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Volumn 28, Issue 6, 2009, Pages 1631-1643

Activation of Carbon Monoxide by (Me3tpa)Rh and (Me 3tpa)Ir

Author keywords

[No Author keywords available]

Indexed keywords

CARBONATE COMPLEXES; CARBONYL COMPLEXES; CO MOLECULES; EPR SPECTROSCOPIES; IRIDIUM COMPLEXES; LIGAND COORDINATES; N-DONOR LIGANDS; ONE-ELECTRON OXIDATIONS; PRESENCE OF WATERS; REDOX PROPERTIES; RHODIUM COMPLEXES; ROOM TEMPERATURES; TETRADENTATE; TIME-SCALE; WATER GAS SHIFT REACTIONS; X- RAY DIFFRACTIONS;

EID: 64649089905     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om801142y     Document Type: Article
Times cited : (26)

References (79)
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    • (e) For a review on models for Rh-mediated olefin oxygenation catalysis see: de Bruin, B.; Budzelaar, P. H. M.; Gal, A. W. Angew. Chem., Int. Ed. 2004, 43, 4142-4157.
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  • 21
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    • + complexes, revealing a shoulder in the IR and a single NMR peak corresponding to the coordinated CO molecule:(a) Kretzer, R. M.; Ghalidi, R. A.; Lebeau, E. L.; Liang, H.-C.; Karlin, K. D. Inorg. Chem. 2003, 42, 3016-3025.
    • + complexes, revealing a shoulder in the IR and a single NMR peak corresponding to the coordinated CO molecule:(a) Kretzer, R. M.; Ghalidi, R. A.; Lebeau, E. L.; Liang, H.-C.; Karlin, K. D. Inorg. Chem. 2003, 42, 3016-3025.
  • 31
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    • + complex has an ethene C-C bond distance equal to 1.44 Å (vs 1.34 and 1.54 Å for ethene and ethane, respectively), which suggests a significant rhodo(IH)cyclopropane contribution to the Rh-ediene interactions.
    • + complex has an ethene C-C bond distance equal to 1.44 Å (vs 1.34 and 1.54 Å for ethene and ethane, respectively), which suggests a significant rhodo(IH)cyclopropane contribution to the Rh-ediene interactions.
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    • The peak separation of cobaltocene used as internal standard in the measurement was 124 mV. In this case we would expect a fully reversible wave with a peak separation equal to 59 mV.
    • The peak separation of cobaltocene used as internal standard in the measurement was 124 mV. In this case we would expect a fully reversible wave with a peak separation equal to 59 mV.
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    • Although no X-ray diffraction data were available for 72, we assume that the hydride is coordinated trans to the weaker donating amine, and CO is coordinated trans to the stronger donating lutidyl moiety. Also for steric reasons, coordination of hydride trans to the amine seems is more probable, since this position is strongly shielded by two methyl groups of the coordinated lutidine fragments
    • 2+, we assume that the hydride is coordinated trans to the weaker donating amine, and CO is coordinated trans to the stronger donating lutidyl moiety. Also for steric reasons, coordination of hydride trans to the amine seems is more probable, since this position is strongly shielded by two methyl groups of the coordinated lutidine fragments.
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    • + aminyl radical, and traces of water were considered as the hydrogen atom source:Donati, N.; Stein, D.; Büttner, T.; Schönberg, H.: Harmer, J.: Anadaram, S.; Grützmacher, H. Eur. J. Inorg. Chem. 2008, 4691-4703.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.