Reversal of stereoselectivity in the Cu-catalyzed conjugate addition reaction of dialkylzinc to cyclic enone in the presence of a chiral azolium compound

Journal of Organic Chemistry

Volumn 75, Issue 16, 2010, Pages 5707-5715

  Shibata, Naoatsu ^a   Okamoto, Masaki ^a   Yamamoto, Yuko ^a   Sakaguchi, Satoshi ^a  

^a KANSAI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ALCOHOLS; ASYMMETRIC CONJUGATE ADDITION; AZOLIUM SALTS; BEST CHOICE; CATALYZED REACTIONS; CHIRAL LIGAND; CONJUGATE ADDITION REACTIONS; ENANTIOCONTROL; IMIDAZOLIUM; LIGAND PRECURSORS; METHYL ESTERS; REACTION CATALYZED; SCREENING TESTS; SEVEN-MEMBERED RINGS; SIDE CHAINS; STEREOGENIC CENTERS; TERT-BUTYL GROUP;

ALCOHOLS; AMINO ACIDS; CATALYSIS; ENANTIOSELECTIVITY; ESTERS; LIGANDS; ORGANIC POLYMERS; STEREOSELECTIVITY; ZINC;

ADDITION REACTIONS;

2 CYCLOHEPTEN 1 ONE; AMINOALCOHOL; BENZYL DERIVATIVE; COPPER; CYCLOHEPTENE; ESTER DERIVATIVE; IMIDAZOLE DERIVATIVE; LEUCINEMETHYL ESTER; LIGAND; TERT BUTYL ALCOHOL; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

ADDITION REACTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHIRALITY; CONJUGATE; ENANTIOMER; ENANTIOSELECTIVITY; SCREENING TEST; STEREOCHEMISTRY;

AZOLES; CATALYSIS; COPPER; KETONES; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; STEREOISOMERISM; ZINC;

EID: 77955682530     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo101147p     Document Type: Article

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