Efficient phosphodiester binding and cleavage by a ZnII complex combining hydrogen-bonding interactions and double lewis acid activation

Angewandte Chemie - International Edition

Volumn 45, Issue 42, 2006, Pages 7056-7059

  Feng, Guoqiang ^b   Natale, Daniela ^a   Prabaharan, Ravi ^a   Mareque Rivas, Juan C ^a   Williams, Nicholas H ^b  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

Dinuclear complexes; Enzyme models; Hydrogen bonds; Phosphate ester cleavage; Receptors

Indexed keywords

CATALYSIS; HYDROGEN BONDS; INORGANIC ACIDS; PHOSPHATES; RNA; WATER;

DINUCLEAR COMPLEXES; ENZYME MODELS; PHOSPHATE ESTER CLEAVAGES;

ZINC COMPOUNDS;

ESTER; NITROPHENOL; NITROPHENYL PHOSPHATE; ORGANOPHOSPHORUS COMPOUND; ZINC DERIVATIVE;

ARTICLE; CHEMISTRY; CRYSTALLIZATION; HYDROGEN BOND; HYDROLYSIS; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH;

CRYSTALLIZATION; ESTERS; HYDROGEN BONDING; HYDROGEN-ION CONCENTRATION; HYDROLYSIS; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; NITROPHENOLS; ORGANOPHOSPHORUS COMPOUNDS; ZINC COMPOUNDS;

EID: 33750626211     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200602532     Document Type: Article

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46. Experimental details can be found in the Supporting Information.