Dinuclear Zn(II) complex promotes cleavage and isomerization of 2-hydroxypropyl alkyl phosphates by a common cyclic phosphate intermediate

Journal of the American Chemical Society

Volumn 131, Issue 11, 2009, Pages 4159-4166

  Tsang, Wing Yin ^a   Edwards, David R ^a   Melnychuk, Stephanie A ^a   Liu, C Tony ^a,b   Liu, Chaomin ^a   Neverov, Alexei A ^a   Williams, Nicholas H ^b   Brown, R Stan ^a  

^a QUEEN S UNIVERSITY   (Canada)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYLATION; CATALYSIS; GROUP TECHNOLOGY; ISOMERS; METHANOL; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOSPHATES; PROPANE; THERMODYNAMICS; ZINC; ZINC COMPOUNDS;

1H-NMR SPECTRA; ARYL PHOSPHATE; CATALYTIC REACTIONS; CLEAVAGE PRODUCTS; CONCERTED REACTIONS; CYCLIC PHOSPHATES; DETAILED KINETICS; DINUCLEAR; DOMINANT PROCESS; H NMR SPECTRA; ISOMERIC PRODUCTS; LEAVING GROUPS; P-NITROPHENYL PHOSPHATE; PHOSPHORANE; REACTION MIXTURE; STARTING MATERIALS; THERMODYNAMIC MIXTURES; TIME-DEPENDENT; TIME-SCALE; TRANSITION STATE; ZN COMPLEX;

MIXTURES;

1 HYDROXYPROPAN 2 YL METHYL PHOSPHATE; 2 HYDROXYPROPYLMETHYL PHOSPHATE; 4 METHYLETHYLENE PHOSPHATE; ALKYL GROUP; BIS 1,3 N1,N1' (1,5,9 TRIAZACYCLODODECYL)PROPANE; LACTIC ACID DERIVATIVE; METHANOL; PHOSPHATE; PHOSPHORANE DERIVATIVE; UNCLASSIFIED DRUG; ZINC COMPLEX; ORGANOPHOSPHATE; ZINC;

ARTICLE; CALCULATION; CATALYSIS; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; CYCLIZATION; ISOMER; ISOMERIZATION; PH; PHASE TRANSITION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; THERMODYNAMICS; CHEMICAL REACTION; CHEMISTRY; ISOMERISM; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CHEMICAL PROCESSES; ISOMERISM; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOPHOSPHATES; ZINC;

EID: 67849095713     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja900525t     Document Type: Article

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