Leaving group assistance in the La3+-catalyzed cleavage of dimethyl (o-methoxycarbonyl)aryl phosphate triesters in methanol

Journal of the American Chemical Society

Volumn 131, Issue 38, 2009, Pages 13738-13748

  Edwards, David R ^a   Liu, C Tony ^a   Garrett, Graham E ^a   Neverov, Alexei A ^a   Brown, R Stan ^a  

^a QUEEN S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ARYL GROUP; ARYL PHOSPHATE; ARYLOXY; CATALYTIC COMPLEXES; CATALYTIC RATES; CLEAVAGE RATES; CONCERTED REACTIONS; LEAVING GROUPS; METHANOLYSIS; NITROPHENYL PHOSPHATES; SECOND ORDERS; SECOND-ORDER RATE CONSTANTS; SPECIATION DIAGRAMS; THREE COMPONENT; TRANSITION STATE; TRIESTERS;

FUNCTIONAL GROUPS; METHANOL; OLIGOMERS; SUBSTRATES;

RATE CONSTANTS;

CARBONYL DERIVATIVE; DIMER; ESTER DERIVATIVE; LANTHANUM; METHANOL; PHOSPHATE;

ARTICLE; CATALYSIS; CHEMICAL REACTION; COMPARATIVE STUDY; CONCENTRATION (PARAMETERS); METHANOLYSIS; OBSERVATIONAL STUDY; PARAMETER; PH; SPECIES;

CATALYSIS; ESTERS; LANTHANUM; METHANOL; PHOSPHORIC ACID ESTERS;

EID: 70349742472     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja904659e     Document Type: Article

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