Synthesis and reactivity of mononuclear (pentachlorophenyl)rhodium(II) complexes. Structural relevance of rhodium-o-chlorine secondary bonding

Organometallics

Volumn 16, Issue 5, 1997, Pages 1026-1036

  García, María P ^a   Jiménez, M Victoria ^a   Cuesta, Angel ^a   Siurana, Carmen ^a   Oro, Luis A ^a   Lahoz, Fernando J ^a   López, José A ^a   Catalán, M Pilar ^a   Tiripicchio, Antonio ^b   Lanfranchi, Maurizio ^b  

^a Instituto de Nanociencia y Materiales de Aragón   (Spain)

^b UNIVERSITY OF PARMA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING LIGANDS; DEOXYGENATED SOLUTIONS; METHANOLIC SOLUTION; MONOMERIC COMPLEXES; RHODIUM COMPLEXES; SECONDARY BONDING; SECONDARY BONDING INTERACTIONS; SQUARE PLANAR GEOMETRY;

ATOMS; CHELATION; CHLORINE; CHLORINE COMPOUNDS; LIGANDS; RHODIUM; SYNTHESIS (CHEMICAL);

RHODIUM COMPOUNDS;

EID: 84897586283     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om960663i     Document Type: Article

References (81)

1. (a) Jardine, F. H.; Sheridan, P. S. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon Press: Oxford, U.K., 1987; Vol. 4, p 930.
2. (b) Livingstone, S. E. In Comprehensive Inorganic Chemistry; Bailar, J. C., Emeléus, H. J., Nyholm, R., Trotman-Dickenson, A. F., Eds.; Pergamon Press: Oxford, U.K., 1973; Vol. 3, Chapter 43.
3. (c) Felthouse, T. M. Prog. Inorg. Chem. 1982, 29, 73.
4. (d) Pruchnick, F. P. Pure Appl. Chem. 1989, 61, 795.
5. For recent reviews see: (a) Bianchini, C.; Peruzzini, M.; Laschi, F.; Zanello, P. In Topics in Physical Organometallic Chemistry; Gielen, M. F., Ed.; Freund: London, 1991; Vol. 4, pp 139-220.
6. (b) Pandey, K. K. Coord. Chem. Rev. 1992, 121, 1.
7. (c) De Wit, D. G. Coord. Chem. Rev. 1996, 147, 209.
8. (a) Haefner, S. C.; Dunbar, K. R.; Bender, C. Organometallics 1991, 113, 9540.
9. (b) Dunbar, K. R.; Haefner, S. C.; Pence, L. E. J. Am. Chem. Soc. 1989, 111, 5504.
10. (c) Harlow, R. L.; Thorn, D. L.; Barker, R. T.; Jones, N. L. Inorg. Chem. 1992, 31, 993.
11. Cooper, S. R.; Rawle, S. C.; Yagbasan, R.; Watkin, J. J. Am. Chem. Soc. 1991, 113, 1600.
12. Pandey, K. K.; Nehete, D. T.; Sharma, R. B. Polyhedron 1990, 9, 2013.
13. Peng, S.; Peters, K.; Peters, E. M.; Simon, A. Inorg. Chim. Acta 1985, 101, L35.
14. Wayland, B. B.; Ba, S.; Sherry, A. E. J. Am. Chem. Soc. 1991, 113, 5305.
15. Wayland, B. B.; Ba, S.; Sherry, A. E. Inorg. Chem. 1992, 31, 148.
16. Bunn, A. G.; Wei, M.; Wayland, B. B. Organometallics 1994, 13, 3390 and references therein.
17. Hay-Motherwell, R. S.; Koschmieder, S. U.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1991, 2821.
18. García, M. P.; Jiménez, M. V.; Oro, L. A.; Lahoz, F. J.; Casas, J. M.; Alonso, P. J. Organometallics 1993, 12, 3257.
19. Dunbar, K. R.; Haefner, S. C. Organometallics 1992, 11, 1431.
20. Bianchini, C.; Laschi, F.; Ottaviani, F.; Peruzzini, M.; Zanello, P. Organometallics 1988, 7, 1660.
21. Fischer, E. O.; Lindner, H. H. J. Organomet. Chem. 1964, 1, 307.
22. Fischer, E. O.; Wawersick, H. J. Organomet. Chem. 1966, 5, 559.
23. Keller, H. J.; Wawersick, H. J. Organomet. Chem. 1967, 8, 185.
24. Dessy, R. E.; King, R. B.; Waldrop. M. J. Am. Chem. Soc. 1966, 88, 5112.
25. Pilloni, G.; Schiavon, G.; Zotti, G.; Zecchin, S. J. Organomet. Chem. 1977, 134, 305.
26. Bianchini, C.; Laschi, F.; Meli, A.; Peruzzini, M.; Zanello, P.; Frediani, P. Organometallics 1988, 7, 2575.
27. Bianchini, C.; Herrera, V.; Jiménez, M. V.; Laschi, F.; Meli, A.; Sanchez-Delgado, R.; Vizza, F.; Zanello, P. Organometallics 1995, 14, 4390.
28. (a) García, M. P.; Oro, L. A.; Lahoz, F. J. Angew. Chem. 1988, 100, 1766;
29. Angew. Chem., Int. Ed. Engl. 1988, 27, 1700.
30. (b) García, M. P.; Jiménez, M. V.; Lahoz, F. J.; Oro, L. A.; Tiripicchio, A.; Lopez, J. A. J. Chem. Soc., Dalton Trans. 1990, 1503.
31. (c) García, M. P.; Jiménez, M. V.; Lahoz, F. J.; Oro, L. A. J. Chem. Soc., Dalton Trans. 1995, 917.
32. (d) García, M. P.; Jiménez, M. V.; Oro, L. A. J. Organomet. Chem. 1992, 438, 229.
33. (a) García, M. P.; Jiménez, M. V.; Lahoz, F. J.; Oro, L. A. Inorg. Chem. 1995, 34, 2153.
34. (b) García, M. P.; Jiménez, M. V.; Oro, L. A.; Lahoz, F. J.; Alonso, P. J. Angew. Chem. 1992, 104, 1512;
35. Angew. Chem., Int. Ed. Engl. 1992, 31, 1527.
36. García, M. P.; Jiménez, M. V.; Oro, L. A.; Lahoz, F. J.; Camellini Tiripicchio, M.; Tiripicchio, A. Organometallics 1993, 12, 4660.
37. (a) Usón, R.; Forniés, J.; Tomás, M.; Menjón, B.; Sünkel, K.; Bau, R. J. Chem. Soc., Chem. Commun. 1984, 751.
38. (b) Usón, R.; Forniés, J.; Tomás, M.; Menjón, B.; Bau, R.; Sünkel, K.; Kuwabara, E. Organometallics 1986, 5, 1576.
39. + cations, respectively.
40. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. J. Chem. Soc., Chem. Commun. 1989, 1436.
41. Hay-Motherwell, R. S.; Wilkinson, G.; Hussain-Bates, B.; Hursthouse, M. B. Polyhedron 1990, 2071.
42. Geary, W. J. Coord. Chem. Rev. 1971, 7, 81.
43. Maslowsky, E. Vibrational Spectra of Organometallic Compounds; Wiley: New York, 1977; p 437.
44. Usón, R.; Fornies, J.; Martínez, F.; Tomás, M.; Reoyo, I. Organometallics 1983, 2, 1386.
45. Usón, R.; Fornies, J.; Fandos, R.; Tomás, M. J. Chem Soc., Dalton Trans. 1980, 888.
46. Norbury, A. H. Adv. Inorg. Chem. Radiochem. 1975, 17, 231.
47. Bock, B.; Flatau, K.; Junge, H.; Kurh, M.; Musso, H. Angew. Chem., Int. Ed. Engl. 1971, 10, 225.
48. Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
49. McGuiggan, M. F.; Doughty, D. H.; Pignolet, L. H. J. Organomet. Chem. 1980, 185, 241.
50. 27b
51. (b) Porterfield, W. W. Inorganic Chemistry: A Unified Approach; Addison-Wesley: Reading, MA, 1984; p 168.
52. 29
53. Kulawiec, R. J.; Crabtree, R. H. Coord. Chem. Rev. 1990, 99, 89.
54. Leigh, G. J. In Nomenclature of Inorganic Compounds; Blackwell Scientific: Oxford, U.K., 1991; p 159.
55. Forniés, J.; Menjón, B.; Sanz-Carrillo, R. M.; Tomás, M.; Connelly, N. G.; Crossley, J. G.; Orpen, A. G. J. Am. Chem. Soc. 1995, 11, 4295.
56. Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. in International Tables for Crystallography; Kluwer Academic: Dordrecht, The Netherlands, 1992; Vol. C, p 707.
57. Appleton, T. G.; Clark, H. C.; Manzer, L. E. Coord. Chem. Rev. 1973, 10, 335.
58. Shie, J.-Y.; Lin, Y.-C.; Wang, Y. J. Organomet. Chem. 1989, 371, 383.
59. Cabeza, J.; Riera, V.; Villa-García, M. A.; Ouahab, L.; Triki, S. J. Organomet. Chem. 1992, 441, 323.
60. Usón, R.; Forniés, J.; Tomás, M. J. Organomet. Chem. 1988, 358, 525.
61. Harrison, R.; Arif, A. M.; Wulfsberg, G.; Lang, R.; Ju, T.; Kiss, G.; Hoff, C. D.; Richmond, T. G. J. Chem. Soc., Chem. Commun. 1992, 1374.
62. Lahuerta, P.; Peris, E.; Ubeda. M. A.; García-Granda, S.; Gómez-Beltrán, F.; Díaz, M. R. J. Organomet. Chem. 1993, 455, C10.
63. García-Bernabé, A.; Lahuerta, P.; Ubeda, M. A.; García-Granda, S.; Pertierra, P. Inorg. Chim. Acta 1995, 229, 203.
64. Van Seggen, D. M.; Hurlburt, P. K.; Anderson, O. P.; Strauss, S. H. Inorg. Chem. 1995, 34, 3453 and references therein.
65. Meyer, R.; Gagliardi, J., Jr.; Wulfsberg, G. J. Mol. Struct. 1983, 111, 311.
66. Wulfsberg, G.; Yanisch, J.; Meyer, R.; Bowers, J.; Essig, M. Inorg. Chem. 1984, 23, 715.
67. Wulfsberg, G.; Jackson, D.; Ilsley, W.; Dou, S.; Weiss, A; Gagliardi, J., Jr. Z. Naturforsch. 1992, 47A, 75.
68. Richardson, M. F.; Wulfsberg, G.; Marlow, R.; Zaghonni, S.; McCorkle, D.; Shadid, K.; Gagliardi, J., Jr.; Farris, B. Inorg. Chem. 1993, 32, 1913.
69. Mealli, C.; Proserpio, D. M. J. Chem. Educ. 1990, 67, 39.
70. Burk, M. J.; Crabtree, R. H.; Holt, E. M. J. Organomet. Chem. 1988, 341, 495.
71. Allen, E. A.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1972, 613.
72. Rausch, M. D.; Moser, G. A.; Meade, C. F. J. Organomet. Chem. 1973, 51, 1.
73. Bermejo, F. Tratado de Química Analítica, 6th ed.; Editorial Dossat: Madrid, 1981; p 813.
74. North, A. C. T.; Phillips, D. C.; Mathews, F. S. Acta Crystallogr. 1968, A24, 351.
75. Sheldrick, G. M. SHELX-76. Program for Crystal Structure Determination; University of Cambridge, Cambridge, U.K., 1976.
76. Sheldrick, G. M. SHELXL-93; University of Göttingen, Göttingen, Germany, 1993.
77. International Tables for X-Ray Crystallography; Kynoch Press: Birmingham, U.K., 1974; Vol. 4.
78. Altomare, A.; Cascarano, G.; Giacovazzo, C.; Guagliardi, A. J. Appl. Crystallogr. 1994, 27, 435.
79. Flack, H. D. Acta Crystallogr. 1983, A39, 876.
80. Ammeter, J. H.; Bürgi, H. B.; Thibeault, J. C.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 3686.
81. Alvarez, S. Table of Parameters for Extended Hückel Calculations; Departamento de Química Inorgánica, Universidad de Barcelona: Barcelona, Spain, 1989.