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For unquenched quantum yield and lifetimes, we consider here the values of 6 and for the quenched figures we consider the quantum yields and lifetimes (on exciting at a wavelength at which absorption of the higher-energy Bodipy is maximized, that is, 480 nm) of the high-energy emission, of 1 and 2.
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93
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77955141397
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note
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It can be noted that the rate constants calculated by Equation (2) are always slightly larger than those calculated by Equation (1). This could be due to the presence of trace impurities of starting compounds missing the acceptor subunits. Please note that traces of such impurities, even under the level of detection by any other method, could affect the quantum yield data, whereas they do not affect the lifetime data, which are therefore considered to be more reliable values.
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Energy-transfer rate constants calculated by Equation (3) have also led to values larger than experimental ones for other systems in which aminostyryl-substituted Bodipy molecules - and as a consequence CT states - were involved.[41]
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77955145987
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The decreased emission quantum yield of the protonated chromophore relative to the unprotonated species could be due to effective participation of the protonated bipyridine moiety in the radiationless decay. However, this aspect is not investigated here.
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