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Volumn 45, Issue 20, 2006, Pages 8342-8354

Syntheses, characterization, and catalytic ability in alkane oxygenation of chloro(dimethyl sulfoxide)ruthenium(II) complexes with tris(2-pyridylmethyl) amine and its derivatives

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EID: 33750323502     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060722c     Document Type: Article
Times cited : (44)

References (82)
  • 2
    • 33750295689 scopus 로고    scopus 로고
    • note
    • 3-TPA = tris[2-(5-methoxycarbonyl)pyridylmethyl]amine; TQA = tris(2-quinolylmethyl)amine; BPGH = bis(2-pyridylmethyl)glycine.
  • 3
    • 33750288776 scopus 로고    scopus 로고
    • note
    • The survey of the Cambridge Crystallographic Data Centre revealed that the crystal structures of the transition-metal complexes of TPA and derivatives of V, Cr, Mn, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Cu, Nd, Eu, Tb, Lu, and U have been reported.
  • 4
    • 0003735525 scopus 로고    scopus 로고
    • Kluwer Academic Publishers: Dordrecht, The Netherlands, Chapter 3
    • (a) Funabiki, T. Oxygenases and Model Systems; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1997; Chapter 3.
    • (1997) Oxygenases and Model Systems
    • Funabiki, T.1
  • 16
    • 0002655049 scopus 로고    scopus 로고
    • Ruthenium catalysts containing TPA or its derivatives: (a) Kojima, T. Chem. Lett. 1996, 121-122.
    • (1996) Chem. Lett. , pp. 121-122
    • Kojima, T.1
  • 21
    • 0001510851 scopus 로고
    • Ruthenium catalysts containing a ligand(s) other than TPA: (a) Che, C.-M. Pure Appl. Chem. 1995, 67, 225-232.
    • (1995) Pure Appl. Chem. , vol.67 , pp. 225-232
    • Che, C.-M.1
  • 46
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Göttingen, Germany
    • Sheldrick, G. M. SHELXL-97; University of Göttingen: Göttingen, Germany, 1997.
    • (1997) SHELXL-97
    • Sheldrick, G.M.1
  • 48
    • 1242351767 scopus 로고    scopus 로고
    • Tris(2-fluoro-6-pyridylmethyl)amine was also prepared from 2-fluoro-6-(bromomethyl)pyridine by an analogous procedure, although the yield was moderate (40%). Machkour, A.; Mandon, D.; Lachkar, M.; Welter, R. Inorg. Chem. 2004, 43, 1545-1550.
    • (2004) Inorg. Chem. , vol.43 , pp. 1545-1550
    • Machkour, A.1    Mandon, D.2    Lachkar, M.3    Welter, R.4
  • 49
    • 33750328126 scopus 로고    scopus 로고
    • note
    • 4 in ref 14. See the text.
  • 56
    • 33750342810 scopus 로고    scopus 로고
    • note
    • The crystal of 6 contains two independent complex ions in the asymmetric unit.
  • 62
    • 33750316573 scopus 로고
    • The Chemical Society of Japan, Maruzen: Tokyo, Japan
    • According to Kojima et al. in ref 14, the S-O bond length of free DMSO was 1.47 Å: Kagaku Binran, Kisohen; The Chemical Society of Japan, Maruzen: Tokyo, Japan, 1966; Vol. II, p 1222.
    • (1966) Kagaku Binran, Kisohen , vol.2 , pp. 1222
  • 63
    • 33750317939 scopus 로고
    • The Chemical Society of Japan, Maruzen: Tokyo, Japan
    • However, the value was revised to be 1.485 Å in: Kagaku Binran, Kisohen, 3rd ed.; The Chemical Society of Japan, Maruzen: Tokyo, Japan, 1984; Vol. II, p 658.
    • (1984) Kagaku Binran, Kisohen, 3rd Ed. , vol.2 , pp. 658
  • 65
    • 33750354681 scopus 로고    scopus 로고
    • note
    • The thermal isomerization experiment was attempted in MeOH, either. However, after heating at 60°C for 5 h, only a small change in the UV/visible absorption spectrum, which did not correspond to that of the isomerization reaction, was observed. It is assumed that the thermal isomerization rate in MeOH is very slow and/or the ligand substitution by a solvent molecule proceeded simultaneously in MeOH.
  • 66
    • 33750351610 scopus 로고    scopus 로고
    • note
    • 3-TPA, which has the substituents with the opposite electronic effect, showed no peak attributable to the linkage isomerization.
  • 71
    • 33750299291 scopus 로고    scopus 로고
    • note
    • 48
  • 72
    • 33750348306 scopus 로고    scopus 로고
    • note
    • /([2-ol] + [2-one]) ratio taking account of the number of C-H bonds in a group.
  • 73
    • 0001739660 scopus 로고
    • Selective hydroxylation of adamantane at tertiary C atom(s) catalyzed by ruthenium porphyrin complexes was reported: (a) Ohtake, H.; Higuchi, T.; Hirobe, M. J. Am. Chem. Soc. 1992, 114, 10660-10662.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 10660-10662
    • Ohtake, H.1    Higuchi, T.2    Hirobe, M.3
  • 75
    • 33750331761 scopus 로고    scopus 로고
    • unpublished results
    • No Baeyer-Villiger product was observed in the oxidation of cyclooctane, although ε-caprolactone was obtained in the oxidation of cyclohexane: Yamaguchi, M.; Murakami, N.; Yamagishi, T., unpublished results.
    • Yamaguchi, M.1    Murakami, N.2    Yamagishi, T.3
  • 77
    • 33750283477 scopus 로고    scopus 로고
    • unpublished results
    • 2SO)]Cl complexes and found that the complex with 5-(benzylamide)-TPA was less reactive than that with TPA although that with 5-(benzyloxycarbonyl)-TPA was as reactive as that with 5-(methoxycarbonyl)-TPA: Yamaguchi, M.; Izawa, S.; Yamagishi, T., unpublished results.
    • Yamaguchi, M.1    Izawa, S.2    Yamagishi, T.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.