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Volumn 5, Issue 10, 1999, Pages 2921-2936

Selective oxidation of [RhI(cod)]+ by H2O2 and O2

Author keywords

Alkene complexes oxygen; Oxygenations; Peroxides; Rhodium

Indexed keywords

ALKADIENE; ALKENE DERIVATIVE; HYDROGEN PEROXIDE; METAL COMPLEX; OXYGEN; RHODIUM DERIVATIVE;

EID: 0032820302     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(19991001)5:10<2921::AID-CHEM2921>3.0.CO;2-1     Document Type: Article
Times cited : (76)

References (97)
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    • note
    • 2 in bulk olefin oxidation: Wacker process (ethene to acetaldehyde), SMPO process (propene to propeneoxide and ethylbenzene to styrene), EO process (ethene to etheneoxide).
  • 9
    • 85034564751 scopus 로고    scopus 로고
    • See: p. 72 in ref. [1c] and chapter 3 in ret. [1g]
    • See: p. 72 in ref. [1c] and chapter 3 in ret. [1g].
  • 14
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    • see ret. [1g]
    • e) see ret. [1g]
  • 26
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    • B. de Bruin, M. J. Boerakker, J. J. J. M. Donners, B. E. C. Christiaans, P. P. J. Schlebos, R. de Gelder, J. M. M. Smits, A. L. Spek, A. W. Gal, Angew. Chem. 1997, 109, 2153; Angew. Chem. Int. Ed. Engl. 1997, 36, 2064.
    • (1997) Angew. Chem. Int. Ed. Engl. , vol.36 , pp. 2064
  • 58
    • 85034552526 scopus 로고    scopus 로고
    • note
    • P = 1080 mV). Therefore, oxidation of the nitrogen-donor ligand can be excluded. In case of cod-centred oxidation, one would expect a much smaller influence of the nitrogen-donor ligand on the observed oxidation potential.
  • 72
    • 85034550359 scopus 로고    scopus 로고
    • note
    • 3J(H,H) = 5.4 Hz, 2H; Py-H6), 5.92 (m, 2H; O-CH-), 2.77 (m, 2H; Rh-CH-).
  • 76
    • 85034548146 scopus 로고    scopus 로고
    • note
    • 2-endo).
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    • note
    • +.
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    • 0004106467 scopus 로고    scopus 로고
    • A computer program system for crystal structure determination by Patterson methods and direct methods applied to difference structure factors; Crystallography Laboratory, University of Nijmegen (The Netherlands)
    • P. T. Beurskens, G. Beurskens, W. P. Bosman, R. de Gelder, S. Garcia-Granda, R. O. Gould, R. Israel, J. M. M. Smits, DIRDIF-96. A computer program system for crystal structure determination by Patterson methods and direct methods applied to difference structure factors; Crystallography Laboratory, University of Nijmegen (The Netherlands) 1996.
    • (1996) DIRDIF-96
    • Beurskens, P.T.1    Beurskens, G.2    Bosman, W.P.3    De Gelder, R.4    Garcia-Granda, S.5    Gould, R.O.6    Israel, R.7    Smits, J.M.M.8


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.