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(a) Goldberg, S. Z.; Kubiak, C.; Meyer, C. D.; Eisenberg, R. Inorg. Chem. 1975, 14, 1650-1654.
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Goldberg, S.Z.1
Kubiak, C.2
Meyer, C.D.3
Eisenberg, R.4
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69
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37049137680
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(b) Masters, C.; McDonald, W. S.; Raper, G.; Shaw, B. L. Chem. Commun. 1971, 210-211.
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Masters, C.1
McDonald, W.S.2
Raper, G.3
Shaw, B.L.4
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70
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33947085761
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and references there in
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Axtell, D. D.; Yoke, J. T. Inorg. Chem. 1973, 12, 1265-1268 and references there in.
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Inorg. Chem
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Axtell, D.D.1
Yoke, J.T.2
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71
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37349056618
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3H][OTf], formed by the addition of triflic acid to an acetone solution of triethylphosphine, gave a signal at 44.41 ppm.
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3H][OTf], formed by the addition of triflic acid to an acetone solution of triethylphosphine, gave a signal at 44.41 ppm.
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72
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37349055288
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The presence of the non-coordinating BArf is significant in this reaction. Reaction of 4, 6 and, PNPtBu)RhCl, BArf] with CO gave exclusively 13, whereas the reaction of, PNP tBu)RhCl][BF4] with CO afforded 13 as a major product (75% yield according to 31P NMR) along with a new complex. Moreover, 4 and 6 react with one equiv of CO, whereas the reaction of 2 with CO required an excess for completion. The new complex exhibits, in the 31P{1H} NMR spectrum, a doublet at 54.4 ppm (JRhP, 84.5 Hz) and in the 19F NMR spectrum a broad signal at -149 ppm (coordinated BF4, This complex is transformed to 13 with time under CO. We assume that the complex is, PNPtBu)Rh(Cl)2BF4
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4)].
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73
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37349083747
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The X-ray diffraction of 13 was collected at 17°C because at lower temperature the crystals cracked.
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The X-ray diffraction of 13 was collected at 17°C because at lower temperature the crystals cracked.
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74
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0000429083
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(a) Wayland, B. B.; Sherry, A. E.; Bunn, A. G. J. Am. Chem. Soc. 1993, 115, 7675-7684.
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J. Am. Chem. Soc
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Wayland, B.B.1
Sherry, A.E.2
Bunn, A.G.3
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75
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0000129901
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(b) Poszmik, G.; Carroll, P. J.; Wayland, B. B. Organometallics 1993, 12, 3410-3417.
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Organometallics
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, pp. 3410-3417
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Poszmik, G.1
Carroll, P.J.2
Wayland, B.B.3
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76
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33751439214
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For recent mechanistic studies see
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For recent mechanistic studies see Zhang, L.; Fung, C. W.; Chan, K. S. Organometallics 2006, 25, 5381-89.
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(2006)
Organometallics
, vol.25
, pp. 5381-5389
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Zhang, L.1
Fung, C.W.2
Chan, K.S.3
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77
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Hay-Motherwell, R. S.; Koschmieder, S. U.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1991, 2821-2830.
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(1991)
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Hay-Motherwell, R.S.1
Koschmieder, S.U.2
Wilkinson, G.3
Hussain-Bates, B.4
Hursthouse, M.B.5
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79
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37349095846
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In the case of added PEt3, the resulting deprotonation process masks the difference in redox reactivity between 2 and 6
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3, the resulting deprotonation process masks the difference in redox reactivity between 2 and 6.
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