
197. M. R. Smith III, P. T. Matsunaga, and R. A. Andersen, J. Am. Chem. Soc., 115, 7049 (1993).
198. F. Bottomley, G. O. Egharevba, I. J. B. Lin, and P. S. White, Organometallics, 4, 550 (1985).
199. J. L. Poise, R. A. Andersen, and R. G. Bergman, J. Am. Chem. Soc., 117, 5393 (1995).
200. D. J. Schwartz, M. R. Smith, III, and R. A. Andersen, Organometallics, 15, 1446 (1996).
201. L. Peng-Ju, H., Sheng-Hua, H. Kun-Yao, W. Ru-Ji, and T. C. W. Mak, Inorg. Chim. Acta, 175, 105 (1990).
202. A. Z. Feltz, Anorg. Allg. Chem., 334, 242 (1965).
203. W. Haase and H. Hoppe, Acta Crystallogr., B24, 282 (1968).
204. (a) V. Krug, G. Koellner, U. Müller, Z. Naturforsch.,43b, 1501 (1988).
205. (b) U. Müller and V. Krug, Angew. Chem. Int. Ed. Engl., 27, 293 (1988).
206. P. J. Lundmark, G. J. Kubas, and B. L. Scott, Organometallics, 15, 3631 (1996).
207. J. M. Fischer, W. E. Piers, L. R. MacGillivray, and M. J. Zaworotko, Inorg. Chem., 34, 2499 (1995).
208. 2. See G. Fachinetti, C. Floriani, A. Chiesi-Villa, and C. Guastini, J. Am. Chem. Soc., 101, 1767 (1979).
209. A. Shaver and J. M. McCall, Organometallics, 3, 1823 (1984).
210. F. Bottomley, D. F. Drummond, G. O. Egharevba, and P. S. White, Organometallics, 5, 1620 (1986).
211. E. Hey, M. F. Lappert, J. L. Atwood, and S. G. Bott, J. Chem. Soc. Chem. Commun., 421 (1987).
212. G. Tainturier, M. Fahim, G. Trouvé-Bellan, and B. Gautheron, J. Organomet. Chem., 376, 121 (1989).
213. (a) G. Teinturier, M. Fahim, and B. Gautheron, J. Organomet. Chem., 373, 193 (1989).
214. (b) M. Fahin and G. Teinturier, J. Organomet. Chem., 301, C45 (1986).
215. (c) G. Tainturier, M. Fahim, and B. Gautheron, J. Organomet. Chem., 362, 311 (1989).
216. G. Erker, T. Mühlenbernd, R. Benn, A. Rufinska, G. Tainturier, and B. Gautheron, Organometallics, 5, 1023 (1986).
217. (a) G. Tainturier, B. Gautheron, and S. Pouly, Nouv. J. Chim., 10, 625 (1986).
218. (b) B. Gautheron, G. Tainturier, and S. Pouly, J. Organomet. Chem., 268, C56 (1984).
219. (a) G. Erker, T. Mühlenbernd, R. Nolte, J. L. Petersen, G. Tainturier, and B. Gautheron, J. Organomet. Chem., 314, C21 (1986).
220. (b) G. Erker, R. Nolte, G. Tainturier, and A. Rheingold, Organometallics, 8, 454 (1989).
221. 2(μ-S) [W. A. Howard, and G. Parkin, Organometallics, 12, 2363 (1993)].
222. 2 been confirmed by X-ray diffraction, (a) R. Beckhaus and K.-H. Thiele, Z. Anorg. Allg. Chem., 573, 195 (1989).
223. (b) R. Broussier, M. Rigoulet, R. Amardeil, G. Delmas, and B. Gautheron, Phosphorus, Sulfur, Silicon, 82, 55 (1993).
224. E. W. Harlan and R. H. Holm, J. Am. Chem. Sac., 112, 186 (1990).
225. R. Bortolin, V. Patel, I. Munday, N. J. Taylor, and A. J. Carty, J. Chem. Soc. Chem. Commun., 456 (1985).
226. (a) M. J. Carney, P. J. Walsh, F. J. Hollander, and R. G. Bergman, Organometallics, 11, 761 (1992).
227. (b) M. J. Carney, P. J. Walsh, and R. G. Bergman, J. Am. Chem. Soc., 112, 6426 (1990).
228. M. J. Carney, P. J. Walsh, F. J. Hollander, and R. G. Bergman, J. Am. Chem. Soc., 111, 8751 (1989).
229. (a) T. A. Hanna, A. M. Baranger, P. J. Walsh, and R. G. Bergman, J. Am. Chem. Soc., 117, 3292 (1995).
230. (b) T. A. Hanna, A. M. Baranger, and R. G. Bergman, J. Org. Chem., 61, 4532 (1996).
231. (a) S. Y. Lee and R. G. Bergman, J. Am. Chem. Soc., 118, 6396 (1996).
232. (b) P. J. Walsh, F. J. Hollander, and R. G. Bergman, Organometallics, 12, 3705 (1993).
233. 2-OC(Ph)=C(Ph)]. See (a) G. A. Vaughan, G. L. Hillhouse, and A. L. Rheingold, J. Am. Chem. Soc., 112, 7994 (1990).
234. (b) G. A. Vaughan, C. D. Sofield, and G. L. Hillhouse, J. Am. Chem. Soc., 111, 5491 (1989).
235. (c) G. A. Vaughan, G. L. Hillhouse, R. T. Lum, S. L. Buchwald, and A. L. Rheingold, J. Am. Chem. Soc., 110, 7215 (1988).
236. -1.
237. 2*Zr= O] would be expected to have similar M=O bond orders, despite the fact that the metal centers are 18- and 16-electron, respectively, since the metallocene fragment is not capable of supporting a triply bonded ligand without compromising the metal-Cp* interactions. See Section III.A.
238. D. Jacoby, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 115, 7025 (1993).
239. D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 117, 2793 (1995).
240. D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 117, 2805 (1995).
241. D. Jacoby, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 115, 7025 (1993).
242. D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 117, 2793 (1995).
243. For a further discussion of carbon monoxide cleavage by transition metals, see D. R. Neithamer, R. E. LaPointe, R. A. Wheeler, D. S. Richeson, G. D. Van Duyne, and P. T. Wolczanski, J. Am. Chem. Soc., 111, 9056 (1989).
244. D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa, and C. Rizzoli, J. Am. Chem. Soc., 117, 2805 (1995).
245. (a) M. M. Dawod, F. I. Khalili, and A. M. Seyam, Synth. React. Inorg. Met.-Org. Chem., 24, 663 (1994).
246. (b) R. K. Agarwal, B. S. Tyagi, M. Srivastava, and A. K. Srivastava, Thermochim. Acta, 61, 241 (1983).
247. 2. See (32b).
248. W. A. Howard, G. Parkin, and A. L. Rheingold, Polyhedron, 14, 25 (1995).
249. A. Shaver and J. M. McCall, Organometallics, 3, 1823 (1984).
250. F. Bottomley, D. F. Drummond, G. O. Egharevba, and P. S. White, Organometallics, 5, 1620 (1986).
251. E. Hey, M. F. Lappert, J. L. Atwood, and S. G. Bott, J. Chem. Soc. Chem. Commun., 421 (1987).
252. (a) G. Tainturier, M. Fahim, and B. Gautheron, J. Organomet. Chem., 373, 193 (1989).
253. (b) M. Fahin and G. Tainturier, J. Organomet. Chem., 301, C45 (1986).
254. (c) G. Tainturier, M. Fahim, and B. Gautheron, J. Organomet. Chem., 362, 311 (1989).
255. G. Erker, T. Mühlenbernd, R. Benn, A. Rufinska, G. Tainturier, and B. Gautheron, Organometallics, 5, 1023 (1986).
256. W. A. Howard, T. M. Trnka, and G. Parkin, Organometallics, 14, 4037 (1995).
257. W. A. Howard, and G. Parkin, unpublished results.
258. For leading recent references on nonclassical carbonyl complexes, see (a) P. K. Hurlburt, J. J. Rack, J. S. Luck, S. F. Dec, J. D. Webb, O. P. Anderson, and S. H. Strauss, J. Am. Chem. Soc., 116, 10003 (1994).
259. (b) F. Aubke, and C. Wang, Coord. Chem. Rev., 137, 483 (1994).
260. (c) L. Weber, Angew. Chem. Int. Ed. Engl., 33, 1077 (1994).
261. (d) H. Willner, M. Bodenbinder, C. Wang, and F. Aubke, J. Chem. Soc. Chem. Commun., 1189 (1994).
262. (e) S. H. Strauss, Chemtracts-Inorg. Chem., 10, 77 (1997).
263. 2SiNBu′)CO (138f). (a) J. M. Manriquez, D. R. McAlister, R. D. Sanner, and J. E. Bercaw, J. Am. Chem. Soc., 100, 2716 (1978).
264. (b) J. A. Marsella, C. J. Curtis, J. E. Bercaw, and K. G. Caulton, J. Am. Chem. Soc., 102, 7244 (1980).
265. (c) A. S. Guram, D. C. Swenson, and R. F. Jordan, J. Am. Chem. Soc., 114, 8991 (1992).
266. (d) Z. Guo, D. C. Swenson, A. S. Guram, and R. F. Jordan, Organometallics, 13, 766 (1994).
267. (e) D. M. Antonelli, E. B. Tjaden, and J. M. Stryker, Organometallics, 13, 763 (1994).
268. (f) L. J. Procopio, P. J. Carroll, and D. H. Berry, Polyhedron, 14, 45 (1995).
269. D. J. Sikora, M. D. Rausch, R. D. Rogers, and J. L. Atwood, J. Am. Chem. Soc., 103, 1265 (1981).
270. (a) H. H. Brintzinger, J. Organomet. Chem., 171, 337 (1979).
271. (b) S. H. Strauss, Chemtracts - Inorg. Chem., 6, 157 (1994).
272. (a) V. Christou and J. Arnold, J. Am. Chem. Soc., 114, 6240 (1992).
273. (b) C. P. Gerlach, V. Christou, and J. Arnold, Inorg. Chem., 35, 2758 (1996).
274. D. E. Gindelberger and J. Arnold, Organometallics, 13, 4462 (1994).
275. W. A. Howard and G. Parkin, J. Organomet. Chem., 472, C1 (1994).
276. L. V. Boas and J. C. Pessoa, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 33.
277. C. C. Cummins, R. R. Schrock, and W. M. Davis, Inorg. Chem., 33, 1448 (1994).
278. 3]VO are also known (146b). (a) W. Plass, and J. G. Verkade, J. Am. Chem. Soc., 114, 2275 (1992).
279. (b) K. Nomura, R. R. Schrock, and W. M. Davis, Inorg. Chem., 35, 3695 (1996).
280. 2-E) (E = S, Se, Te). (a) J. Schiemann, P. Hübener, U. Behrens, and E. Weiss, Angew. Chem. Int. Ed. Engl., 22, 980 (1983).
281. (b) N. Albrecht, P. Hübener, U. Behrens, and E. Weiss, Chem. Ber., 118, 4059 (1985).
282. W. Priebsch and D. Rehder, Inorg. Chem., 24, 3085 (1985).
283. C. P. Gerlach and J. Arnold, Inorg. Chem., 35, 5770 (1996).
284. (a) J. L. Poncet, R. Guilard, P. Priant, C. Goulon-Ginet, and J. Goulon, Nouv. J. Chim., 8, 583 (1984).
285. (b) J. L. Poncet, R. Guilard, P. Priant, and J. Goulon, Polyhedron, 5, 417 (1983).
286. (a) V. L. Goedken and J. A. Ladd, J. Chem. Soc. Chem. Commun., 910 (1981).
287. (b) C.-H. Yang, J. A. Ladd, and V. L. Goedken, J. Coord. Chem., 18, 317 (1988).
288. H. Schumann, Z. Naturforsch., 50B, 1494 (1995).
289. -1, d(V=O) = 1.601(2) Å] (152b). (a) S. Lee, C. Floriani, A. Chiesi-Villa, and C. Guastini, J. Chem. Soc. Dalton Trans., 145 (1989).
290. (b) F. A. Cotton, J. Czuchajowska, and X. Feng, Inorg. Chem., 30, 349 (1991).
291. (a) V. L. Goedken and J. A. Ladd, J. Chem. Soc. Chem. Commun., 910 (1981).
292. (b) C.-H. Yang, J. A. Ladd, and V. L. Goedken, J. Coord. Chem., 18, 317 (1988).
293. -1, d(V=O) = 1.601(2) Å](154b). (a) S. Lee, C. Floriani, A. Chiesi-Villa, and C. Guastini, J. Chem. Soc. Dalton Trans., 145 (1989).
294. (b) F. A. Cotton, J. Czuchajowska, and X. Feng, Inorg. Chem., 30, 349 (1991).
295. (a) F. Bottomley, C. P. Magill, and B. Zhao, Organometallics, 9, 1700 (1990).
296. (b) F. Bottomley, C. P. Magill, and B. Zhao, Organometallics, 10, 1946 (1991).
297. K. P. Callahan, P. J. Durand, and P. H. Rieger, J. Chem. Soc. Chem. Commun., 75 (1980).
298. (b) K. P. Callahan and P. J. Durand, Inorg. Chem., 19, 3211 (1980).
299. Y. Do, E. D. Simhon, and R. H. Holm, Inorg. Chem., 22, 3809 (1983).
300. F. Preuss and H. Noichl, Z. Naturforsch. ,42B, 121 (1987).
301. J. R. Nicholson, J. C. Huffman, D. M. Ho, and G. Christou, Inorg. Chem., 26, 3030 (1987).
302. L. G. Hubert-Pfalzgraf, M. Postel, and J. G. Riess, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 34.
303. A. Antiñolo, J. Martinez de Ilarduya, A. Otero, P. Royo, A. M. M. Lanfredi, and A. Tiripicchio, J. Chem. Soc. Dalton Trans., 2685 (1988).
304. P.-F. Fu, M. A. Khan, and K. M. Nicholas, Organometallics, 10, 382 (1991).
305. H. Brunner, G. Gehart, W. Meier, J. Wachter, and B. Nuber, J. Organomet. Chem., 454, 117 (1993).
306. For a review of niobium and molybdenum porphyrin oxo chemistry, see Y. Matsuda and Y. Murakami, Coord. Chem. Rev., 92, 157 (1988).
307. E. L. Muetterties and C. M. Wright, J. Am. Chem. Soc., 87, 4706 (1965).
308. M. G. B. Drew, D. A. Rice, and D. M. Williams, Inorg. Chim. Acta, 118, 165 (1986).
309. U. Siemeling and V. C. Gibson, J. Chem. Soc. Chem. Commun., 1670 (1992).
310. V. C. Gibson, T. P. Kee, R. M. Sorrell, A. P. Bashall, and M. McPartlin, Polyhedron, 7, 2221 (1988).
311. A. Bashall, V. C. Gibson, T. P. Kee, M. McPartlin, O. B. Robinson, and A. Shaw, Angew. Chem. Int. Ed. Engl., 30, 980 (1991).
312. V. C. Gibson and M. McPartlin, J. Chem. Soc. Dalton Trans., 947 (1992).
313. Y. Do and R. H. Holm, Inorg. Chim. Acta, 104, 33 (1985).
314. J. L. Seela, J. C. Huffman, and G. Christou, Polyhedron, 8, 1797 (1989).
315. S. C. Lee, J. Li, J. C. Mitchell, and R. H. Holm, Inorg. Chem., 31, 4333 (1992).
316. M. Latroche and J. A. Ibers, Inorg. Chem., 29, 1503 (1990).
317. H. Yun, C. R. Randall, and J. A. Ibers, J. Solid State Chem., 76, 109 (1988).
318. D. Coucouvanis, S. Al-Ahmad, C. G. Kim, and S.-M. Koo, Inorg. Chem., 31, 2996 (1992).
319. K. Tatsumi, Y. Sekiguchi, A. Nakamura, R. E. Cramer, and J. J. Rupp, J. Am. Chem. Soc., 108, 1358 (1986).
320. A. van Asselt, B. J. Burger, V. C. Gibson, and J. E. Bercaw, J. Am. Chem. Soc., 108, 5347 (1986).
321. G. Parkin, A. van Asselt, D. J. Leahy, L. Whinnery, N. G. Hua, R. Quan, L. M. Henling, W. P. Schaefer, B. D. Santarsiero, and J. E. Bercaw, Inorg. Chem., 31, 82 (1992).
322. D. M. Antonelli, W. P. Schaefer, G. Parkin, and J. E. Bercaw, J. Organomet. Chem., 462, 213 (1993).
323. 2(μ-O). See A. Castro, M. Gómez, P. Gómez-Sal, A. Manzanero, and P. Royo, J. Organomet. Chem., 518, 37 (1996).
324. J. E. Nelson, G. Parkin, and J. E. Bercaw, Organometallics, 11, 2181 (1992).
325. J. H. Shin and G. Parkin, Organometallics, 13, 2147 (1994).
326. W. A. Nugent and J. M. Mayer, Metal-Ligand Multiple Bonds, Wiley-Interscience, New York, 1988, p. 163.
327. W. A. Nugent and J. M. Mayer, Metal-Ligand Multiple Bonds, Wiley-Interscience, New York, 1988, p. 116.
328. G. Parkin, E. Bunel, B. J. Burger, M. S. Trimmer, A. van Asselt, and J. E. Bercaw, J. Mol. Catal., 41, 21 (1987).
329. H. Brunner, M. M. Kubicki, J.-C. Leblanc, C. Moise, F. Volpato, and J. Wachter, J. Chem. Soc. Chem. Commun., 851 (1993).
330. H.-J. Bach, H. Brunner, J. Wachter, M. M. Kubicki, J.-C. Leblanc, and M. L. Ziegler, Organometallics, 11, 1403 (1992).
331. A. van Asselt, B. J. Burger, V. C. Gibson, and J. E. Bercaw, J. Am. Chem. Soc., 108, 5347 (1986).
332. G. Parkin, E. Bunel, B. J. Burger, M. S. Trimmer, A. van Asselt, and J. E. Bercaw, J. Mol. Catal., 41, 21 (1987).
333. J. H. Shin and G. Parkin, Organometallics, 13, 2147 (1994).
334. 2*Ta(CO)Me under similar conditions.
335. A. van Asselt, M. S. Trimmer, L. M. Henling, and J. E. Bercaw, J. Am. Chem. Soc., 110, 8254 (1988).
336. L. L. Whinnery, Jr., L. M. Henling, and J. E. Bercaw, J. Am. Chem. Soc., 113, 7575 (1991).
337. For a review of transition metal catalyzed epoxidations, see K. A. Jorgensen, Chem. Rev., 89, 431 (1989).
338. J. E. Nelson, G. Parkin, and J. E. Bercaw, Organometallics, 11, 2181 (1992).
339. (a) G. Proulx and R. G. Bergman, Science, 259, 661 (1993).
340. (b) G. Proulx and R. G. Bergman, J. Am. Chem. Soc., 115, 9802 (1993).
341. (c) G. Proulx and R. G. Bergman, J. Am. Chem. Soc., 118, 1981 (1996).
342. (d) G. Proulx, F. J. Hollander, and R. G. Bergman, Can. J. Chem., 73, 1111 (1995).
343. (a) G. Proulx and R. G. Bergman, Organometallics, 15, 133 (1996).
344. (b) G. Proulx and R. G. Bergman, J. Am. Chem. Soc., 116, 7953 (1994).
345. C. C. Cummins, R. R. Schrock, and W. M. Davis, Angew. Chem. Int. Ed. Engl., 32, 756 (1993).
346. V. Christou and J. Arnold, Angew. Chem. Int. Ed. Engl., 32, 1450 (1993).
347. (a) R. E. LaPointe, P. T. Wolczanski, and J. F. Mitchell, J. Am. Chem. Soc., 108, 6382 (1986).
348. (b) D. R. Neithamer, R. E. LaPointe, R. A. Wheeler, D. S. Richeson, G. D. Van Duyne, and P. T. Wolczanski, J. Am. Chem. Soc., 111, 9056 (1989).
349. M. G. B. Drew, D. A. Rice, and D. M. Williams, J. Chem. Soc. Dalton Trans., 845 (1984).
350. E. J. Peterson, R. B. von Dreele, and T. M. Brown, Inorg. Chem., 17, 1410 (1978).
351. M. G. B. Drew, D. A. Rice, and D. M. Williams, J. Chem. Soc. Dalton Trans., 1821 (1985).
352. -1 cited in (203) is incorrect. See (171).
353. P. F. Gilletti, D. A. Femec, F. I. Keen, and T. M. Brown, Inorg. Chem., 31, 4008 (1992).
354. H. Yun, C. R. Randall, and J. A. Ibers, J. Solid State Chem., 76, 109 (1988).
355. L. F. Larkworthy, K. B. Nolan, and P. O'Brien, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds.; Pergamon Oxford, UK, 1987, Chapter 35.
356. (a) J. T. Groves, W. J. Kruper, Jr., R. C. Haushalter, and W. M. Butler, Inorg. Chem., 21, 1363 (1982).
357. (b) T. L. Siddall, N. Miyaura, J. C. Huffman, and J. K. Kochi, J. Chem. Soc. Chem. Commun., 1185 (1983).
358. (c) D. B. Morse, T. B. Rauchfuss, and S. R. Wilson, J. Am. Chem. Soc., 110, 8234 (1988).
359. (d) J. A. McGinnety, Acta Crystallogr., B28, 2845 (1972).
360. S.-K. Noh, R. A. Heintz, B. S. Haggerty, A. L. Rheingold, and K. H. Theopold, J. Am. Chem. Soc., 114, 1892 (1992).
361. G. K. Cook and J. M. Mayer, J. Am. Chem. Soc., 116, 1855 (1994).
362. M. Poliakoff, K. P. Smith, J. J. Turner, and A. J. Wilkinson, J. Chem. Soc. Dalton Trans., 651 (1982).
363. M. J. Almond, J. Chem. Soc. Rev., 23, 309 (1994).
364. K. Lane, L. Sallans, and R. R. Squires, J. Am. Chem. Soc., 106, 2719 (1984).
365. (a) C. D. Garner and J. M. Charnock, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 36.4.
366. (b) E. I. Stiefel, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, J. A. McCleverty, Eds., Pergamon: Oxford, UK, 1987, Chapter 36.5.
367. (c) C. D. Garner, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxfoid, UK, 1987, Chapter 36.6.
368. R. H. Holm, Coord. Chem. Rev., 100, 183 (1990).
369. (a) B. E. Schultz and R. H. Holm, Inorg. Chem., 32, 4244 (1993).
370. (b) B. E. Schultz, R. Hille, and R. H. Holm, J. Am. Chem. Soc., 117, 827 (1995).
371. (c) B. E. Schultz, S. F. Gheller, M. C. Muetterties, M. J. Scott, and R. H. Holm, J. Am. Chem. Soc., 115, 2714 (1993).
372. V. J. Murphy and G. Parkin, J. Am. Chem. Soc., 117, 3522 (1995).
373. 4). See L. C. Roof, W. T. Pennington, and J. W. Kolis, J. Am. Chem. Soc., 112, 8172 (1990).
374. (a) F. A. Cotton and X. Feng, Inorg. Chem., 35, 4921 (1996).
375. (b) F. A. Cotton, and G. Schmid, Inorg. Chem., 36, 2267 (1997).
376. 4] (221b) (a) T. Adachi, D. L. Hughes, S. K. Ibrahim, S. Okamoto, C. J. Pickett, N. Yabanouchi, and T. Yoshida, J. Chem. Soc. Chem. Commun., 1081 (1995).
377. (b) M. R. Churchill and F. Rotella, J. Inorg. Chem., 17, 668 (1978).
378. T. Yoshida, T. Adachi, K. Matsumura, K. Kawazu, and K. Baba, Chem. Lett., 1067 (1991).
379. For a compilation of Mo=S bond lengths in dinuclear complexes, see J. L. Dulebohn, T. C. Stamatakos, D. L. Ward, and D. G. Nocera, Polyhedron, 10, 2813 (1991).
380. 2- [2.182(7) Å; 2.135(7) Å] (223e), (a) M. R. DuBois, D. L. DuBois, M. C. vanDerveer, and R. C. Haltiwanger, Inorg. Chem., 20, 3064 (1981).
381. (b) W. Clegg, G. Christou, C. D. Garner, and G. M. Sheldrick, Inorg. Chem., 20, 1562 (1981).
382. (c) X. Lei, Z. Huang, Q. Liu, M Hong, and H. Liu, Inorg. Chem., 28, 4302 (1989).
383. (d) S. A. Roberts, C. G. Young, W. E. Cleland, Jr., K. Yamanouchi, R. B. Ortega, and J. H. Enemark, Inorg. Chem., 27, 2647 (1988).
384. (e) D. Coucouvanis and S.-M. Koo, Inorg. Chem., 28, 2 (1989).
385. I.-P. Lorenz, G. Walter, and W. Killer, Chem. Ber., 123, 979 (1990).
386. J. A. Paradis, D. W. Wertz, and H. H. Thorp, J. Am. Chem. Soc., 115, 5308 (1993).
387. A. V. Butcher and J. Chatt, J. Chem. Soc. (A), 2652 (1970).
388. F. A. Cotton, M. P. Diebold, and W. J. Roth, Inorg. Chem., 26, 2848 (1987).
389. L. K. Atkinson, A. H. Mawby, and D. C. Smith, Chem. Commun., 1399 (1970).
390. E. Carmona, A. Galindo, L. Sanchez, A. J. Nielson, and G. Wilkinson, Polyhedron, 3, 347 (1984).
391. K. A. Hall and J. M. Mayer, J. Am. Chem. Soc., 114, 10402 (1992).
392. K. A. Hall and J. M. Mayer, Inorg. Chem., 34, 1145 (1995).
393. J. M. Mayer, Adv. Transition Metal Coord. Chem., 1, 105 (1996).
394. K. A. Hall and J. M. Mayer, Inorg. Chem., 33, 3289 (1994).
395. T. Yoshida, T. Adachi, K. Matsumura, and K. Baba, Chem. Lett., 2447 (1992).
396. 3(SEt)] has recently been reported. See P. M. Boorman, M. Wang, and M. Parvez, J. Chem. Soc. Chem. Commun., 999 (1995).
397. T. Yoshida, T. Adachi, K. Matsumura, and K. Baba, Angew. Chem. Int. Ed. Engl., 32, 1621 (1993).
398. For a review of niobium and molybdenum porphyrin oxo chemistry, see Y. Matsuda, and Y. Murakami, Coord. Chem. Rev., 92, 157 (1988).
399. T. Diebold, B. Chevrier, and R. Weiss, Inorg. Chem., 19, 1193 (1979).
400. L. M. Berreau, V. G. Young, Jr., and L. K. Woo, Inorg. Chem., 34, 3485 (1995).
401. L. M. Berreau, J. A. Hays, V. G. Young, and L. K. Woo, Inorg. Chem., 33, 105 (1994).
402. For a review of such atom-transfer reactions see L. K. Woo, Chem. Rev., 93, 1125 (1993).
403. C. C. Cummins, personal communication.
404. C. E. Laplaza, A. L. Odom, W. M. Davis, C. C. Cummins, and J. D. Protasiewicz, J. Am. Chem. Soc., 117, 4999 (1995).
405. M. L. H. Green, A. H. Lynch, and M. G. Swanwick, J. Chem. Soc. Dalton Trans., 1445 (1972).
406. M. Berry, S. G. Davies, and M. L. H. Green, J. Chem. Soc. Chem. Commun., 99 (1978).
407. F. G. N. Cloke, J. P. Day, J. C. Green, C. P. Morley, and A. C. Swain, J. Chem. Soc. Dalton Trans., 789 (1991).
408. M. Henary, W. C. Kaska, and J. I. Zink, Inorg. Chem., 30, 1674 (1991).
409. 2. See K. A. Belmore, R. A. Vanderpool, J.-C. Tsai, M. A. Khan, and K. M. Nicholas, J. Am. Chem. Soc., 110, 2004 (1988).
410. R. S. Pilato, C. E. Housmekerides, P. Jernakoff, D. Rubin, G. L. Geoffroy, and A. L. Rheingold, Organometallics, 9, 2333 (1990).
411. R. S. Pilato, K. A. Eriksen, E. I. Stiefel, and A. L. Rheingold, Inorg. Chem., 32, 3799 (1993).
412. R MO.
413. Z. Dori, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 37.
414. (a) V. C. Gibson, C. E. Graimann, P. M. Hate, M. L. H. Green, J. A. Bandy, P. D. Grebenik, and K. Prout, J. Chem. Soc. Dalton Trans., 2025 (1985).
415. (b) M. L. H. Green, G. Parkin, M. Chen, and K. Prout, J. Chem. Soc. Dalton Trans., 2227 (1986).
416. (a) D. Rabinovich and G. Parkin, J. Am. Chem. Soc., 113, 5904 (1991).
417. (b) D. Rabinovich and G. Parkin, J. Am. Chem. Soc., 113, 9421 (1991).
418. (c) D. Rabinovich and G. Parkin, J. Am. Chem. Soc., 115, 9822 (1993).
419. (d) D. Rabinovich and G. Parkin, Inorg. Chem., 33, 2313 (1994).
420. Hydrogen telluride must be handled in the dark below 0°C to avoid decomposition. See N. N. Greenwood and A. Earnshaw, Chemistry of the Elements, Pergamon, New York, 1986, pp. 899-900.
421. (a) K. E. Howard, T. B. Rauchfuss, and S. R. Wilson, Inorg. Chem., 27, 1710 (1988).
422. (b) L. C. Roof, W. T. Pennington, and J. W. Kolis, J. Am. Chem. Soc., 112, 8172 (1990).
423. D. R. Gardner, J. C. Fettinger, and B. W. Eichom, Angew. Chem. Int. Ed. Engl., 33, 1859 (1994).
424. J. A. Crayston, M. J. Almond, A. J. Downs, M. Poliakoff, and J. I. Turner, Inorg. Chem., 23, 3051 (1984).
425. 2. See M. Poliakoff, K. P. Smith, J. J. Turner, and A. J. Wilkinson, J. Chem. Soc. Dalton Trans., 651 (1982).
426. 6, see (213) and (a) M. J. Almond, A. J. Downs, and R. N. Perutz, Inorg. Chem., 24, 275 (1985).
427. (b) M. J. Almond and M. Hahne, J. Chem. Soc. Dalton Trans., 2255 (1988).
428. (c) M. J. Almond, J. A. Crayston, A. J. Downs, M. Poliakoff, and J. J. Turner, Inorg. Chem., 25, 19 (1986).
429. M. J. Almond and A. J. Downs, J. Chem. Soc. Dalton Trans., 809 (1988).
430. The W-E bond lengths listed are the mean values obtained from a search of the Cambridge Structural Database (Version 5.09, April 1995) for bonds between tungsten and a two-coordinate chalcogen. The range of W-E bond lengths are d(W-S) = 2.03 - 2.72 Å, d(W-Se) = 2.32 - 2.70 Å, and d(E-Te) = 2.67 - 2.88 Å.
431. 2S. See (a) C.-L. Lee, G. Besenyei, B. R. James, D. A. Neslon, and M. A. Lilga, J. Chem. Soc. Chem. Commun., 1175 (1985).
432. (b) G. Besenyei, C.-L. Lee, J. Gulinski, S. J. Rettig, B. R. James, D. A. Nelson, and M. A. Lilga, Inorg. Chem., 26, 3622 (1987).
433. A. F. Barnabas, D. Sallin, and B. R. James, Can. J. Chem., 67, 2009 (1989).
434. (d) R. McDonald and M. Cowie, Inorg. Chem., 32, 1671 (1993).
435. (e) T. Y. H. Wong, A. F. Barnabas, D. Sallin, and B. R. James, Inorg. Chem., 34, 2278 (1995).
436. 3), have recently been isolated and structurally characterized. See T. Hascall, V. J. Murphy, and G. Parkin, Organometallics, 15, 3910 (1996).
437. 3PTe. See (a) R. A. Zingaro, B. H. Sleeves, and K. Irgolic, J. Organomet. Chem., 4, 320 (1965).
438. (b) M. L. Steigerwald, and C. R. Sprinkle, Organometallics, 7, 245 (1988).
439. (a) D. J. Berg, C. J. Burns, R. A. Andersen, and A. Zalkin, Organometallics, 8, 1865 (1989).
440. (b) S. M. Stuczynski, Y.-U. Kwon, and M. L. Steigerwald, J. Organomet. Chem., 449, 167 (1993).
441. (c) J. G. Brennan, T. Siegrist, S. M. Stuczynski, and M. L. Steigerwald, J. Am. Chem. Soc., 111, 9240 (1989).
442. (d) J. G. Brennan, R. A. Andersen, and A. Zalkin, Inorg. Chem., 25, 1761 (1986).
443. (e) K. McGregor, G. B. Deacon, R. S. Dickson, G. D. Fallen, R. S. Rowe, and B. O. West, J. Chem. Soc. Chem. Commun., 1293 (1990).
444. (f) W. E. Piers, L. R. MacGillivray, and M. Zaworotko, Organometallics, 12, 4723 (1993).
445. (g) I. P. Beletskaya, A. Z. Voskoboynikov, A. K. Shestakova, and H. Schumann, J. Organomet. Chem., 463, C1 (1993).
446. (h) M. L. Steigerwald and C. E. Rice, J. Am. Chem. Soc., 110, 4228 (1988).
447. 3PE, see (a) R. D. Baechler, M. Stack, K. Stevenson, and V. Vanvalkenburgh, Phosphorus, Sulfur, Silicon, 48, 49 (1990).
448. (b) K. A. Hall and J. M. Mayer, Inorg. Chem., 33, 3289 (1994).
449. N. Kuhn, H. Schumann, and G. Wolmershäuser, J. Chem. Soc. Chem. Commun., 1595 (1985).
450. N. Kaltsoyannis, J. Chem. Soc. Dalton Trans., 1391 (1994).
451. M. H. Chisholm, J. C. Huffman, and J. W. Pasterczyk, Polyhedron, 6, 1551 (1987) and references cited therein.
452. The term "reductive coupling" is used here to indicate changes in formal oxidation state at the metal center, and not at the ligands. (a) C. Elschenbroich and A. Salzer, Organometallics: A Concise Introduction, 2nd ed., VCH, New York, 1992, pp. 412-414.
453. (b) R. H. Crabtree, The Organometallic Chemistry of the Transition Metals, 2nd ed., Wiley, New York, 1994, Chapter 6.
454. For some other examples of coupling and cleavage reactions, see (a) E. M. Carnahan, J. D. Protasiewicz, and S. J. Lippard, Acc. Chem. Res., 26, 90 (1993).
455. (b) A. Mayr, and C. M. Bastos, Progress in Inorganic Chemistry, Wiley-Interscience, New York, Vol. 40, 1992, pp. 1-98.
456. (c) R. Hoffmann, C. N. Wilker, S. J. Lippard, J. L. Templeton, and D. C. Brewer, J. Am. Chem. Soc., 105, 146 (1983).
457. (d) C. N. Wilker, R. Hoffmann, and O. Eisenstein, Nouv. J. Chim., 7, 535 (1983).
458. (e) R. Hoffmann, C. N. Wilker, and O. Eisenstein, J. Am. Chem. Soc., 104, 632 (1982).
459. (f) S. Nakamura and K. Morokuma, Organometallics, 7, 1904 (1988).
460. (g) F. Delbecq, J. Organomet. Chem., 443, 191 (1993).
461. Bent coordination of isocyanide ligands is not as common as linear coordination, although it does have precedence. See, for example, (a) E. M. Carnahan, R. L. Rardin, S. G. Bott, and S. J. Lippard, Inorg. Chem., 31, 5193 (1992).
462. (b) E. M. Camahan and S. J. Lippard, J. Chem. Soc. Dalton Trans., 699 (1991).
463. (c) J. Chatt, A. J. L. Pombeiro, R. L. Richards, G. H. D. Royston, K. W. Muir, and R. Walker, J. Chem. Soc. Chem. Commun., 708 (1975).
464. (d) A. M. Martins, M. J. Calhorda, C. C. Romão, C. Völkl, P. Kiprof, and A. C. Filippou, J. Organomet. Chem., 423, 367 (1992).
465. (e) W. D. Jones, G. P. Foster, and J. M. Putinas, Inorg. Chem., 26, 2120 (1987).
466. (f) J.-M. Bassett, D. E. Berry, G. K. Barker, M. Green, J. A. K. Howard, and F. G. A. Stone, J. Chem. Soc. Dalton Trans., 1003 (1979).
467. (g) K. W. Chiu, C. G. Howard, G. Wilkinson, A. M. R. Galas, and M. B. Hursthouse, Polyhedron, 1, 803 (1982).
468. (h) M. Green, J. A. K. Howard, M. Murray, J. L. Spencer, and F. G. A. Stone, J. Chem. Soc. Dalton Trans., 1509 (1977).
469. For reviews on isocyanide complexes see (a) E. Singleton and H. E. Oosthuizen, Adv. Organomet. Chem., 22, 209 (1983).
470. (b) Y. Yamamoto, Coord. Chem. Rev., 32, 193 (1980).
471. (c) H. Werner, Angew. Chem. Int. Ed. Engl., 29, 1077 (1990).
472. (a) C. L. Coyle, M. A. Harmer, G. N. George, M. Daage, and E. I. Stiefel, Inorg. Chem., 29, 14 (1990).
473. (b) S. A. Cohen and E. I. Stiefel, Inorg. Chem., 24, 4657 (1985).
474. (c) F. Sécheresse, J. M. Manoli, and C. Potvin, Inorg. Chem., 25, 3967 (1986).
475. (d) C. Simonnet-Jegat, N. Jourdan, F. Robert, C. Bois, and F. Sécheresse, Inorg. Chim. Acta, 216, 201 (1994).
476. (e) W. Rittner, A. Müller, A. Neumann, W. Bäther, and R. C. Sharma, Angew. Chem. Int. Ed. Engl., 18, 530 (1979).
477. (f) L. Wei, T. R. Halbert, H. H. Murray, III, and E. I. Stiefel, J. Am. Chem. Soc., 112, 6431 (1990).
478. (g) T. R. Halbert, L. L. Hatchings, R. Rhodes, and E. I. Stiefel, J. Am. Chem. Soc., 108, 6437 (1986).
479. (h) J. M. Berg, D. J. Spira, K. O. Hodgson, A. E. Bruce, K. F. Miller, J. L. Corbin, and E. I. Stiefel, Inorg. Chem., 23, 3412 (1984).
480. (i) H. Ledon, M. Bonnet, and J.-Y. Lallemand, J. Chem. Soc. Chem. Commun., 702 (1979).
481. (j) D. G. Lee, C. R., Moylan, T. Hayashi, and J. I. Brauman, J. Am. Chem. Soc., 109, 3003 (1987).
482. A. V. Butcher, J. Chart, G. J. Leigh, and P. L. Richards, J. Chem. Soc. Dalton Trans., 1064 (1972).
483. E. Carmona, L. Sánchez, M. L. Poveda, R. A. Jones, and J. G. Hefner, Polyhedron, 2, 797 (1983).
484. K. Yoon, G. Parkin, D. L. Hughes, and G. J. Leigh, J. Chem. Soc. Dalton Trans., 769 (1992).
485. J. C. Bryan, S. J. Geib, A. L. Rheingold, and J. M. Mayer, J. Am. Chem. Soc., 109, 2826 (1987).
486. F.-M. Su, J. C. Bryan, S. Jang, and J. M. Mayer, Polyhedron, 8, 1261 (1989).
487. J. C. Bryan and J. M. Mayer, J. Am. Chem. Soc., 112, 2298 (1990).
488. F.-M. Su, C. Cooper, S. J. Geib, A. L. Rheingold, and J. M. Mayer, J. Am. Chem. Soc., 108, 3545 (1986).
489. J. C. Bryan and J. M. Mayer, J. Am. Chem. Soc., 109, 7213 (1987).
490. J. C. Bryan and J. M. Mayer J. Am.-Chem. Soc., 112, 2298 (1990).
491. For a MO analysis of this cleavage reaction, see (271g).
492. S. G. Feng, L. Luan, P. White, M. S. Brookhart, J. L. Templeton, and C. G. Young, Inorg. Chem., 30, 2582 (1991).
493. C. G. Young, R. W. Gable, and M. F. Mackay, Inorg. Chem., 29, 1777 (1990).
494. S. Thomas, E. R. T. Tiekink, and C. G. Young, Organometallics, 15, 2428 (1996).
495. G. Parkin and J. E. Bercaw, Organometallics, 8, 1172 (1989).
496. P. Jernakoff, J. R. Fox, J. C. Hayes, S. Lee, B. M. Foxman, and N. J. Cooper, Organometallics, 14, 4493 (1995).
497. G. Parkin, R. E. Marsh, W. P. Schaefer, and J. E. Bercaw, Inorg. Chem., 27, 3262 (1988).
498. B. Chiswell, E. D. McKenzie, and L. F. Lindoy, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 41.
499. T. J. Collins, R. D. Powell, C. Slebodnick, and E. S. Uffelman, J. Am. Chem. Soc., 112, 899 (1990).
500. T. J. Collins and S. W. Gorfon-Wylie, J. Am. Chem. Soc., 111, 4511 (1989).
501. F. M. MacDonnell, N. L. P. Fackler, C. Stern, and T. V. O'Halloran, J. Am. Chem. Soc., 116, 7431 (1994).
502. R. S. Czemuszewicz, Y. O. Su, M. K. Stern, K. A. Macor, D. Kim, J. D. Groves, and T. G. Spiro, J. Am. Chem. Soc., 110, 4158 (1988).
503. (a) O. Bortolini and B. Meunier, J. Chem. Soc. Chem. Commun., 1364 (1983).
504. (b) P. J. Pospisil, D. H. Carsten, and E. N. Jacobsen, Chem. Eur. J., 2, 974 (1996).
505. M. J. Almond, R. W. Atkins, and R. H. Orrin, J. Chem. Soc. Datlon Trans., 311 (1994).
506. (a) W. A. Herrmann, C. Hecht, M. L. Ziegler, and B. Balbach, J. Chem. Soc. Chem. Commun., 686 (1984).
507. (b) M. Herberhold, D. Reiner, and D. Neugebauer, Angew. Chem. Int. Ed. Engl., 22, 59 (1983).
508. For a review of structurally characterized technetium complexes, including oxo derivatives, see M. Melník, and J. E. van Lier, Coord. Chem. Rev., 77, 275(1987).
509. For other comparisons of Tc=O bond lengths, see (a) A. Duatti, A. Marchi, L. Magon, E. Deutsch, V. Bertolasi, and G. Gilli, Inorg. Chem., 26, 2182 (1987).
510. (b) R. W. Thomas, G. W. Estes, R. C. Elder, and E. Deutsch, J. Am. Chem. Soc., 101, 4581 (1979).
511. R. W. Thomas, A. Davison, H. S. Trop, and E. Deutsch, Inorg. Chem., 19, 2840 (1980).
512. J. A. Thomas and A. Davison, Inorg. Chim. Acta, 190, 231 (1991).
513. H. J. Banberry, W. Hussain, I. G. Evans, T. A. Hamor, C. J. Jones, J. A. McCleverty, H.-J. Schulte, B. Engles, and W. Kläui, Polyhedron, 9, 2549 (1990).
514. S. N. Brown and J. M. Mayer, Inorg. Chem., 31, 4091 (1992).
515. W. A. Hermann, R. Alberto, P. Kiprof, and F. Baumgärtner, Angew. Chem. Int. Ed. Engl., 29, 189 (1990).
516. B. Kanellakopulos, B. Nuber, K. Raptis, and M. L. Ziegler, Angew. Chem. Int. Ed. Engl., 28, 1055 (1989).
517. A. W. E. Chan, R. Hoffmann, and S. Alvarez, Inorg. Chem., 30, 1086 (1991).
518. See footnote 10 of (305).
519. A. K. Burrell, F. A. Cotton, L. M. Daniels, and V. Petricek, Inorg. Chem., 34, 4253 (1995).
520. N. Masciocchi, P. Cairati, F. Saiano, and A. Sironi, Inorg. Chem., 35, 4060 (1996).
521. A. Duatti, F. Tisato, F. Refosco, U. Mazzi, and M. Nicolini, Inorg. Chem., 28, 4564 (1989).
522. K. A. Conner and R. A. Walton, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 43.
523. (a) D. M. Hoffman, in Comprehensive Organometallic Chemistry II, E. W. Abel, F. G. A. Stone, G. Wilkinson, Eds., Pergamon, New York, 1995, Vol. 6, Chapter 10.
524. (b) C. C. Romao, in Encyclopedia of Inorganic Chemistry, R. B. King, Ed., Wiley, New York, 1994, Vol. 6, pp. 3437-3465.
525. I. R. Beattie and P. J. Jones, Inorg. Chem., 18, 2318 (1979).
526. F. E. Kühn, W. A. Herrmann, R. Hahn, M. Elison, J. Blümel, and E. Herdtweck, Organometallics, 13, 1601 (1994).
527. W. A. Hermann, F. E. Kühn, and C. C. Romao, J. Organomet. Chem., 489, C56 (1995).
528. (a) A. H. Klahn-Oliva and D. Sutton, Organometallics, 3, 1313 (1984).
529. (b) W. A. Hermann, R. Serrano, and H. Bock, Angew. Chem. Int. Ed. Engl., 23, 383 (1984).
530. 3 derivative, see J. Okuda, E. Herdtweck, and W. A. Hermann, Inorg. Chem., 27, 1254 (1988).
531. (a) W. A. Hermann, J. Mol. Catal., 41, 109 (1987).
532. (b) W. A. Hermann, J. Organomet. Chem., 300, 111 (1986).
533. (c) W. A. Hermann, Angew. Chem. Int. Ed. Engl Ed.Engl., 27, 1297 (1988).
534. (d) W. A. Hermann, J. Organomet. Chem., 382, 1 (1990).
535. (a) J. Takacs, P. Kiprof, J. Riede, and W. A. Hermann, Organometallics, 9, 782 (1990).
536. (b) W. A. Hermann, W. Wagner, U. N. Flessner, U. Volkhardt, and H. Komber, Angew. Chem. Int. Ed. Engl., 30, 1636 (1991).
537. (c) W. A. Herrmann, R. W. Fischer, and D. W. Marz, Angew. Chem. Int. Ed. Engl., 30, 1638 (1991).
538. (d) W. A. Hermann and M. Wang, Angew. Chem. Int. Ed. Engl., 30, 1641 (1991).
539. W. A. Hermann, R. W. Fischer, M. U. Rauch, and W. Scherer, J. Mol. Catal., 86, 243 (1994).
540. (a) W. A. Hermann and R. W. Fischer, J. Am. Chem. Soc., 117, 3223 (1995).
541. (b) W. A. Hermann, W. Scherer, R. W. Fischer, J. Blümel, M. Kleine, W. Mertin, R. Gruehn, J. Mink, H. Boysen, C. C. Wilson, R. M. Ibberson, L. Bachmann, and M. Mattner, J. Am. Chem. Soc., 117, 3231 (1995).
542. (c) H. S. Genin, K. A. Lawler, R. Hoffmann, W. A. Herrmann, R. W. Fischer, and W. Scherer, J. Am. Chem. Soc., 117, 3244 (1995).
543. (a) I. A. Degnan, W. A. Herrmann, and E. Herdtweck, Chem. Ber., 123, 1347 (1990).
544. (b) I. A. Degnan, J. Behm, M. R. Cook, and W. A. Herrmann, Inorg. Chem., 30, 2165 (1991).
545. (a) A. Müller, E. Diemann, and V. V. K. Rao, Chem. Ber., 103, 2961 (1970).
546. (b) J. T. Goodman, S. Inomata, and T. B. Rauchfuss, J. Am. Chem. Soc., 118, 11674 (1996).
547. (c) H. H. Murray, L. Wei, S. E. Sherman, M. A. Greaney, K. A. Eriksen, B. Carstensen, T. R. Halben, and E. I. Stiefel, Inorg. Chem., 34, 841 (1995).
548. P. J. Blower, J. R. Dilworth, J. P. Hutchinson, and J. A. Zubieta, Inorg. Chim. Acta, 65, L225 (1982).
549. 2SH. See A. Davison, C. Orvig, H. S. Trop, M. Sohn, B. dePamphilis, and A. G. Jones, Inorg. Chem., 19, 1988 (1978).
550. S. K. Tahmassebi and J. M. Mayer, Organometallics, 14, 1039 (1995).
551. F. P. Guengerich and T. L. Macdonald, Acc. Chem. Res., 17, 9 (1984).
552. S. M. Nelson, in. Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 44.2.
553. (a) D.-H. Chin, A. L. Balch, and G. N. La Mar, J. Am. Chem. Soc., 102, 1446 (1980).
554. (b) G. Simonneaux, W. F. Scholz, C. A. Reed, and G. Lang, Biochim. Biophys. Acta, 716, 1 (1982).
555. III bromide derivative, so that the derived Fe=O bond length [1.604(19) Å] should be regarded with caution [sec (75)].
556. (a) J. E. Penner-Hahn, K. S. Eble, T. J. McMurry, M. Renner, A. L. Balch, J. T. Groves, J. H. Dawson, and K. O. Hodgson, J. Am. Chem. Soc., 108, 7819 (1986).
557. (b) J. E. Penner-Hahn, T. J. McMurry, M. Renner, L. Latos-Grazynsky, K. S. Eble, I. M. Davis, A. L. Balch, J. T. Groves, J. H. Dawson, and K. O. Hodgson, J. Biol. Chem., 258, 12761 (1983).
558. M. L. Hoppe, E. O. Schlemper, and R. K. Murmann, Acta Crystallogr., B38, 2237 (1982).
559. 2-, see R. J. Deeth, J. Chem. Soc. Faraday Trans., 89, 3745 (1993).
560. (a) K. Czarnecki, S. Nimri, Z. Gross, L. M. Proniewicz, and J. R. Kincaid, J. Am. Chem. Soc., 118, 2929 (1996), and references cited therein,
561. (b) M. Schappacher, G. Chottard, and R. Weiss, J. Chem. Soc. Chem. Commun., 93 (1986).
562. (a) M. Fanfarillo, H. E. Cribb, A. J. Downs, T. M. Greene, and M. J. Almond, Inorg. Chem., 31, 2962 (1992).
563. (b) M. Fanfarillo, A. J. Downs, T. M. Greene, and M. J. Almond, Inorg. Chem., 31, 2973 (1992).
564. M. Schröder and T. A. Stephenson, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 45.
565. (a) S. Perrier, T. C. Lau, and J. K. Kochi, Inorg. Chem., 29, 4190 (1990).
566. (b) S. Perrier and J. K. Kochi, Inorg. Chem., 27, 4165 (1988).
567. W. P. Griffith, in Comprehensive Coordination Chemistry, G. Wilkinson, R. D. Gillard, and J. A. McCleverty, Eds., Pergamon, Oxford, UK, 1987, Chapter 46.
568. M. Schröder, Chem. Rev., 80, 187 (1980).
569. For some recent theoretical calculations concerning the mechanisms of dihydroxylation of olefins, see (a) A. Veldkamp and G. Frenking, J. Am. Chem. Soc., 116, 4937 (1994).
570. (b) P.-O. Norrby, H. C. Kolb, and K. B. Sharpless, Organometallics, 13, 344 (1994).
571. (a) W. A. Nugent, R. L. Harlow, and R. J. McKinney, J. Am. Chem. Soc., 101, 7265 (1979).
572. (b) M. H. Schofield, T. P. Kee, J. T. Anhaus, R. R. Schrock, K. H. Johnson, and W. M. Davis, Inorg. Chem., 30, 3595 (1991).
573. (c) W. P. Griffith, A. C. Skapski, K. A. Woode, and M. J. Wright, Inorg. Chim. Acta, 31, L413 (1978).
574. (d) E. J. Corey, S. Sarshar, M. D. Azimioara, R. C. Newbold, and M. C. Noe, J. Am. Chem. Soc., 118, 7851 (1996).
575. (e) M. Nakajima, K. Tomioka, Y. Iitaka, and K. Koga, Tetrahedron, 49, 10793 (1993).
576. (a) P. Stavropoulos, P. G. Edwards, T. Behling, G. Wilkinson, M. Motevalli, and M. B. Hursthouse, J. Chem. Soc. Dalton Trans., 169 (1987).
577. (b) W. A. Hermann, S. J. Eder, and P. Kiprof, J. Organomet. Chem., 412, 407 (1991).
578. (c) W. A. Hermann, S. J. Eder, and P. Kiprof, J. Organomet. Chem., 413, 27 (1991).
579. (d) C. J. Longley, P. D. Savage, G. Wilkinson, B. Hussain, and M. B. Hursthouse, Polyhedron, 7, 1079 (1988).
580. (e) B. S. McGilligan, J. Arnold, G. Wilkinson, B. Hussain-Bates, and M. B. Hursthouse, J. Chem. Soc. Dalton Trans., 2465 (1990).
581. (f) W. A. Hermann, S. J. Eder, and W. Scherer, J. Organomet. Chem., 454, 257 (1993).
582. (g) R. W. Marshman, W. S. Bigham, S. R. Wilson, and P. A. Shapley, Organometallics, 9, 1341 (1990).
583. (h) S. J. Eder, W. A. Hermann, and P. J. Kiprof, J. Organomet. Chem., 428, 409 (1992).
584. W. A. Hermann, S. J. Eder, P. Kiprof, and P. Watzlowik, J. Organomet. Chem., 428, 187 (1992).
585. Q. Feng, H. Krautscheid, T. B. Rauchfuss, A. E. Skaugset, and A. Venturelli, Organometallics, 14, 297 (1995).
586. Likewise, only bridging chalcogenido and polyselenido complexes have so far been obtained for the pentamethylcyclopentadienyl osmium system. See M. Herberhold, G.-X. Jin, L. M. Liable-Sands, and A. L. Rheingold, J. Organomet. Chem., 519, 223 (1996).
587. M. Henary, W. C. Kaska, and J. I. Zink, Inorg. Chem., 28, 2995 (1989).
588. A. J. Downs, T. M. Greene, and C. M. Gordon, Inorg. Chem., 34, 6191 (1995).
589. M. A. Andrews, G. L. Gould, and E. J. Voss, Inorg. Chem., 35, 5740 (1996).
590. (a) H. C. E. McFarlane and W. McFarlane, in Multinuclear NMR, J. Mason, Ed., Plenum, New York, 1987; Chapter 15, pp. 417-435.
591. (b) N. P. Luthra and J. D. Odom, in The Chemistry of Organic Selenium and Tellurium Compounds, S. Patai, Ed., Wiley, New York, 1987; Vol. 1, Chapter 6, pp. 189-241.
592. (c) H. C. E. McFarlane and W. McFarlane, in NMR of Newly Accessible Nuclei, P. Laszlo, Ed., Academic, New York, 1983, Vol. 2, Chapter 10, pp. 275-299.
593. (d) D. H. O'Brien, K. J. Irgolic, and C.-K. Huang, in Proceedings of the Fourth International Conference on the Organic Chemistry of Selenium and Tellurium, F. J. Berry and W. R. McWhinnie, Eds., The University of Aston, Birmingham, UK, 1983; pp. 468-491.
594. (e) C. Rodger, N. Sheppard, C. McFarlane, and W. McFarlane, in NMR and the Periodic Table, R. K. Harris and B. E. Mann, Eds., Academic, New York, 1978, Chapter 12, pp. 383-419.
595. 77Se chemical shifts in the ranges δ 1000-2500 and δ 600-1000 ppm have been reported for terminal and bridging selenido ligands, respectively, in a variety of anionic polyselenide complexes of tungsten. See, for example, (a) R. W. M. Wardle, C. H. Mahler, C.-N. Chau, and J. A. Ibers, Inorg. Chem., 27, 2790 (1988).
596. (b) R. W. M. Wardle, S. Bhaduri, C.-N. Chau, and J. A. Ibers, Inorg. Chem., 27, 1747 (1988).
597. (c) Y.-J. Lu, M. A. Ansari, and J. A. Ibers, Inorg. Chem., 28, 4049 (1989).
598. (d) M. A. Ansari, C.-N. Chau, C. H. Mahler, and J. A. Ibers, Inorg. Chem., 28, 650 (1989).
599. (e) C. C. Christuk, M. A. Ansari, and J. A. Ibers, Inorg. Chem., 31, 4365 (1992).
600. (f) M. A. Ansari, C. H. Mahler, and J. A. Ibers, Inorg. Chem., 28, 2669 (1989).
601. (g) C. C. Christuk and J. A. Ibers, Inorg. Chem., 32, 5105 (1993).
602. 125Te NMR chemical shift data, see (a) H. C. E. McFarlane and W. McFarlane, J. Chem. Soc. Dalton Trans., 2416 (1973).
603. (b) M. Baiwir, G. Llabrès, L. Christiaens, M. Evers, and J.-L. Piette, Magn. Resort. Chem., 25, 129 (1987).
604. (a) D. H. O'Brien, N. Dereu, C.-K. Huang, and K. J. Irgolic, Organometallics, 2, 305 (1983).
605. (c) M. Baiwir, in Proceedings of the Fourth International Conference on the Organic Chemistry of Selenium and Tellurium, F. J. Berry and W. R. McWhinnie, Eds., The University of Aston, Birmingham, UK, 1983, pp. 406-467.
606. (d) M. Baiwir, G. Llabrès, A. Luxen, L. Christiaens, and J.-L. Piette, Org. Magn. Reson., 22, 312 (1984).
607. (e) M. Björgvinsson and G. J. Schrobilgen, Inorg. Chem., 30, 2540 (1991).
608. (f) T. Drakenberg, F. Fringuelli, S. Gronowitz, A.-B. Hörnfeldt, I. Johnson, and A. Taticchi, Cliem. Ser., 10, 139 (1976).
609. (g) T. Drakenberg, A.-B. Hörnfeldt, S. Gronowitz, J.-M. Talbot, and J.-L. Piette, Chem. Ser., 13, 152 (1979).
610. (h) G. A. Kalabin, R. B. Valeev, and D. F. Kushnarev, J. Org. Chem. USSR, 17, 830 (1981)
611. (translation from Zh. Org. Khim., 17, 947 (1981).
612. (i) E. A. V. Ebsworth, D. W. H. Rankin, and S. Cradock, Structural Methods in Inorganic Chemistry, 2nd ed., CRC Press, Boca Raton, FL, 1991.
613. Z. K. Sweeney, J. L. Poise, R. A. Andersen, R. G. Bergman, and M. G. Kubinec, J. Am. Chem. Soc., 119, 4543 (1997).
614. J. L. Kisko, T. Hascall, and G. Parkin, J. Am. Chem. Soc. 119, 7611 (1997).
615. K. B. P. Ruppa, N. Desmangles, S. Gambarotta, G. Yap, and A. L. Rheingold, Inorg. Chem., 36, 1194 (1997).