Development of a formal [4+1] cycloaddition: Pd(OAc) 2-catalyzed intramolecular cyclopropanation of 1,3-dienyl β-keto esters and MgI 2-promoted vinylcyclopropane-Cyclopentene rearrangement

Journal of the American Chemical Society

Volumn 131, Issue 7, 2009, Pages 2496-2498

  Coscia, Rockford W ^a   Lambert, Tristan H ^a  

^a Columbia University ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPENTENE; CYCLOPROPANATION; INTRAMOLECULAR CYCLOPROPANATION; KETO ESTER; SUBSTITUTION PATTERNS; TAUTOMERIZATION; TWO-STEP PROCESS; VINYLCYCLOPROPANE;

ESTERIFICATION; PALLADIUM; PALLADIUM COMPOUNDS;

ESTERS;

CYCLOPENTENE DERIVATIVE; CYCLOPROPANE DERIVATIVE; ESTER DERIVATIVE; MAGNESIUM DERIVATIVE; MAGNESIUM IODIDE; PALLADIUM ACETATE; UNCLASSIFIED DRUG; VINYLCYCLOPROPANE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLOADDITION; CYCLOPROPANATION;

EID: 67849114630     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja809226x     Document Type: Article

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