Oxygen-oxygen bond formation pathways promoted by ruthenium complexes

Accounts of Chemical Research

Volumn 42, Issue 12, 2009, Pages 1944-1953

  Romain, Sophie ^a   Vigara, Laura ^a   Llobet, Antoni ^a,b  

^a INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 72949110158     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar900240w     Document Type: Article

References (29)

1. 2 Formation Tracked by Time-Resolved X-ray Experiments. Science 2005, 310, 1019-1021.
2. Sala, X.; Romero, I.; Rodríguez, M.; Escriche, L.; Llobet, A. Water oxidation catalysts based on transition metal complexes. Angew. Chem., Int. Ed. 2009, 48, 2842-2852.
3. 2+ (Q = 3,5- di-tert-butyl-1,2-benzoquinone, tpy ) 2,2′:6′,2″-terpyridine) and Related Species through Experimental and Theoretical Studies. Inorg. Chem. 2009, 48, 4372-4383.
4. Francas, L.; Sala, X.; Benet-Buchholz, J.; Escriche, L.; Llobet, A. Ru-Hbpp based water oxidation catalyst anchored in TiO2-rutile. ChemSusChem 2009, 2, 321-329.
5. Barber, J. Photosynthetic energy conversion: natural and artificial. Chem. Soc. Rev. 2009, 38, 185-196.
6. Meyer, T. J.; Huynh, M. H. V. The Remarkable Reactivity of High Oxidation State Ruthenium and Osmium Polypyridyl Complexes. Inorg. Chem. 2003, 42, 8140-8160.
7. Huynh, M. H. V.; Meyer, T. J. Proton-Coupled Electron Transfer. Chem. Rev. 2007, 107, 5004-5064.
8. Meyer, T. J.; Huynh, M. H. V.; Thorp, H. H. The Possible Role of Proton-Coupled Electron Transfer (PCET) in Water Oxidation by Photosystem II. Angew. Chem., Int. Ed. 2007, 46, 5284-5304.
9. Zheng, J.; Wang, D.; Thiel, W.; Shaik, S. QM/MM Study of Mechanisms for Compound I Formation in the Catalytic Cycle of Cytochrome P450cam. J. Am. Chem. Soc. 2006, 128, 13204-13215.
10. Gao, Y.; Akermark, T.; Liu, J.; Sun, L.; Akermark, B. Nucleophilic Attack of Hydroxide on a MnV Oxo Complex: A Model of the O-O Bond Formation in the Oxygen Evolving Complex of Photosystem II. J. Am. Chem. Soc. 2009, 131, 8726-8727.
11. Welch, T. W.; Ciftan, S. A.; White, P. S.; Thorp, H. H. Electron-Rich Oxoruthenium(IV) Cleavage Agents: A Zero-Order Rate Law for DNA Catalysis. Inorg. Chem. 1997, 36, 4812-4821.
12. Vigara, L. Llobet, A. Work in progress.
13. 2+. J. Am. Chem. Soc. 2008, 130, 16462-16463.
14. Masllorens, E.; Rodríguez, M.; Romero, I.; Roglans, A.; Parella, T.; Benet-Buchholz, J.; Poyatos, M.; Llobet, A. Can the Disproportion of Oxidation State III Be Favored in RuII-OH2/RuIV=O Systems. J. Am. Chem. Soc. 2006, 128, 5306-5307.
15. Tseng, H.-W.; Zong, R.; Muckerman, J. T.; Thummel, R. Mononuclear Ruthenium(II) Complexes That Catalyze Water Oxidation. Inorg. Chem. 2008, 47, 11763-11773.
16. Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni, S. Luminescent and Redox-Active Polynuclear Transition Metal Complexes. Chem. Rev. 1996, 96, 759-834.
17. 4+. J. Am. Chem. Soc. 1985, 107, 3855-3864.
18. Batista, E. R.; Martin, R. L. Electron Localization in the Ground State of the Ruthenium Blue Dimer. J. Am. Chem. Soc. 2007, 129, 7224-7225.
19. 4+. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 17632-17635.
20. 8-: A Totally Inorganic Oxygen-Evolving Catalyst. J. Am. Chem. Soc. 2008, 130, 5006-5007.
21. (b) Geletii, Y. V.; Botar, B.; Kogerler, P.; Hillesheim, D. A.; Musaev, D. G.; Hill, C. L. An All- Inorganic, Stable, and Highly Active Tetraruthenium Homogeneous Catalyst for Water Oxidation. Angew. Chem., Int. Ed. 2008, 47, 3896-3899.
22. Sens, C.; Romero, I.; Rodríguez, M.; Llobet, A.; Parella, P.; Benet-Buchholz, J. A New Ru Complex Catalyst Capable of Catalitically Oxidizing Water to Molecular Dioxygen. J. Am. Chem. Soc. 2004, 126, 7798-7799.
23. Romain, S.; Bozoglian, F.; Sala, X.; Llobet, A. Oxygen-Oxygen Bond Formation by the Ru-Hbpp Water Oxidation Catalyst Occurs Solely via an Intramolecular Reaction Pathway. J. Am. Chem. Soc. 2009, 131, 2768-2769.
24. Bozoglian, F.; Romain, S.; Ertem, M. Z.; Todorova, T. K.; Sens, C.; Mola, J.; Rodríguez, M.; Romero, I.; Benet-Buchholz, J.; Fontrodona, X.; Cramer, C. J.; Gagliardi, L.; Llobet, A. The Ru-Hbpp Water Oxidation Catalyst. J. Am. Chem. Soc. 2009, 131, 15176-15187.
25. 2 Evolution from Water Promoted by a Metal Complex. Science 2009, 324, 74-77.
26. 2O. Angew. Chem., Int. Ed. 2000, 39, 1479-1482.
27. Muckerman, J. T.; Polyansky, D. E.; Wada, T.; Tanaka, K.; Fujita, E. Water Oxidation by a Ruthenium Complex with Noninnocent Quinone Ligands: Possible Formation of an O-O Bond at a Low Oxidation State of the Metal. Inorg. Chem. 2008, 47, 1787-1802.
28. 4+-Catalyzed Water Oxidation. J. Am. Chem. Soc. 2008, 130, 827-829.
29. (IV) Dimer Complex with [HOHOH]-BL as an Intermediate for Catalytic Water Oxidation. J. Am. Chem. Soc. 2009, 131, 10397-10399.