Demonstration of prominent Cu(ll)-promoted leaving group stabilization of the cleavage of a homologous set of phosphate Mono-, Di-, and triesters in methanol

Journal of the American Chemical Society

Volumn 132, Issue 10, 2010, Pages 3561-3573

  Tony Liu, C ^a   Neverov, Alexei A ^a   Maxwell, Christopher I ^a   Stan Brown, R ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

1 ,10-PHENANTHROLINE; ACTIVATION PARAMETER; CATALYZED REACTIONS; CONTROLLED CONDITIONS; CU COMPLEXES; DIANIONS; DIESTERS; DIMETHYL PHOSPHATES; DISSOCIATION CONSTANT; DRIVING FORCES; EMERGING PRODUCTS; LEAVING GROUPS; MONOANIONS; PLATEAU REGION; TRIESTERS;

DISSOCIATION; IONIZATION; METHANOL;

COORDINATION REACTIONS;

1,10 PHENANTHROLINE; 2 (2 PHENANTHROLYL) PHENYL DIMETHYL PHOSPHATE; 2 (2 PHENANTHROLYL) PHENYL METHYL PHOSPHATE; 2 (2' PHENANTHROLYL) PHENYL PHOSPHATE; 2' (2 PHENOXY) 1,10 PHENANTHROLINE; 4 NITROPHENYLPHOSPHATASE; COPPER COMPLEX; CUPRIC ION; DIESTER; ESTER; METHANOL; MONOESTER; NUCLEOPHILE; PHOSPHATE; TRIESTER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CONTROLLED STUDY; DECOMPOSITION; DISSOCIATION CONSTANT; ENERGY; FORCE; IONIZATION; KINETICS; METHANOLYSIS; PH MEASUREMENT; TITRIMETRY;

CATIONS, DIVALENT; COPPER; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; METHANOL; PHENANTHROLINES; PHOSPHORIC ACID ESTERS; SPECTROPHOTOMETRY, ULTRAVIOLET; THERMODYNAMICS;

EID: 77949355606     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja910111q     Document Type: Article

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