Tetrathiafulvalene porphyrins

Chemistry - A European Journal

Volumn 15, Issue 2, 2009, Pages 506-516

  Nielsen, Kent A ^a   Levillain, Eric ^b   Lynch, Vincent M ^c   Sessler, Jonathan L ^c   Jeppesen, Jan O ^a  

^a UNIVERSITY OF SOUTHERN DENMARK   (Denmark)

^b UNIVERSITÉ D'ANGERS   (France)

^c UNIVERSITY OF TEXAS AT AUSTIN   (United States)

Author keywords

Electrochemistry; Electron transfer; Porphyrinoids; Supramolecular chemistry; Tetrathiafulvalenes

Indexed keywords

ABSORPTION SPECTROSCOPY; ELECTROCHEMISTRY; ELECTRON TRANSITIONS; EMISSION SPECTROSCOPY; FLUORESCENCE; MACROMOLECULES; OXIDATION; REDUCTION; SPECTROSCOPIC ANALYSIS; SUPRAMOLECULAR CHEMISTRY;

ELECTRON TRANSFER; EMISSION INTENSITIES; EMISSION SPECTRUMS; MODEL COMPOUNDS; NEUTRAL STATES; OXIDATION POTENTIALS; PORPHYRINOIDS; REDOX POTENTIAL (RP); REDUCTION POTENTIALS; TETRAPHENYLPORPHYRIN (TCPP); TETRATHIAFULVALENE) (BEDT TTF); TETRATHIAFULVALENES;

PORPHYRINS;

HETEROCYCLIC COMPOUND; PORPHYRIN; TETRATHIAFULVALENE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; ELECTROCHEMISTRY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; HETEROCYCLIC COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; MASS SPECTROMETRY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PORPHYRINS;

EID: 58449123488     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801636     Document Type: Article

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87. ̇+) reflects the different physical properties of these ostensibly similar tetraTTF-porphyrin products. Note the high stability of both the neutral product 1, whose synthesis is detailed in this report, and the radical-cation porphyrin mixture prepared earlier. Unfortunately, as noted above, efforts to interconvert these ostensibly similar materials proved unsuccessful.
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