Enantioselective synthesis of allylsilanes bearing tertiary and quaternary si-substituted carbons through Cu-catalyzed allylic alkylations with alkylzinc and arylzinc reagents

Angewandte Chemie - International Edition

Volumn 46, Issue 24, 2007, Pages 4554-4558

  Kacprzynski, Monica A ^a   May, Tricia L ^a   Kazane, Stephanie A ^a   Hoveyda, Amir H ^a  

^a BOSTON COLLEGE   (United States)

Author keywords

Allylation; Allylsilanes; Asymmetric catalysis; N heterocyclic carbenes; Quaternary stereocenters

Indexed keywords

ALLYLSILANES; ASYMMETRIC CATALYSIS; N-HETEROCYCLIC CARBENES; QUATERNARY STEREOCENTERS;

CATALYSIS; CHIRALITY; COPPER; ORGANIC COMPOUNDS; SYNTHESIS (CHEMICAL);

ENANTIOSELECTIVITY;

ALKENE; ALLYLSILANE; COPPER; SILANE DERIVATIVE; UNCLASSIFIED DRUG; ZINC;

ALKYLATION; ARTICLE; CATALYSIS; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

ALKENES; ALKYLATION; CATALYSIS; COPPER; SILANES; STEREOISOMERISM; ZINC;

EID: 34250704681     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200700841     Document Type: Article

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