Chiral bis(NHC)-palladium(II) complex catalyzed and diethylzinc-mediated enantioselective umpolung allylation of aldehydes

Organometallics

Volumn 28, Issue 8, 2009, Pages 2640-2642

  Wang, Wenfeng ^a   Zhang, Tao ^a   Shi, Min ^a,b  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLATION; COUNTERIONS; DIASTEREOSELECTIVITIES; DIETHYLZINC; ENANTIOSELECTIVE; HOMOALLYLIC ALCOHOL; PALLADIUM COMPLEXES; UMPOLUNG;

ALDEHYDES; ENANTIOSELECTIVITY; PALLADIUM;

PALLADIUM COMPOUNDS;

EID: 65649143846     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900109m     Document Type: Article

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40. The crystal data of 4c have been deposited with the CCDC as No. 683364. Selected data: empirical formula, C60H46Br2N4O2Pd; formula weight, 1121.23; crystal color and habit, colorless and prismatic; crystal dimensions, 0.321 x 0.178 x 0.166 mm; crystal system, orthorhombic; lattice type, primitive; lattice parameters, a = 10.0949(7) A, b = 20.4152(16) A, c = 24.5195(19) A, a = 90°, = 90°, y = 90°, V = 5053.2(7) A3; space group, P212121; Z = 4; >calcd = 1.474 g/cm3; F000 = 2264; diffractometer, Rigaku AFC7R; residuals R and Rw, 0.0654 and 0.1298.
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