Diastereoselective addition of zincated hydrazones to alkenylboronates and stereospecific trapping of boron/zinc bimetallic intermediates by carbon electrophiles

Journal of the American Chemical Society

Volumn 130, Issue 46, 2008, Pages 15688-15701

  Hatakeyama, Takuji ^a,b   Nakamura, Masaharu ^a,b   Nakamura, Eiichi ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; BORON; CARBON; CHEMICAL BONDS; CONDENSATION REACTIONS; DENSITY FUNCTIONAL THEORY; KETONES; STEREOSELECTIVITY; ZINC;

ASYMMETRIC INDUCTION; BOAT CONFORMATIONS; C-C BOND FORMATION; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE ADDITIONS; STEREOGENIC CENTERS; STERIC REPULSIONS; TRANSITION STRUCTURES;

ADDITION REACTIONS;

ALKENYLBORONATE; BORON DERIVATIVE; CARBON; HYDRAZONE DERIVATIVE; UNCLASSIFIED DRUG; ZINC;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONFORMATIONAL TRANSITION; DENSITY FUNCTIONAL THEORY; DIASTEREOSELECTIVE; STEREOCHEMISTRY; STEREOSPECIFICITY;

EID: 56449117142     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja806258v     Document Type: Article

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