Mechanistic study of β-hydrogen elimination from organoplatinum(II) enolate complexes

Journal of the American Chemical Society

Volumn 130, Issue 46, 2008, Pages 15627-15635

  Alexanian, Erik J ^a   Hartwig, John F ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CONCENTRATION (PROCESS); ELECTRONIC PROPERTIES; HYDROGEN; LIGANDS; METHANE; NONMETALS; PHOSPHORUS COMPOUNDS; RATE CONSTANTS; REACTION RATES; STEREOCHEMISTRY;

ALKYL COMPLEXES; ALKYL LIGANDS; ALKYL SUBSTITUENTS; BISPHOSPHINE; ELECTRONIC DIFFERENCES; ELECTRONIC EFFECTS; ENOLATE; H BONDS; HYDROGEN ELIMINATIONS; KINETIC ISOTOPE EFFECTS; KINETIC STUDIES; MECHANISTIC INVESTIGATIONS; MECHANISTIC STUDIES; ORGANOPLATINUM; REDUCTIVE ELIMINATIONS; REVERSIBLE DISSOCIATIONS; STERIC PROPERTIES; THERMAL REACTIONS; TWO TYPES;

COORDINATION REACTIONS;

ALKYL GROUP; HYDROGEN; ISOTOPE; LIGAND; METHANE; PHOSPHINE DERIVATIVE; PLATINUM COMPLEX;

ARTICLE; CHEMICAL STRUCTURE; CONCENTRATION (PARAMETERS); DECOMPOSITION; DISSOCIATION; ELECTRON; ELIMINATION REACTION; HYDROGEN BOND; ISOTOPE ANALYSIS; KINETICS; MOLECULAR ELECTRONICS; MOLECULAR MECHANICS; STEREOCHEMISTRY; STEREOSPECIFICITY; STRUCTURE ANALYSIS;

ALKYLATION; ELECTRONS; HYDROGEN; KETONES; KINETICS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOPLATINUM COMPOUNDS;

EID: 56449123856     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8056908     Document Type: Article

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