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The few isolated 2-metallaoxetanes known are all stabilized by various substituents. Consequently, it is difficult to deduce the intrinsic reactivity of the unsubstituted 2-metallaoxetane moiety from these substituted examples: a) V. W. Day, W. G. Klemperer, S. P. Lockledge, D. J. Main, J Am. Chem. Soc. 1990, 112, 2031;
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28
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0344280083
-
-
note
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Details of the crystal structure determination are available as supporting information on the WWW.
-
-
-
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29
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85088333894
-
-
note
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2O.
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30
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0000740880
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2+. see D. L. Thorn, J. C. Calabrese, J. Organomet. Chem. 1984, 272, 283. For other examples of nitrile C≡N-bond activation by metal coordination (including Pinner type reactions with alcohols), see B. N. Storhoff, H. C. Lewis Jr., Coord. Chem. Rev. 1977, 23, 1
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2+. see D. L. Thorn, J. C. Calabrese, J. Organomet. Chem. 1984, 272, 283. For other examples of nitrile C≡N-bond activation by metal coordination (including Pinner type reactions with alcohols), see B. N. Storhoff, H. C. Lewis Jr., Coord. Chem. Rev. 1977, 23, 1
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0344280081
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Wiley, and references therein
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For the Pinner syntheses, see J. March, Advanced Organic Chemistry, 4th ed, Wiley, 1992, p. 892, and references therein. For the Ritter reaction, see J. March, Advanced Organic Chemistry, 4th ed, Wiley, 1992, p. 970. and references therein.
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0344280080
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Wiley, and references therein
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For the Pinner syntheses, see J. March, Advanced Organic Chemistry, 4th ed, Wiley, 1992, p. 892, and references therein. For the Ritter reaction, see J. March, Advanced Organic Chemistry, 4th ed, Wiley, 1992, p. 970. and references therein.
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March, J.1
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0003523826
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Crystallography Laboratory, University of Nijmegen (Netherlands)
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b) P. T. Beurskens, G. Beurskens, W. P. Bosman, R. de Gelder, S. Garcia-Granda, R. O. Gould, R. Israel, J. M. M. Smits, DIRDIF-96, computer program system for crystal structure determination by Patterson and direct methods applied to difference-structure factors, Crystallography Laboratory, University of Nijmegen (Netherlands), 1996;
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0345574058
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note
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2 · MeOH, respectively. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ. UK (fax: (+44) 1223-336-033: e-mail: deposit@ccdc.cam.ac.uk)
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34548068164
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The thermal decomposition of alkylalkanimidates yields, among others, nitriles and alcohols or trisubstituted 1.3.5-triazines and alcohols: a) F. Cramer, K. Pawelzik, J. Kupper, Angew. Chem. 1956, 20, 649;
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