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85034553550
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note
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Under this circumstance, it could be questioned whether a real change in the direction of energy transfer occurs, in that the electronic energy is in any case initially directed to the same, lowest-lying subunit. However, in case the luminescence output origins from the other subunit as a consequence of the thermally activated process, a reverse energy migration takes place within the excited state lifetime.
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Similar synthetic procedures have also been reported: a) G. S. Hanan, C. R. Arana, J.-M. Lehn, D. Fenske, Angew. Chem. 1995, 107, 1191; Angew. Chem. Int. Ed. Engl. 1995, 34, 1122;
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85034564271
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note
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[21]).
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52
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85034548874
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56
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85034535946
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note
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The difference in space domain, although it is correct in principle, should be treated with care when it refers to relatively small molecules.
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-
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