Efficient intramolecular general acid catalysis of nucleophilic attack on a phosphodiester

Journal of the American Chemical Society

Volumn 128, Issue 51, 2006, Pages 16944-16952

  Kirby, Anthony J ^a   Lima, Marcelo F ^b   Da Silva, Davi ^b   Roussev, Christo D ^a   Nome, Faruk ^b  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b FEDERAL UNIVERSITY OF SANTA CATARINA   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

NEGATIVE CHARGES; NUCLEOPHILES; PHOSPHODIESTERS; PROTONATION;

AMINO ACIDS; CATALYSIS; DERIVATIVES; HYDROGEN BONDS; HYDROLYSIS; REACTION KINETICS;

ESTERS;

AMINE; AMMONIUM DERIVATIVE; DIMETHYLAMMONIUM; METHYL 8 DIMETHYLAMINO 1 NAPHTHYL PHOSPHATE; PHOSPHATE; PHOSPHODIESTER; UNCLASSIFIED DRUG;

AB INITIO CALCULATION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; HYDROGEN BOND; HYDROLYSIS; METHYLATION; MOLECULAR MODEL; PH MEASUREMENT; REACTION ANALYSIS;

CATALYSIS; HYDROGEN BONDING; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; HYDROXYLAMINE; MODELS, MOLECULAR; MOLECULAR STRUCTURE; NAPHTHALENES; OXIDATION-REDUCTION; PHOSPHATES; PHOSPHORIC ACID ESTERS; STEREOISOMERISM; THERMODYNAMICS;

EID: 33845919294     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja066439u     Document Type: Article

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