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The peak separation of cobaltocene used as internal standard in the measurement was 124 mV. In this case we would expect a fully reversible wave with a peak separation equal to 59 mV.
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The peak separation of cobaltocene used as internal standard in the measurement was 124 mV. In this case we would expect a fully reversible wave with a peak separation equal to 59 mV.
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Although no X-ray diffraction data were available for 72, we assume that the hydride is coordinated trans to the weaker donating amine, and CO is coordinated trans to the stronger donating lutidyl moiety. Also for steric reasons, coordination of hydride trans to the amine seems is more probable, since this position is strongly shielded by two methyl groups of the coordinated lutidine fragments
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2+, we assume that the hydride is coordinated trans to the weaker donating amine, and CO is coordinated trans to the stronger donating lutidyl moiety. Also for steric reasons, coordination of hydride trans to the amine seems is more probable, since this position is strongly shielded by two methyl groups of the coordinated lutidine fragments.
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85153267383
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de Gelder, R.4
García-Granda, S.5
Gould, R.O.6
Israël, R.7
Smits, J.M.M.8
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