A late-transition metal oxo complex: K7Na9[O=Pt IV(H2O)L2], L = [PW9O 34]9-

Science

Volumn 306, Issue 5704, 2004, Pages 2074-2077

  Anderson, Travis M ^a   Neiwert, Wade A ^a,d   Kirk, Martin L ^b   Piccoli, Paula M B ^c   Schultz, Arthur J ^c   Koetzle, Thomas F ^c   Musaev, Djamaladdin G ^a   Morokuma, Keiji ^a   Cao, Rui ^a   Hill, Craig L ^a  

^a EMORY UNIVERSITY   (United States)

^b UNIVERSITY OF NEW MEXICO   (United States)

^c ARGONNE NATIONAL LABORATORY   (United States)

^d BETHEL UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONS; HYDROGEN BONDS; MOLECULAR DYNAMICS; PROBABILITY DENSITY FUNCTION; SYNTHESIS (CHEMICAL); TRANSITION METAL ALLOYS;

ELECTRON WITHDRAWAL; LIGANDS; METAL OXO COMPLEX; MOLECULAR ORBITS;

COMPLEXATION;

METAL COMPLEX; PLATINUM COMPLEX; SODIUM DERIVATIVE; TUNGSTEN DERIVATIVE;

TRANSITION ELEMENT;

ARTICLE; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; METAL BINDING; MOLECULAR DYNAMICS; MOLECULAR STABILITY; NEUTRON DIFFRACTION; PRIORITY JOURNAL; X RAY DIFFRACTION;

CHEMISTRY, PHYSICAL; CRYSTALLIZATION; CRYSTALLOGRAPHY, X-RAY; ELECTRONS; FOURIER ANALYSIS; HYDROGEN-ION CONCENTRATION; LIGANDS; MOLECULAR STRUCTURE; NEUTRON DIFFRACTION; OXIDATION-REDUCTION; OXYGEN; PLATINUM; PLATINUM COMPOUNDS; SPECTRUM ANALYSIS; TEMPERATURE; TUNGSTEN; TUNGSTEN COMPOUNDS;

EID: 19944409309     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.1104696     Document Type: Article

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38. We thank J. Reibenspies at Texas A & M University for collecting the low temperature x-ray data set and I. A. Weinstock for useful discussions. Supported by the U.S. Department of Energy (DOE) (C.H., J.M., and K.M.), the NSF (grant no. CHE-0236686 to C.H.), and the NIH (grant no. GM-057378 to M.L.K.). The work at Argonne National Laboratory was supported by the DOE Office of Basic Energy Sciences (contract no. W-31-109-ENG-38). Additional details on the crystal structure investigations may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany, on quoting registry nos. CSD-414500 and CSD-414522 (neutron) for 1 and CSD-414501 for 2 and 3.